2017 Publications

  1. Adam, Suzanne, “Critical Aspects of Heme­–Peroxo–Cu Complex Structure and Nature of Proton Source Dictate Metal–Operoxo Breakage versus Reductive O–O Cleavage Chemistry”, J. Am. Chem. Soc. 2017, 139, 472−481.   DOI: 10.1021/jacs.6b11322       PubMed #  28029788 NIHMSID 844374.
  2. Quist, David A.; Diaz, Daniel E.; Liu, Jeffrey J.; Karlin, Kenneth D. “Activation of dioxygen by copper metalloproteins and insights from model complexes J. Biol. Inorg. Chem. (JBIC)201722, 253-288.  DOI: 10.1007/s00775-016-1415-2.  PMCID: PMC5600896
  3. Garcia-Bosch, Isaac; Cowley, Ryan E.; Diaz, Daniel E.; Peterson, Ryan L.; Solomon, Edward I.; Karlin, Kenneth D. “Substrate and Lewis Acid Coordination Promote O−O Bond Cleavage of an Unreactive L2CuII2(O22–)2Species to Form Cores L2CuIII2(O)2with Enhanced Oxidative Reactivity.” J. Am. Chem. Soc. 2017139, 3186−3195. DOI: 10.1021/jacs.6b12990. PMCID: PMC5532877.
  4. Schaefer, Andrew W.; Kieber-Emmons, Matthew T.; Adam, Suzanne M.; Karlin, Kenneth D.; Solomon, Edward I., “Phenol-Induced O−O Bond Cleavage in a Low-Spin Heme−Peroxo−Copper Complex: Implications for O2Reduction in Heme−Copper Oxidases”,J. Am. Chem. Soc. 2017139, 7958-7973.  DOI: 10.1021/jacs.7b03292.  PMCID: PMC5605297.
  5. Wijeratne, Gayan, B.; Hematian, Shabnam; Siegler, Maxime A.: Karlin, Kenneth D., “Copper(I) / NO(g)Reductive Coupling Producing atrans-Hyponitrite Bridged Dicopper(II) Complex – Redox Reversal Giving Copper(I) / NO(g) Disproportionation”., J. Am. Chem. Soc. 2017139, 13276-13279. DOI: 10.1021/jacs.7b07808 PMCID: PMC5630263
  6. Sharma, Savita K.; Schaefer, Andrew W.; Lim, Hyeongtaek; Matsumura, Hirotoshi; Moënne-Loccoz, Pierre; Hedman, Britt; Hodgson, Keith O.; Solomon, Edward I.; Karlin, Kenneth D. “A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex—The Product of the Reaction of Nitrogen Monoxide (·NO(g)) with a Ferric-Superoxide Species”J. Am. Chem. Soc.2017139, 17421-17430. DOI: 10.1021/jacs.7b08468. PMCID: PMC5783694
  7. López, Isidoro; Cao, Rui, Quist, David A.; Karlin, Kenneth D; Le Poul, Nicolas, “Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach”Chem. Eur. J.201723, 18314-18319. DOI: 10.1002/chem.201705066.  PMCID:PMC578369