Kenneth D. Karlin Research Group > 2007-08 Publications

2007-08 Publications

  1. Yunho Lee, Dong-Heon Lee, Amy A. Narducci Sarjeant, Kenneth D. Karlin, “Thiol-copper(I) and disulfide–dicopper(I) complex O2-reactivity leading to sulfonate–copper(II) complex or the formation of a cross-linked thioether–phenol product with phenol addition” J. Inorg. Biochem. 2007, 101, 1845-1858. PMID: 17651805.            Special issue J. Inorg. Biochem. in honor of the memory of Edward I. Stiefel.
  2. Maiti, D.; Woertink, Julia S.; Vance, Michael A.; Milligan, Ashley E.; Narducci Sarjeant, Amy A.; Solomon, Edward I.; Karlin, Kenneth D. “Copper(I)/S8 Reversible Reactions Leading to an End-On Bound Dicopper(II) Disulfide Complex: Nucleophilic Reactivity and Analogies to Copper-Dioxygen Chemistry” J. Am. Chem. Soc. 2007, 129, 8882-8892. PMID: 17592845.
  3. Chufán, E. E.; Mondal, B.; Gandhi, T.; Kim, E.; Rubie, N. D.; Moënne-Loccoz, P.; Karlin, K. D. “Reactivity Studies on FeIII–(O22–)–CuII Compounds: Influence of the Ligand Architecture and Copper Ligand Denticity”, Inorg. Chem. 2007, 46, 6482-6394. PMID: 17616124.
  4. Lee, D.-H.; Hatcher, L. Q.; Vance, M. A.; Sarangi, R.; Milligan, A. E.; Narducci Sarjeant, A. A. Incarvito, C. D.; Rheingold, A. L.; Hodgson, K. O.; Hedman, B.; Solomon, E. I.; Karlin, K. D., “Copper(I) Complex O2-Reactivity with a N3S Thioether Ligand: a Copper-Dioxygen Adduct Including Sulfur Ligation, Ligand Oxygenation, and Comparisons with All Nitrogen Ligand Analogues”, Inorg. Chem. 2007, 46, 6056-6068. PMID: 17580938.
  5. Chufán, E. E.; Puiu, S. C.; Karlin, K. D. “Heme–Copper/Dioxygen Adduct Formation, Properties, and Reactivity”, Acc. Chem. Res. 2007, 40, 563–572. PMID: 17550225.
  6. Maiti, D.; Lucas, H. R.; Sarjeant, A. A. N.; Karlin, K. D. “Aryl Hydroxylation from a Mononuclear Copper-Hydroperoxo Species”, J. Am. Chem. Soc. 2007, 129, 6998-6999. PMID: 17497785.
  7. Ghiladi, R. A.; Chufán, E. E.; del Rio, D.; Solomon, E. I.; Krebs, C.; Huynh, B. H.; Huang, H.-w.; Moënne-Loccoz, P.; Kaderli, S.; Honecker, M.; Zuberbühler, A. D.; Marzilli, L.; Cotter, R. J.; Karlin, K. D. “Further Insights into the Spectroscopic, Electronic Structure, and Kinetics of Formation of the Heme-Peroxo-Copper Complex [(F8TPP)FeIII–(O22–)–CuII(TMPA)]+“, Inorg. Chem. 2007, 46, 3889-3902. PMID: 17444630.
  8. Maiti, Debabrata; Narducci Sarjeant, Amy A.; Karlin, Kenneth D., “Copper(II)-Hydroperoxo Complex Induced Oxidative N-Dealkylation Chemistry” J. Am. Chem. Soc., 2007, 129, 6720-6721. PMID: 17474748.
  9. Chufán, E. E.; Verani, C. N.; Puiu, S. C.; Rentschler, E.; Schatzschneider, U.; Incarvito, C.; Rheingold, A. L.; Karlin, K. D. “Generation and Characterization of [(P)M-(X)-Co(TMPA)]n+ Assemblies; P = Porphyrinate, M = FeIII and CoIII, X = O2-, OH–, O22-, and TMPA = Tris(2-pyridylmethyl)amine”, Inorg. Chem. 2007, 46, 3017-3026. PMID: 17371009.
  10. Himes, R. A.; Park, G. Y.; Barry, A. N.; Blackburn, N. J.; Karlin, K. D. ” Synthesis and X-ray Absorption Spectroscopy Structural Studies of Cu(I) Complexes of HistidylHistidine Peptides: The Predominance of Linear 2-Coordinate Geometry”, J. Am Chem. Soc. 2007, 129, 5352-5353.
  11. Lee, D.-H.; Murthy, N. N.; Karlin, K. D. “Copper-Dioxygen Reactivity Using Dinucleating Ligands with Activated Methylene or Ketone Function”, Bull. Chem. Soc. Jpn. 2007, 80, 732-742.
  12. Maiti, D.; Fry, H. C.; Woertink, J. S.; Vance, M. A.; Solomon, E. I.; Karlin, K. D., “A 1:1 Copper-Dioxygen Adduct is an End-on Bound Superoxo Copper(II) Complex which Undergoes Oxygenation Reactions with Phenols” J. Am. Chem. Soc., 2007, 129, 264-265.
  13. Lee, Yunho; Lee, Dong-Heon; Sarjeant, Amy A. N.; Zakharov, Lev N.; Rheingold, A. L.; Karlin, Kenneth D. “Thioether Sulfur Oxygenation from O2 or H2O2 Reactivity of Copper Complexes with Tridentate N2S(Thioether) Ligands”, Inorg. Chem. 2006, 45, 10098-10107.

269.  Himes, Richard A.; Park Ga Young; Siluvai, Gnana Sutha; Blackburn, Ninian J.; Karlin, Kenneth             “Structural Studies of Copper(I) Complexes of Amyloid-b Peptide Fragments: Formation of               Two-Coordinate Bis(histidine) Complexes, Angew. Chem. Int. Ed., 2008, 47, 9084-9087. PMCID =        PMC2662329

270.  Maiti, D.; Lee, Narducci Sarjeant, A. A.; Karlin, K. D., “Copper­–Hydroperoxo-Mediated                      N-Debenzylation Chemistry Mimicking Aspects of Copper Monooxygenases“, Inorg. Chem. 2008, 47, 8736-8747. PMCID: PMC271399

271.    Maiti, D.; Lee, D.-H.; Narducci Sarjeant, A. A.; Pau, M. Y.; Solomon, E. I.; Gaoutchenova, K.;            Sundermeyer, J.; Karlin, K. D., “Reaction of a Copper-Dioxygen Complex with Nitrogen Monoxide (•NO) Leads to a Copper(II)-Peroxynitrite Species“, J. Am. Chem. Soc. 2008, 130, 6700-6701. PMID: 18457392.

272.   Zhu, Q.; Lian, Y.; Thyagarajan, S.; Rokita, S. E.; Karlin, K. D. Karlin; Blough, N. V., “Hydrogen Peroxide and Dioxygen Activation by Dinuclear Copper Complexes in Aqueous Solution: Hydroxyl Radical Production Initiated by Internal Electron Transfer”, J. Am. Chem. Soc. 2008, 130, 6304-6305. PMID: 18433125.

273.   Maiti, D.; Narducci Sarjeant, A. A.; Itoh, S.; Karlin, K. D. “Suggestion of an Organometallic Intermediate in an Intramolecular Dechlorination Reaction Involving Copper(I) and a ArCH2Cl Moiety” J. Am. Chem. Soc. 2008, 130, 5644-5645. PMID: 18393421.

274.  Maiti, D.; Woertink, J. S.; Narducci Sarjeant, A. A.; Solomon, E. I.; Karlin, K. D. “Copper Dioxygen Adducts: Formation of bis(μ-oxo)dicopper(III) versus (m-1,2)peroxodicopper(II) Complexes with Small Changes in One Pyridyl-Ligand Substituent”  Inorg. Chem. 2008, 47, 3787-3800. PMID: 18396862.

275.  Fry, H. Christopher; Lucas, Heather R.; Zakharov, Lev N.; Rheingold, Arnold L.; Meyer, Gerald J.; Karlin, Kenneth D. “Intermolecular versus intramolecular electron-/atom- (Cl•) transfer in heme-iron and copper pyridylalkylamine complexes” Inorg. Chim. Acta, 2008, 361, 1100-1115.  Not listed on PubMed.    Contribution to a special issue of Inorg. Chim. Acta in honor of the career of Edward I. Solomon (Stanford Univ.).

276.  Sarangi, R.; York, J. T.; Helton, M. E.; Fujisawa, K.; Karlin, K. D.; Tolman, W. B.; Hodgson, K. O.; Hedman, B.; Solomon, E. I. “X-Ray Absorption Spectroscopic and Theoretical Studies on (L)2[Cu2(S2)n]2+ Complexes: Disulfide versus Disulfide(•1–) Bonding”, J. Am. Chem. Soc. 2008, 130, 676-686. PMCID: PMC2570853

277.  Fry, H. Christopher; Lucas, Heather R.; Narducci Sarjeant, Amy A.; Karlin, Kenneth D.; Meyer, Gerald J. “Carbon Monoxide Coordination and Reversible Photodissociation in Copper(I) Pyridylalkylamine Compounds” Inorg. Chem. 2008, 47, 241-256. PMID: 18052158.

278.  Maiti, D.; Lee, D.-H.; Gaoutchenova, K.; Würtele, C.; Holthausen, M. C.; Narducci Sarjeant, A. A.; Sundermeyer, J.; Schindler, S.; Karlin, K. D. “Reactions of a Copper(II) Superoxo Complex Lead to C–H and O–H Substrate Oxygenation: Modeling Copper-Monooxygenase C–H Hydroxylation”, Angew. Chem. Int. Ed., 2008, 47, 82-85. PMID: 18022887.