Kenneth D. Karlin Research Group > Publications > 1995-1991

1995-1991

  • Lee, D.-H.; Wei, N.; Murthy, N. N.; Tyeklár, Z.; Karlin, K. D.; Kaderli, S.; Jung, B.; Zuberbühler, A. D. “Reversible O2-Binding to a Dinuclear Copper(I) Complex with Linked TMPA {tris(2-pyridylmethyl)amine} Units:  Kinetic-Thermodynamic Comparisons with Mononuclear Analogues” J. Am. Chem. Soc., 1995, 117, 12498-12513.
  • Sanyal, I.; Karlin, K. D. “Metalloproteins and Dioxygen Metabolism” In Handbook of Metal-Ligand Interactions in Biological Fluids: Bioinorganic Chemistry, Vol. 1, G. Berthon, Ed., Marcel Dekker: New York, Part Two, Chapter 1, Section B14, pp. 284-294, 1995.
  • Reedy, B. J.; Murthy, N. N.; Karlin, K. D.; Blackburn, N. J. “Isocyanides as Ligand-Directed Indicators of Cu(I) Coordination in Copper Proteins.  Probing the Inequivalence of the Cu(I) Centers in Reduced Dopamine-b-monooxygenase” J. Am. Chem. Soc., 1995, 117, 9826-9831.
  • Fox, S.; Karlin, K. D. “Dioxygen Reactivity in Copper Proteins and Complexes” In Reactive Oxygen in Biochemistry, Valentine, J. S.; Foote, C. S.; Greenberg, A.; Liebman, J. F., Eds., Blackie Academic & Professional, Chapman & Hall:  Glasgow, 1995, Chapter 4, pp.188-231.
  • Murthy, N. N.; Karlin, K. D., “Biomimetic Copper-Dioxygen Chemistry: Reversible O2-Binding and Mechanistic Insights into Cu(I)/O2 Mediatedw1 Arene Hydroxylation and Amide Hydrolysis”, In Mechanistic Bioinorganic Chemistry, “Advances in Chemistry Series, Volume 246, H. H. Thorp, V. L. Pecoraro, Eds., American Chemical Society, Washington, D. C., pp. 165-193, 1995.
  • Sanyal, I.; Ghosh, P.; Karlin, K. D. “Mononuclear Copper(II)-Acylperoxo Complexes”. Inorg. Chem. 1995, 34, 3050-3056.
  • Nanthakumar, A..; Fox, S.; Karlin, K. D. “Copper-Dioxygen Reactivity Involved in the Formation of m-oxo [[(P)FeIII-O-CuII(L)]+ Heterodinuclear Complexes (P = porphyrinate, L = tetradentate ligand), and Novel Synthesis of Square Planar (P)-FeII Species”, J. Chem. Soc., Chem. Commun., 1995, 499-501.
  • Karlin, K. D.; Fox., S.; Nanthakumar, A.; Murthy, N. N.; Wei, N.; Obias, H. V.; Martens, C. F. “Copper-Dioxygen Chemistry and Modeling the Fe-Cu Center in Cytochrome c Oxidase”, Pure Appl. Chem., 1995, 67, 289-296.
  • Wei, N.; Murthy, N. N.; Karlin, K. D. “Chemistry of Pentacoordinated [LCuII-Cl]+ Complexes with Quinolyl Containing Tripodal Tetradentate Ligands L”, Inorg. Chem., 1994, 33, 6093-6100.
  • Wei, N.; Lee, D.-H.; Murthy, N. N.; Tyeklár, Z.; Karlin, K. D.; Kaderli, S.; Jung, B.; Zuberbühler, A. D. “Kinetic Preference without Thermodynamic Stabilization in the Intra- vs Intermolecular Formation of Copper-Dioxygen Complexes”, Inorg. Chem., 1994, 33, 4625-4626.
  • Karlin, K. D.; Nanthakumar, A.; Fox, S.; Murthy, N. N.; Ravi, N.; Huynh, B. H.; Orosz, R. D.; Day, E. P. “X-ray Structure and Physical Properties of the Oxo-Bridged Complex [(F8-TPP)Fe-O-Cu(TMPA)]+, F8-TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-), TMPA = tris(2-pyridylmethyl)amine: Modeling the Cytochrome c Oxidase Fe-Cu Heterodinuclear Active Site.”, J. Am. Chem. Soc., 1994, 116, 4753-4763.
  • Conry, R. R.; Karlin, K. D. “Dioxygen & Related Ligands”, Encyclopedia of Inorganic Chemistry, R. B. King, Ed.-in-Chief; R. H. Crabtree, Sect. Ed., John Wiley & Sons: New York, pp 1036-1040, 1994.
  • Conry, R. R.; Karlin, K. D. “Copper: Inorganic and Coordination Chemistry”, Encyclopedia of Inorganic Chemistry, R. B. King, Ed.-in-Chief; R. H. Crabtree, Sect. Ed., John Wiley & Sons:  New York, pp 829-840, 1994.
  • Wei, N.; Murthy, N. N.; Chen, Q.; Zubieta, J.; Karlin, K. D. “Copper(I)/Dioxygen Reactivity of Mononuclear Complexes with Pyridyl and Quinolyl Tripodal Tetradentate Ligands: Reversible Formation of Cu:O2 = 1:1 and 2:1 Adducts”, Inorg. Chem. 1994, 33, 1953-1965.
  • Wei, N.; Murthy, N. N.; Tyeklár, Z.; Karlin, K. D. “Copper(I) Complexes with Pyridyl and Imidazolyl Contanining Tripodal Tetradentate Ligands, and Their Reactions with Dioxygen”, Inorg. Chem. 1994, 33, 1177-1183.
  • Karlin, K. D.; Nasir, M. S.; Cohen, B. I.; Cruse, R. W.; Kaderli, S.; Zuberbühler, A. D. “Reversible Dioxygen Binding and Aromatic Hydroxylation in O2-Reactions with Substituted Xylyl Dinuclear Copper(I) Complexes: Syntheses, Low-Temperature Kinetic/Thermodynamic and Spectroscopic Investigations of a Copper Monooxygenase Model System.” J. Am. Chem. Soc., 1994, 116, 1324-1336.
  • Karlin, K. D.; Tyeklár, Z. “Functional Biomimics for Copper Proteins Involved in Reversible O2-Binding, Substrate Oxidation/Oxygenation and Nitrite Reduction”, Advances in Inorganic Biochemistry, 1994, 9, 123-172.
  • Sanyal, I.; Karlin, K. D.; Strange, R. W.; Blackburn, N. J. “Chemistry & Structural Studies on the Dioxygen-Binding Copper-1,2-Dimethylimidazole System”, J. Am. Chem. Soc., 1993, 115, 11259-11270.
  • Fox, S.; Nanthakumar, A.; Wei, N.; Murthy, N. N.; Karlin, K. D. “Investigations of Dioxygen Reactivity with Synthetic Models of the Metalloproteins Hemocyanin and Cytochrome c Oxidase”, Pure Appl. Chem., 1993, 65, 2335-2342.
  • Sanyal, I.; Murthy, N. N.; Karlin, K. D., “A Dicopper(I) Complex and Its Oxygenation Chemistry Using a Dinucleating Ligand with Pendant Alkene Group”, Inorg. Chem. 1993, 32, 5330-5337.
  • Nanthakumar, A.; Fox., S.; Nasir, S. M.; Ravi, N.; Huynh, B. H.; Orosz, R. D.; Day, E. P.; Hagen, K. S.; Karlin, K. D., “Dioxygen Reactivity Models for Cytochrome c Oxidase: Synthesis and Characterization of Oxo and Hydroxo-Bridged Porphyrin-Iron/Copper Dinuclear Complexes”, In The Activation of Dioxygen and Homogeneous Catalytic Oxidation, D. H. R. Barton, A. E. Martell and D. T. Sawyer, Eds. Plenum Press:  New York, 1993, pp 381-394.
  • Murthy, N. N.; Mahroof-Tahir, M.; Karlin, K. D., “Facile Amide Hydrolysis Effected by Dinuclear Copper Complexes”, to J. Am. Chem. Soc., 1993, 115, 10404-10405.
  • Karlin, K. D.; Wei, N.; Jung, B.; Kaderli, S.; Niklaus, P.; Zuberbühler, A. D. “Kinetics and Thermodynamics of Formation of Copper-Dioxygen Adducts: Oxygenation of Mononuclear Copper(I) Complexes Containing Tripodal Tetradentate Ligands”, J. Am. Chem. Soc., 1993, 115, 9506-9514.
  • Nanthakumar, A.; Fox., S.; Murthy, N. N.; Karlin, K. D.; Ravi, N.; Huynh, B. H.; Orosz, R. D.; Day, E. P.; Hagen, K. S.; Blackburn, N. J. “Oxo and Hydroxo-Bridged (Porphyrin)Iron(III)-Copper(II) Species as Cytochrome c Oxidase Models: Acid-Base Interconversions and X-ray Structure of the Fe(III)-(O2–)-Cu(II) Complex”, J. Am. Chem. Soc., 1993, 115, 8513-8514.
  • Gultneh, Y.; Farooq, A.; Karlin, K. D.; Liu, Shuncheng; Zubieta, J. “Structure and Reactions of an Eight-Coordinate Mn(II) Complex: [Mn(TMPA)2](ClO4)2 (TMPA = tris[(2-pyridyl)methyl]amine”, Inorg. Chim. Acta, 1993, 311, 171-175.
  • Karlin, K. D. “Metalloenzymes, Structural Motifs and Inorganic Models”, Science, 1993, 261, 701-708.
  • Murthy, N. N.; Karlin, K. D. “A Dinuclear Zinc Hydroxide Complex which Traps Atmospheric Carbon Dioxide: Formation of a Tri-zinc Complex with a Triply Bridging Carbonate Group”, J. C. S. Chem. Commun., 1993, 1236-1238.
  • Jiang, F.; Karlin, K. D.; Peisach, J. “An Electron Spin Echo Envelope Modulation (ESEEM) Study of Electron-Nuclear Hyperfine and Nuclear Quadrupole Interactions of dz2 Ground State Cu(II) Complexes with Substituted Imidazoles”, Inorg. Chem., 1993, 32, 2576-2582.
  • Mahroof-Tahir, M.; Karlin, K. D.; Chen, Qin; Zubieta J. “Phosphate Ester Coordination to Dicopper(II) Compounds; X-ray Structure of a Bis(4-nitrophenyl)phosphato Bridged Dicopper(II) Complex”, Inorg. Chim. Acta., 1993, 207, 135-138.
  • Martens, C. F.; Klein Gebbink, R. J. M.; Kenis, P. J. A.; Schenning, A. P. H. J.; Feiters, M. C.; Ward, J. L.; Karlin, K. D.; Nolte, R. J. M., In Bioinorganic Chemistry of Copper, Karlin, K. D., Tyeklár, Z., Eds., Chapman & Hall:  New York, 1993, pp. 374-381.
  • Tyeklár, Z.; Karlin, K. D., “Functional Models for Hemocyanin and Copper Monooxygenases”, In Bioinorganic Chemistry of Copper, Karlin, K. D., Tyeklár, Z., Eds., Chapman & Hall:  New York, 1993, pp. 277-291.
  • Tyeklár, Z.; Jacobson, R. R.; Wei, N.; Murthy, N. N.; Zubieta, J.; Karlin, K. D. “Reversible Reaction of O2 (and CO) with a Copper(I) Complex: X-ray Structures of Relevant Mononuclear Cu(I) Precursor Adducts and the trans-m-1,2-Peroxo-Dicopper(II) Product”, J. Am. Chem. Soc. 1993, 115, 2677-2689.
  • Jiang, F.; Conry, R. R.; Bubacco, L.; Tyeklár, Z.; Jacobson, R. R.; Karlin, K. D.; Peisach, J. “Crystal Structure and Electron Spin Echo Envelope Modulation Study of [Cu(II)(TEPA)(NO2)]PF6 (TEPA = tris-[2-(2-pyridyl)ethyl]amine):  A Potential Model for the Nitrite Derivative of Hemocyanin”, J. Am. Chem. Soc. 1993, 115, 2093-2102.
  • Nasir, M. S.; Jacobson, R. R.; Zubieta, J.; Karlin, K. D. “Pyridine Ligand Donor Substituent Effects Upon Structure, Redox Properties and O2-Reactivity of Xylyl Dinuclear Copper(I) Complexes”, Inorg. Chim. Acta, 1993, 203, 5-7.
  • Karlin, K. D.; Tyeklár, Z.; Zuberbühler, A. D. “Formation, Structure and Reactivity of Copper Dioxygen Complexes” In Bioinorganic Catalysis (Reedijk, J., Ed.), Marcel Dekker:  New York 1993, Chapter 9, pp 261-315.
  • Sanyal, I.; Mahroof-Tahir, M.; Nasir, M. S.; Ghosh, P.; Cohen, B. I.; Gultneh, Y.; Cruse, R. W.; Farooq, A.; Karlin, K. D.; Liu, S.; Zubieta, J. “Reactions of Dioxygen (O2) with Mononuclear Copper(I) Complexes: Temperature-Dependent Formation of Peroxo- or Oxo- (and Dihydroxo-) Bridged Dicopper(II) Complexes”  Inorg. Chem. 1992, 31, 4322-4332.
  • Mahroof-Tahir, M.; Karlin, K. D. “A Dinuclear Mixed-Valence Cu(I)/Cu(II) Complex and Its Reversible Reaction with O2: Generation of A Superoxo-Dicopper(II) Species”, J. Am. Chem. Soc. 1992, 114, 7599-7601.
  • Gultneh, Y.; Farooq, A.; Liu, Shuensheng; Karlin, K. D.; Zubieta, J. “Synthesis, Structure and Characterization of a Phenolate-Bridged Dimanganese(II) Complex of a Dinucleating Phenol Ligand”, Inorg. Chem., 1992, 31, 3607-3611.
  • Nanthakumar, A.; Nasir, M. S.; Karlin, K. D.; Ravi, N.; Huynh, B.H. “A Cytochrome c Oxidase Reactivity Model: Generation of a Peroxo-Bridged Iron/Copper Dinuclear Complex”, J. Am. Chem. Soc. 1992, 114, 6564-6566.
  • Mahroof-Tahir, M.; Murthy, N. N.; Karlin, K. D.; Blackburn, N. J.; Shaikh, S. N.; Zubieta, J. “New Thermally Stable Hydroperoxo and Peroxo Copper Complexes”, Inorg. Chem., 1992, 31, 3001-3003.
  • Ling, J.; Farooq, A.; Karlin, K. D.; Loehr, T. M.; Sanders-Loehr, J. “Vibrational Spectroscopic Studies of a Hydroxo-Bridged Dinuclear Copper Complex, a Potential Model for Multi-Copper Proteins”, Inorg. Chem., 1992, 31, 2552-2556.
  • Nasir, M. S.; Karlin, K. D.; Chen, Q.; Zubieta, J. “Copper(I) and Copper(II) Complexes of New Chelating Pterins”, J. Am. Chem. Soc., 1992, 114, 2264-2265.
  • Karlin, K. D.; Tyekár, Z.; Farooq, A.; Haka, M. S.; Ghosh, P.; Cruse, R. W.; Gultneh, Y.; Hayes, J. C.; Zubieta, J. “Functional Modeling of Hemocyanins. Reversible Binding of O2 and CO to Dicopper(I) Complexes [Cu(I)2(L)]2+ (L = Dinucleating Ligand) and the Structure of a Bis(Carbonyl) Adduct, [Cu(I)2(L)(CO)2]2+,” Inorg. Chem., 1992, 31, 1436-1451.
  • Nasir, M. S.; Cohen, B. I.; Karlin, K. D. “Mechanism of Aromatic Hydroxylation in a Copper Monooxygenase Model System. The NIH Shift in Copper Chemistry”,  J. Am. Chem. Soc.,  1992, 114, 2482-2494.
  • Baldwin, M. J.; Ross, P. K.; Pate, J. E.; Tyeklár, Z.; Karlin, K. D.; Solomon, E. I. “Spectroscopic and Theoretical Studies of an End-On Peroxide-Bridged Coupled Binuclear Copper(II) Model Complex of Relevance to the Active Sites of Hemocyanin and Tyrosinase” J. Am. Chem. Soc.,  1991, 113, 8671-8679.
  • Paul, P. P.; Karlin, K. D., “Functional Modeling of Copper Nitrite Reductases: Reactions of NO2– or NO with Copper(I) Complexes”,  J. Am. Chem. Soc.,  1991, 113, 6331-6332.
  • Karlin, K. D.; Wei, N.; Jung, B.; Kaderli, S.; Zuberbühler, A. D. ,”Kinetic, Thermodynamic and Spectral Characterization of the Primary Cu-O2 Adduct in a Reversibly Formed and Structurally Characterized Peroxo-Dicopper(II) Complex”, J. Am. Chem. Soc., 1991, 113, 5868-5870.
  • Paul, P. P.; Tyeklár, Z.; Jacobson, R. R.; Karlin, K. D., “Reactivity Patterns and Comparisons in Three Classes of Synthetic Copper-Dioxygen {Cu2-O2} Complexes: Implication for Structure and Biological Relevance”, J. Am. Chem. Soc.,  1991, 113, 5322-5332.
  • Sanyal, I.; Strange, R. R.; Blackburn, N. J.; Karlin, K. D., “Formation of a Copper-Dioxygen Complex (Cu2-O2) Using Simple Imidazole Ligands”, J. Am. Chem. Soc. 1991, 113, 4692-4693.  [Highlighted in “Chemical & Engineering News”, June 17, 1991.]
  • Tyeklár, Z.; Karlin, K. D “Biomimetic Binding and Activation of Dioxygen with Copper Complexes”, In Dioxygen Activation and Homogeneous Catalytic Oxidation, L. I. Simándi, Ed., Elsevier: Amsterdam, 1991, pp. 237-248.
  • Karlin, K. D.; Tyeklár, Z.; Farooq, A.; Jacobson, R. R.; Sinn, E.; Lee, D. W.; Bradshaw, J. E.; Wilson, L. J. “Peroxide (O22-) as a Bridging Ligand for Copper(II): Strong Exchange Coupling in Complexes Drived from Copper(I) and Dioxygen”, Inorg. Chim. Acta, 1991, 182, 1-3.
  • Jacobson, R. R.; Tyeklár, Z.; Karlin, K. D.; Zubieta, J. “Fluoride as a Terminal and Bridging Ligand for Copper: Isolation and X-ray Crystallographic Characterization of Monomeric and Dimeric Complexes [CuII(TMPA)F]nn+ (n = 1, or 2; TMPA = Tris[(2-pyridyl)methyl]amine), Inorg. Chem., 1991, 30, 2035-2040.
  • Jacobson, R. R.; Tyeklár, Z.; Karlin, K. D, “Reaction of Organic Halides with [CuI(TMPA)(CH3CN)]PF6“, Inorg. Chim. Acta, 1991, 181, 111-118.
  • Nasir, M. S.; Karlin, K. D.; McGowty, D.; Zubieta, J. “Unsymmetrical Dicopper Complexes. Direct Observation of Reversible O2-Binding in a Copper Monooxygenase Model System.” J. Am. Chem. Soc.  1991, 113, 698-700.