2013 Publications

  1. Qayyum, M. F.; Sarangi, R.; Fujisawa, K.; Stack, T. D. P.; Karlin, K. D.; Hodgson, K. O.; Hedman, B.; Solomon, E. I. “L-Edge X-ray Absorption Spectroscopy and DFT Calculations on Cu2O2 Species: Direct Electrophilic Aromatic Attack by Side-on Peroxo Bridged Dicopper(II) Complexes” J. Am. Chem. Soc. 2013, 135, 17417-17431. doi:  10.1021/ja4078717 PMCID: PMC3891796
  2. Karlin, Kenneth D.; Rolle, Clarence J.; Kim, Sunghee; Lee, Jung Yoon, “Highlights and Directions in Copper-Dioxygen Chemistry of Bioinorganic Relevance” Bull. Jpn. Soc. Coord. Chem., 62, 2013, 40-44. Non compliant Publication.
  3. Ginsbach, J. W.; Peterson, R. L.; Cowley, R. E.; Karlin, K. D.; Solomon, E. I., Correlation of the Electronic and Geometric Structures in Mononuclear Copper(II) Superoxide Complexes. Inorg. Chem. 2013, 52 (22), 12872-12874. DOI: 10.1021/ic402357u PMCID: PMC3882273
  4. Peterson, R. L.; Ginsbach, J. W.; Cowley, R. E.; Qayyum, M. F.; Himes, R. A.; Siegler, M. A.; Moore, C. D.; Hedman, B.; Hodgson, K. O.; Fukuzumi, S.; Solomon, E. I.; Karlin, K. D., Stepwise Protonation and Electron-Transfer Reduction of a Primary Copper–Dioxygen Adduct. J. Am. Chem. Soc. 2013, 135, 16454-16467. DOI: 10.1021/ja405739m PMCID: PMC3877574.
  5. Sharma, Vivek; Karlin, Kenneth D.; Wikström, Marten “Computational Study of the Activated OH State in the Catalytic Mechanism of Cytochrome c Oxidase Proc. Nat. Acad. Sci. 2013, 110, 16844-16849. doi:  10.1073/pnas.1220379110 PMCID: PMC3801011
  6. Garcia-Bosch, I.; Sharma, S. K.; Karlin, K. D., A Selective Stepwise Heme Oxygenase Model System: An Iron(IV)-Oxo Porphyrin Pi-Cation Radical Leads to a Verdoheme-Type Compound via an Isoporphyrin Intermediate. J. Am. Chem. Soc. 2013, 135 (44), 16248-16251. DOI: 10.1021/ja405739m PMCID: PMC3877574
  7. Yokoyama, A.; Cho, K.-B.; Karlin, K. D.; Nam, W., Reactions of a Chromium(III)-Superoxo Complex and Nitric Oxide That Lead to the Formation of Chromium(IV)-Oxo and Chromium(III)-Nitrito Complexes. J. Am. Chem. Soc. 2013, 135 (40), 14900-14903.doi:  10.1021/ja405891n PMCID: PMC3864658
  8. Peterson, R. L.; Kim, S.; Karlin, K. D., 3.07 – Copper Enzymes. In Comprehensive Inorganic Chemistry II (Second Edition), Reedijk, J.; Poeppelmeier, K., Eds. Oxford: Elsevier: Amsterdam, 2013; Volume 3, “Bioinorganic Fundamentals and Applications: Metals in Natural Living Systems.; Pecoraro, Vincent L., Hambley, Trevor; Volume Eds. Chapter 3.09, pp 149-177. http://dx.doi.org/10.1016/B978-0-08-097774-4.00309-0; http://www.sciencedirect.com/science/article/pii/B9780080977744003090 (Does not fall under the Public Access Policy)
  9. Li, Yuqi; Sharma, Savita K.; Karlin, Kenneth D. “New heme-dioxygen and carbon monoxide adducts using pyridyl or imidazolyl tailed porphyrins”, Polyhedron 2013, 58, 190-196.doi:  10.1016/j.poly.2012.11.011 PMCID: PMC3818803
  10. Kakuda, Saya; Peterson, Ryan L.; Ohkubo, Kei; Karlin, Kenneth D.; Fukuzumi, Shunichi “Enhanced Catalytic Four-Electron Dioxygen (O2) and Two-Electron Hydrogen Peroxide (H2O2) Reduction with a Copper(II) Complex Possessing a Pendant Ligand Pivalamido Group”, J. Am. Chem. Soc., 2013, 135, 6513-6522. doi:  10.1021/ja3125977 PMCID: PMC3682076
  11. Das, Dipanwita, Lee, Yong-Min; Ohkubo, Kei; Nam, Wonwoo; Karlin, Kenneth D.; Fukuzumi, Shunichi, “Acid-Induced Mechanism Change and Overpotential Decrease in Dioxygen Reduction Catalysis with a Dinuclear Copper Complex” J. Am. Chem. Soc., 2013, 135, 4018-4026. NIHMSID #450792, doi:  10.1021/ja312256u PMCID: PMC3596431
  12. Das, Dipanwita, Lee, Yong-Min; Ohkubo, Kei; Nam, Wonwoo; Karlin, Kenneth D.; Fukuzumi, Shunichi, ” Temperature-Independent Catalytic Two-Electron Reduction of Dioxygen by Ferrocenes with a Copper(II) Tris[2-(2-pyridyl)ethyl]amine Catalyst in the Presence of Perchloric AcidJ. Am. Chem. Soc., 2013, 135, 2825-2834. NIHMSID #444622,  doi:  10.1021/ja312523u PMCID: PMC3596002
  13. Fukuzumi, Shunichi and Karlin, Kenneth D. “Kinetics and thermodynamics of formation and electron-transfer reactions of Cu–O2 and Cu2–O2 complexes.” Coord. Chem. Rev. 2013, 257, 187-195. doi:  10.1016/j.ccr.2012.05.031 PMCID: PMC3587051