Kenneth D. Karlin Research Group > 2009-10 Publications

2009-10 Publications

  1. Lee, Y.; Park, G. Y.; Lucas, H. R.; Vajda, P. L.; Kamaraj, K.; Vance, M. A.; Milligan, A. E.; Woertink, J. S.; Siegler, M. A.; Narducci Sarjeant, A. A.; Zakharov, L. N.; Rheingold, A. L.; Solomon, E. I.; Karlin, K. D. “Copper(I)/O2 Chemistry with Imidazole Containing Tripodal Tetradentate Ligands Leading to m-1,2-Peroxo–Dicopper(II) Species” Inorg. Chem. 2009, 48, 11297-11309. PMCID2787896.
  2. Himes, R. A.; Karlin, K. D. “A New Copper-Oxo Player in Methane Oxidation”, Proc. Nat. Acad. Sci. 2009, 106, 18877-18878. PMCID: PMC2776413.     (Invited Commentary).
  3. Park, G. Y.; Deepalatha, S.; Puiu, S. C.; Lee, D.-H.; Mondal, B.; Narducci Sarjeant, A. A.; del Rio, D.; Pau, M. Y. M.; Solomon, E. I.; Karlin, K. D. “A peroxynitrite complex of copper: formation from a copper–nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration”, J. Biol. Inorg. Chem. 2009, 14, 1301-1311. PMCID: PMC2908284
  4. Lucas, Heather R.; Meyer, Gerald, J.; Karlin, Kenneth D. “Carbon Monoxide and Nitrogen Monoxide Ligand Dynamics in Synthetic Heme and Heme–Copper Complex Systems”, J. Am. Chem. Soc., 2009, 131, 13924-13925. PMCID2771263
  5. Maiti, D.; Woertink, J. S.; Ghiladi, R. A.; Solomon, E. I.; Karlin, K. D. “Molecular Oxygen and Sulfur Reactivity of a Cyclotriveratrylene Derived Trinuclear Copper(I) Complex”, Inorg. Chem. 2009, 48, 8342-8356. PMCID: PMC2917907
  6. Schopfer, M. P.; Mondal, B.; Lee, D.-H.; Sarjeant, A. A. N.; Karlin, K. D. “Heme/O2/•NO Nitric Oxide Dioxygenase (NOD) Reactivity: Phenolic Nitration via a Putative Heme-Peroxynitrite Intermediate”, J. Am. Chem. Soc. 2009, 131, 11304-11305. PMCID: PMC2747244
  7. Himes, R. A.; Karlin, K. D. “Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO)”, Curr. Opin. Chem. Biol. 2009, 13, 119-131. PMCID: PMC2676220.
  8. Lucas, H. R.; Li, L.; Sarjeant, A. A. N.; Vance, M. A.; Solomon, E. I.; Karlin, K. D. “Toluene and Ethylbenzene Aliphatic C–H Bond Oxidations Initiated by a Dicopper(II)- m-1,2-Peroxo Complex”, J. Am. Chem. Soc. 2009, 131, 3230-3245. PMCID: PMC2765497
  9. Lucas, Heather R.; Karlin, Kenneth D. “Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site” Met. Ions Life Sci. 2009, 6, 295–361. Book Series article/chapter. (Does not fall under the Public Access Policy)
  10. Wang, Jun; Schopfer, Mark P.; Sarjeant, Amy A. N.; Karlin, Kenneth D. “Heme-Copper Assembly Mediated Reductive Coupling of Nitrogen Monoxide (•NO)”, J. Am. Chem. Soc. 2009, 131, 450-451. PMCID: PMC2662328
  11. Park, G. Y., Lee, D.-H. & Karlin, K. D. in Encyclopedia of Catalysis (ed Istvan Horvath)  Published Online: 15 SEP 2010. DOI: 2010.1002/0471227617.eoc0471227064.pub0471227612 (John Wiley & Sons, Inc., 2010). (Does not fall under the Public Access Policy)
  12. Woertink, Julia S.; Tian, Lu.; Maiti, Debabrata ; Lucas, Heather R.; Himes, Richard A.; Karlin, Kenneth D.; Neese, Frank; Würtele, Christian; Holthausen, Max C.; Bill, Eckhard; Sundermeyer, Jörg; Schindler, Siegfried; Solomon, Edward. I. “Spectroscopic and Computational Studies of an End-on Bound Superoxo-Cu(II) Complex: Geometric and Electronic Factors that Determine the Ground State” Inorg. Chem. 2010, 49, 9450-9459. PMCID: PMC2963092.
  13. Himes, R., Barnese, K. & Karlin, K. D. “One is Lonely and Three is a Crowd: Two Coppers Are for Methane Oxidation” Angew. Chem. Int. Ed. 2010, 49, 6714-6716. (Does not fall under the Public Access Policy)
  14. Karlin, Kenneth D. “Bioinorganic chemistry: Redox control of oxoiron(IV)”. Nature Chemistry 2010, 2, 711-712. (Does not fall under the Public Access Policy)
  15. Lee, Y.; Lee, D.-H.; Park, G. Y.; Lucas, H. R.; Narducci Sarjeant, A. A.; Kieber-Emmons, M. T.; Vance, M. A.; Milligan, A. E.; Solomon, E. I.; Karlin, K. D. “Sulfur Donor Atom Effects on Copper(I)/O2 Chemistry with Thioanisole Containing Tetradentate N3S Ligand Leading to m-1,2-Peroxo-Dicopper(II) Species” Inorg. Chem. 2010, 49, 8873-8885. PMCID: PMC2949281
  16. Heather R. Lucas, Gerald J. Meyer and Kenneth D. Karlin “CO and O2 Binding to Pseudo-tetradentate Ligand−Copper(I) Complexes with a Variable N-Donor Moiety: Kinetic/Thermodynamic Investigation Reveals Ligand-Induced Changes in Reaction Mechanism” J. Am. Chem. Soc. 2010, 132, 12927-12940. PMCID: PMC2952189.
  17. Schopfer, Mark P. Wang, Jun; Karlin, Kenneth D. “Bioinspired Heme, Heme/Nonheme Diiron, Heme/Copper, and Inorganic NOx Chemistry: •NO(g) Oxidation, Peroxynitrite–Metal Chemistry, and •NO(g) Reductive Coupling” Inorg. Chem. 2010, 49, 6267-6282. PMCID: PMC2920632.
  18. Fukuzumi S, Kotani H, Lucas Heather R., Doi K, Suenobu T, Peterson Ryan L., Karlin Kenneth D. “Mononuclear Copper Complex-Catalyzed Four-Electron Reduction of Oxygen” J. Am. Chem. Soc. 2010, 132, 6874-6875. PMCID: PMC2886287
  19. Halime, Z.; Kieber-Emmons, M. T.; Qayyum, M. F.; Mondal, B.; Gandhi, T.; Puiu, S. C.; Chufán, E. E.; Sarjeant, A. A. N.; Hodgson, K. O.; Hedman, B.; Solomon, E. I.; Karlin, K. D. Heme-Copper/Dioxygen Complexes: Towards Understanding Ligand-Environmental Effects on Coordination Geometry, Electronic Structure and Reactivity Inorg. Chem. 2010, 49, 3629-3645. (PMCID: PMC2893725).
  20. Wang, J.: Schopfer, M. P.; Puiu, S. C.; Sarjeant, A. A. N.; Karlin, K. D. Reductive Coupling of Nitrogen Monoxide (•NO) Facilitated by Heme/Copper Complexes, Inorg. Chem. 2010 49, 1404-1419. (PMCID: PMC2830618)
  21. Karlin, K. D. “Bioinorganic Chemistry: Model Offers Intermediate Insight” Nature 2010, 463, 168-169. PMID20024303 (Invited News & Views article in Nature magazine) (Does not fall under the Public Access Policy)
  22. Park, G. Y.; Lee, Y.; Lee, D.-H.; Woertink, J. S.; Sarjeant, A. A. N.; Solomon, E. I.; Karlin, K. D. “Thioether S-ligation in a side-on m:h2:h2-peroxodicopper(II) complex” Chem. Commun. 2010, 46, 91-93. PMCID: PMC2908150