2012 Publications

  1. Kim, Sunghee; Saracini, Claudio; Siegler, Maxime A.; Drichko, Natalia; Karlin, Kenneth D. “Coordination Chemistry and Reactivity of a Cupric Hydroperoxide Species Featuring a Proximal H-Bonding Substituent”, Inorg. Chem. 2012, 51, 12603-12605.   PMCID: PMC3513638.

Selected as part of an On-Line Virtual special issue of Inorg. Chem, “Models for Metallenzymes”, http://pubs.acs.org/page/vi/2013/models-of-metalloenzymes.html

  1. Hematian, Shabnam; Sigeler, Maxime A.; Karlin, Kenneth D. “Heme/Copper Assembly Mediated Nitrite and Nitric Oxide Interconversion, M. J. Am. Chem. Soc. 2012, 134, 18912-18915. PMCID: PMC3507325
  2. Fukuzumi, S.; Doi, K.; Itoh, A.; Suenobu, T.; Ohkubo, K.; Yamada, Y.; Karlin, K. D. “Formation of a long-lived electron-transfer state in mesoporous silica-alumina composites enhances photocatalytic oxygenation reactivity Proc. Nat. Acad. Sci. 2012, 109, 15572-15577. PMCID: PMC3465401
  3. Fukuzumi, S.; Yamada, Y.; Karlin, K. D. “Hydrogen peroxide as a sustainable energy carrier: Electrocatalytic production of hydrogen peroxide and the fuel cell Electrochimica Acta 2012, 82, 493-511. PMCID: PMC3584454
  4. Yokoyama, A.; Han, J. E.; Cho, J.; Kubo, M.; Ogura, T.; Siegler, M. A.; Karlin, K. D.; Nam, W. “Chromium(IV)–Peroxo Complex Formation and Its Nitric Oxide Dioxygenase Reactivity” J. Am. Chem. Soc. 2012, 134, 15269-15272. PMCID: PMC3496875
  5. Yamada, Y.; Maeda, K.; Ohkubo, K.; Karlin, K. D.; Fukuzumi, S. “Improvement of durability of an organic photocatalyst in p-xylene oxygenation by addition of a Cu(II) complex”, Phys. Chem. Chem. Phys. 2012 14, 9654-9659. PMCID: PMC3413205
  6. Karlin, K. D.; Zhang, C. X.; Rheingold, A. L.; Galliker, B.; Kaderli, S.; Zuberbühler, A. D. “Reversible dioxygen binding and arene hydroxylation reactions: Kinetic and thermodynamic studies involving ligand electronic and structural variations”. Inorg. Chim. Acta 2012, 389, 138-150. PMCID: PMC3570229.

299,     Ghiladi, R. A.; Rheingold, A. L.; Siegler, M. A.; Karlin, K. D. “Synthesis and characterization of new trinuclear copper complexes”, Inorg. Chim. Acta 2012 389, 131-137.  (PMCID: PMC3389755)

  1. Park, G. Y.; Qayyum, M. F.; Woertink, J.; Hodgson, K. O.; Hedman, B.; Narducci Sarjeant, A. A.; Solomon, E. I.; Karlin, K. D.: Geometric and Electronic Structure of [{Cu(MeAN)}2(m-h2:h2-O22–)]2+ with an Unusually Long O–O Bond: O–O Bond Weakening vs Activation for Reductive Cleavage. J. Am. Chem. Soc. 2012, 134, 8513-8524. (PMCID: PMC3437010)
  2. Fukuzumi, S., Tahsini, L., Lee, Y.-M., Ohkubo, K.; Nam, W.; Karlin, K. D. “Factors That Control Catalytic Two- versus Four-Electron Reduction of Dioxygen by Copper Complexes,” J. Am. Chem. Soc. 2012, 134, 7025-7035.   (PMCID: PMC3381452)
  3. Comba, P., Haaf. C.; Helmle, S.; Karlin, K. D.; Pandian, S.; Waleska, A. “Dioxygen reactivity of new bispidine-copper complexes”, Inorg. Chem., 2012 51, 2841-2851. (PMCID: PMC3294187)
  4. Tahsini, L.; Kotani, H.; Lee, Y.-M.; Cho, J.; Nam, W.; Karlin, K. D.; Fukuzumi, S. “Electron-Transfer Reduction of Dinuclear Copper Peroxo and Bis-m-oxo Complexes Leading to the Catalytic Four-Electron Reduction of Dioxygen to Water” Chem.-Eur. J. 2012, 18, 1084-1093. (PMCID: PMC3316124).
  5. Kieber-Emmons, M. T.; Qayyum, M. F.; Li, Y.; Halime, Z.; Hodgson, K. O.; Hedman, B.; Karlin, K. D.; Solomon, E. I. “Spectroscopic Elucidation of a New Heme/Copper Dioxygen Structure Type: Implications for O⋅⋅⋅O Bond Rupture in Cytochrome c Oxidase” Angew. Chem., Int. Ed. 2012, 51, 168-172. PMCID: PMC3517061.