2015 Publications

  1. Saracini, Claudio; Ohkubo, Kei; Suenobu, T.; Meyer, Gerald J.; Karlin, Kenneth D.; Fukuzumi, Shunichi, “Laser-Induced Dynamics of Peroxodicopper(II) Complexes Vary with the Ligand Architecture. One-Photon Two-Electron O2 Ejection and Formation of Mixed-Valent CuICuII–Superoxide Intermediates”, J. Am. Chem. Soc. 2015, 137, 15865-15874. DOI: 10.1021/jacs.5b10177. PMCID: PMC4704693.
  2. Hematian, Shabnam; Garcia-Bosch, Isaac; Karlin, Kenneth D. Synthetic Heme/Copper Assemblies: Toward an Understanding of Cytochrome c Oxidase Interactions with Dioxygen and Nitrogen Oxides,” Acc. Chem. Res. 2015, 48, 2462-2474. DOI: 10.1021/acs.accounts.5b00265. PMCID: PMC4779337
  3. Chatterjee, Sudipta; Sengupta, Kushal; Hematian, Shabnam; Karlin, Kenneth D.; Dey, Abhishek “Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a “Bridging Peroxo” Intermediate Involved in Facile 4e/4H+ O2-Reduction” J. Am. Chem. Soc. 2015, 137, 12897-12905. PMCID: PMC4690469.
  4. Hematian, Shabnam; Kenkel, Isabell Kenkel; Shubina, Tatyana E.; Dürr, Maximilian; Liu, Jeffrey J.; Siegler, Maxime A.; Ivanovic-Burmazovic, Ivana; Karlin, Kenneth D. “Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo heme-FeIII–O–CuII(L) Constructs” J. Am. Chem. Soc., 2015, 137, 6602-6615. PMCID: PMC4469181.
  5. Kumar, Pankaj; Lee, Yong-Min; Park, Young Jun Park; Siegler, Maxime A.; Siegler; Karlin, Kenneth D.; Nam, Wonwoo. “Reactions of Co(III)−Nitrosyl Complexes with Superoxide and Their Mechanistic Insights” J. Am. Chem. Soc., 2015, 137, 4284−4287. doi: 10.1021/ja513234b PMCID: PMC4523085
  6. Lee, Jung Yoon; Karlin, Kenneth D. “Elaboration of copper–oxygen mediated C–H activation chemistry in consideration of future fuel and feedstock generation” Curr. Opin. Chem. Biol. 2015, 25, 184-193. doi: 10.1016/j.cbpa.2015.02.014   PMCID: PMC4385254.
  7. Sharma, Savita K.; Rogler, Patrick J.; Karlin, Kenneth D. “Reactions of a heme-superoxo complex toward a cuprous chelate and •NO(g):CcO and NOD chemistry”. J. Porphyrins and Phthalocyanines, 2015, 19, 352-360.  doi: 10.1142/S108842461550025X. PMCID: PMC4457333
  8. Kakuda, Saya; Rolle, Clarence J.; Ohkubo, Kei; Siegler, Maxime A.; Karlin, Kenneth D.; Fukuzumi, Shunichi “Lewis Acid-Induced Change from Four- to Two-Electron Reduction of Dioxygen Catalyzed by Copper Complexes Using Scandium Triflate” J. Am. Chem. Soc. 2015, 137, 3330-3337. doi: 10.1021/ja512584r, PMCID: PMC4630010.
  9. Kim, Sunghee; Ginsbach, Jake W.; Lee, Jung Yoon; Peterson, Ryan L.; Liu, Jeffrey J.; Siegler, Maxune A.; Sarjeant, Amy A.; Solomon, Edward I.; Karlin, Kenneth D. “Amine Oxidative N-Dealkylation via Cupric Hydroperoxide Cu-OOH Homolytic Cleavage Followed by Site-Specific Fenton Chemistry” J. Am. Chem. Soc. 2015, 137, 2867-2874. doi: 10.1021/ja508371q PMCID: PMC4482616.
  10. Kim, Sunghee; Lee, Jung Yoon; Cowley, Ryan E.; Ginsbach, Jake W.; Siegler, Maxime A.; Solomon, Edward I.; Karlin, Kenneth D. “A N3S(thioether)-Ligated CuII-Superoxo with Enhanced Reactivity” J. Am. Chem. Soc. 2015, 137, 2796-2799. PMCID: PMC4482613330.
  11. Garcia-Bosch, Isaac; Adam, Suzanne M.; Schaefer, Andrew W.; Sharma, Savita K.; Peterson, Ryan L.; Solomon, Edward I.; Karlin, Kenneth D. “A “Naked” FeIII-(O22–)-CuII Species Allows for Structural and Spectroscopic Tuning of Low-spin Heme-Peroxo-Cu Complexes”, J. Am. Chem. Soc., 2015, 137, 1032-1035. doi: 10.1021/ja5115198    PMCID: PMC4311974