Kenneth D. Karlin Research Group > Publications > 2019 Publications

2019 Publications

359. Quist, David A.; Ehudin, Melanie A.; Karlin, Kenneth D. “Unprecedented Direct Cupric-Superoxo Conversion to a Bis-μ-oxo Dicopper(III) Complex and Resulting Oxidative Activity” Inorg. Chim. Acta 2019, 485, 155-161. DOI: 10.1016/j.ica.2018.10.015. PMCID: PMC6461407

360. Ehudin, Melanie A.; Schaefer, Andrew W.; Adam, Suzanne M.; Quist, David A.; Diaz, Daniel E.; Tang, Joel A.; Solomon, Edward I.; Karlin, Kenneth D. “Influence of Intramolecular Secondary Sphere Hydrogen-Bonding Interactions on Cytochrome c Oxidase Inspired Low-Spin Heme-Peroxo-Copper Complexes” Chemical Science, 2019, 10, 2893–2905.  DOI: 10.1039/C8SC05165H. Edge Article. PMCID: PMC6431958

361. Schaefer, Andrew W.; Ehudin, Melanie A.; Quist, David A.; Tang, Joel A.; Karlin, Kenneth D.; Solomon, Edward I. “Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions” J. Am. Chem. Soc. 2019, 141, 4936–4951. DOI: 10.1021/jacs.9b00118. PMCID: PMC6457345

362. Ehudin; Melanie, A.; Gee, Leland B.; Sabuncu, Sinan; Braun, Augustin; Moënne-Loccoz, Pierre; Hedman, Britt; Hodgson Keith O.; Solomon, Edward I.; Karlin, Kenneth D. “Tuning the Geometric and Electronic Structure of Synthetic High-Valent Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial Ligands.” J. Am. Chem. Soc. 2019, 141, 5942-5960. DOI: 10.1021/jacs.9b00795.    PMCID: PMC6611672

363. Ehudin Melanie, A.; Senft, L.; Franke, Alicja; Ivanović-Burmazović, Ivana; Karlin, Kenneth D. “Formation and Reactivity of New Isoporphyrins: Implications for Understanding the Tyr-His Cross-Link Cofactor Biogenesis in Cytochrome c Oxidase” J. Am. Chem. Soc. 2019, 141, 10632−10643. DOI: 10.1021/jacs.9b01791. PMCID: PMC6639807

364. Liu, Jeffrey J.; Siegler, Maxime A.; Karlin, Kenneth D.; Moenne-Loccoz, P. “Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O2 and NO and Mechanistic Insights into Metal Mediated Peroxynitrite Decomposition” Angew. Chem. Int. Ed., 2019, 58, 10936–10940. DOI: 10.1002/anie.201904672. PMCID: PMC6685550

365. Ehudin, Melanie, A.; Quist, David A.; Karlin, Kenneth D. “Enhanced Rates of C−H Bond Cleavage by a Hydrogen-Bonded Synthetic Heme High-Valent Iron(IV) Oxo Complex” J. Am. Chem. Soc. 2019, 141, 12558-12569. DOI: 10.1021/jacs.9b01253.

366. Quist, David. A.; Ehudin, Melanie A.; Schaefer, Andrew W.; Schneider, Gregory L.; Solomon, Edward I.; Karlin, Kenneth D. “Ligand Identity-Induced Generation of Enhanced Oxidative Hydrogen Atom Transfer Reactivity for a CuII2(O2•−) Complex Driven by Formation of a CuII2(−OOH) Compound with a Strong O−H Bond”. J. Am. Chem. Soc. 2019, 141, 12682-12696. DOI: 10.1021/jacs.9b05277.

367. Diaz, Daniel E.; Quist, David A.; Herzog, Austin E.; Schaefer, Andrew W.; Kipouros, I.; Bhadra, Mayukh; Solomon, Edward I.; Karlin, Kenneth D. “Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O–H and C–H Substrates” Angew. Chem. Int. Ed., 2019, in press.    DOI: 10.1002/anie.201908471