2014 Publications

329.     Garcia-Bosch, Isaac; Karlin, Kenneth D. (2014) ‘Copper peroxide bioinorganic chemistry: from metalloenzymes to bioinspired synthetic systems’ in The Chemistry of Peroxides, Volume 3, edited by A. Greer and J.F. Liebman. John Wiley & Sons, Ltd: Chichester, UK, pp. 805-856. (Does not fall under the Public Access Policy)

328.     Park, Ga Young; Lee, Jung Yoon; Himes, Richard A.; Thomas, Gnana S.; Blackburn, Ninian J.; Karlin, Kenneth D. “Copper–Peptide Complex Structure and Reactivity When Found in Conserved His-Xaa-His Sequences” J. Am. Chem. Soc. 2014, 136, 12532-12535. doi 10.1021/ja505098v PMCID:  PMC4160276

327.     Lee, Jung Yoon; Peterson, Ryan L.; Ohkubo, Kei; Garcia-Bosch, Isaac; Himes, Richard A.; Woertink, Julia; Moore, Cathy; Solomon, Edward I,; Fukuzumi, Shunichi; Karlin, Kenneth D.. “Mechanistic Insights into the Oxidation of Substituted Phenols via Hydrogen Atom Abstraction by a Cupric Superoxo Complex”. J. Am. Chem. Soc. 2014, 136, 9925-9937. DOI: 10.1021/ja503105b PMCID: PMC4102632.

326.     Clarence J. Rolle, III, Claudio Saracini and Kenneth D. Karlin “Copper: Hemocyanin/Tyrosinase Models” in Encyclopedia of Inorganic and Bioinorganic Chemistry, ed R.A. Scott, John Wiley: Chichester. DOI: 10.1002/9781119951438.eibc0049.pub2. Published 6/16/2014. (Does not fall under the Public Access Policy)

325.     Kim, Sunghee; Ginsbach Jake W.; Billah, A. Imtiaz; Siegler Maxime A.; Moore, Cathy D.; Solomon Edward I., Karlin Kenneth D. “Tuning of the Copper–Thioether Bond in Tetradentate N3S(thioether) Ligands; O–O Bond Reductive Cleavage via a [CuII2(m-1,2-peroxo)]2+/[CuIII2(m-oxo)2]2+ Equilibrium” J. Am. Chem. Soc. 2014, 136, 8063-8071. doi: 10.1021/ja502974c PMCID: PMC4063178.

324.     Hematian, Shabnam; Siegler, Maxime A.; Karlin, Kenneth D. Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity J Biol Inorg Chem 2014, 19, 515-528. doi:  10.1007/s00775-013-1081-6 PMCID: PMC4031290

323.     Kieber-Emmons, M. T.; Ginsbach, J. W.; Wick, P. K.; Lucas, H. R.; Helton, M. E.; Lucchese, B.; Suzuki, M.; Zuberbühler, A. D.; Karlin, K. D.; Solomon, E. I. Observation of a CuII2(μ-1,2-peroxo)/CuIII2(μ-oxo)2 Equilibrium and its Implications for Copper–Dioxygen Reactivity Angew. Chem., Int. Ed. 2014, 53, 4935-4939. DOI: 10.1002/anie.201402166 PMCID: PMC4041702

322.     Kim, Sunghee, Siegler, Maxime A.; Karlin, Kenneth D. Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction. Chem. Commun. 2014, 50, 2844-2846. DOI: 10.1039/C3CC47942K PMCID: PMC3931255

321.      Yokoyama, A.; Han, J. E.; Karlin, K. D.; Nam, W., An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion. Chem. Commun. 2014, 50 , 1742-1744. doi:  10.1039/c3cc48782b PMCID: PMC4078658.

320.     Saracini, C.; Liakos, D. G.; Zapata Rivera, J. E.; Neese, F.; Meyer, G. J.; Karlin, K. D., Excitation Wavelength Dependent O2 Release from Copper(II)–Superoxide Compounds: Laser Flash-Photolysis Experiments and Theoretical Studies. J. Am. Chem. Soc. 2014, 136, 1260-1263,doi: 10.1021/ja4115314 PMCID: PMC3936478