2016 Publications

348.     Cao, Rui; Elrod, Lee Taylor, Lehane, Ryan L.; Kim, Eunsuk; Karlin, Kenneth D. “A Peroxynitrite Dicopper Complex: Formation via Cu–NO and Cu–O2 Intermediates and Reactivity via O–O Cleavage Chemistry” J. Am. Chem. Soc. 2016, 138, 16148−16158.   DOI: 10.1021/jacs.6b10689

347. Liu, Jeffrey J.; Diaz, Daniel E.; Quist, David A.; Karlin, Kenneth D. “Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms”. Isr. J. Chem. 2016, 56,738-755. DOI: 10.1002/ijch.201600025

346. Hong, S.; Kumar, P.; Cho, K.-B.; Lee, Y.-M.; Karlin, K. D.; Nam, W. “Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)–Superoxo and Manganese(IV)–Peroxo Complexes” Angew. Chem. Intl. Ed. 2016, 55, 12403-12407. DOI: 10.1002/anie.201605705. PMCID: PMC5042135

345. Sharma, Savita K.; Kim, Hyun; Rogler, Patrick J.; Siegler, Maxime, A.; Karlin, Kenneth D. “Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization”. J. Biol. Inorg. Chem. 2016 21, 729-743. DOI: 10.1007/s00775-016- 1369-4 NIHMSID:800180

344. Kumar, P.; Lee, Y.-M.; Hu, L.; Chen, J.; Park, Y. J.; Yao, J.; Chen, H.; Karlin, K. D.; Nam, W. “Factors That Control the Reactivity of Cobalt(III)–Nitrosyl Complexes in Nitric Oxide Transfer and Dioxygenation Reactions: A Combined Experimental and Theoretical Investigation”. J. Am. Chem. Soc. 2016, 138, 7753-7762. DOI: 10.1021/jacs.6b04040, PMCID: PMC4951108

343. Cao, Rui.; Saracini, Claudio; Ginsbach, Jake W.; Kieber-Emmons, Matthew T.; Siegler, Maxime A.; Solomon, Edward I.; Fukuzumi, Shunichi; Karlin, Kenneth D. “Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy”. J. Am.Chem. Soc. 2016, 138, 7055-7066. DOI: 10.1021/jacs.6b02404 800307 PMCID: PMC4950875

342. Garcia-Bosch, Isaac; Cowley, Ryan E.; Diaz, Daniel E.; Siegler, Maxime A. Siegler; Nam,Wonwoo Nam; Solomon, Edward I.; Karlin, Kenneth D. “Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu 2 O 2 Core with Unexpected Structure and Reactivity”, Chem. Eur. J.,2016,DOI: 10.1002/chem.201600551 PMCID: PMC4852750

341. Yamada, Mihoko; Karlin, Kenneth D.; Fukuzumi, Shunichi, “One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina”, Chem. Sci., 2016, 7, 2856-2863. July 5, ‘16In process NIHMSID 781769, DOI: 10.1039/C5SC04312C PMCID: PMC4951108