Kenneth D. Karlin Research Group > 2005-06 Publications

2005-06 Publications

  • Lee, Yunho; Lee, Dong-Heon; Sarjeant, Amy A. N.; Zakharov, Lev N.; Rheingold, A. L.; Karlin, Kenneth D. “Thioether Sulfur Oxygenation from O2 or H2O2 Reactivity of Copper Complexes with Tridentate N2S(Thioether) Ligands”, Inorg. Chem. 2006, 45, 10098-10107.
  • Hatcher, L. Q.; Lee, D.-H., Vance, M. A.; Milligan, A. E.; Sarangi, R. Hodgson, K. O.; Hedman, B.; Solomon, E. I.; Karlin, K. D. “Dioxygen Reactivity of a Copper(I) Complex with N3S Thioether Chelate; Peroxo-Dicopper(II) Formation Including Sulfur Ligation” Inorg. Chem. 2006, 45, 10055-10057.
  • Li, Lei; Sarjeant, Amy A. Narducci; Karlin, Kenneth D. “Reactivity Study of a Hydroperoxo-dicopper(II) Complex: Hydroxylation, Dehydrogenation and Ligand Crosslink Reactions”, Inorg. Chem. 2006, 45, 7160-7172.
  • Lee, D.-H.; Mondal, B.; Karlin, K. D. “NO and N2O Binding and Reduction” In Activation of Small Molecules: Organometallic and Bioinorganic Perspectives (Ed. Tolman, W. B.); Wiley-VCH, 2006, Ch. 2, pp. 43-79.
  • Lei Li, N. N. Murthy, Joshua Telser, Lev. N. Zakharov, Glenn P. A. Yap, Arnold L. Rheingold, Kenneth D. Karlin and Steven E. Rokita, “Targeted Guanine Oxidation by a Dinuclear Cu(II) Complex at Single Stranded/Double Stranded DNA Junctions”. Inorg. Chem. 2006, 45, 7144-7159.
  • Lee, Y.; Karlin, K. D. “Highlights of Copper Protein Active-Site Structure/Reactivity and Synthetic Model Studies”, in Concepts and Models in Bioinorganic Chemistry (Eds: Metzler-Nolte, N.; Kraatz, H.-B.), Wiley-VCH, 2006, 363-395.
  • Thyagarajan, S.; Murthy, N. N.; Sarjeant, A. A. N.; Karlin, K. D.; Rokita, S. E. “Selective DNA Strand Scission with Binuclear Copper Complexes: Implications for an Active Cu2-O2 Species”, J. Am. Chem. Soc., 2006, 128, 7003-7008. PMCID: PMC2556057)
  • Smirnov, V. V.; Brinkley, D. W.; Lanci, M. P.; Karlin, K. D.; Roth, J. P. “Probing Metal-Mediated O2 Activation in Chemical and Biological Systems”, J. Molec. Catal. A., 2006, 251, 100-107.
  • Sprakel, V. S. I.; Elemans, J. A. A. W.; Feiters, M. C. Lucchese, B.; Karlin, K. D.; Nolte, R. J. M. “Synthesis and Characterisation of PY2- and TPA-Appended Diphenylglycoluril Receptors and Their Bis-Cu(I) Complexes”, Eur. J. Org. Chem., 2006, 2281-2295.
  • Hatcher, L. Q.; Vance, M. A.; Sarjeant, A. N. N.; Solomon, E. I.; Karlin, K. D. “Copper-Dioxygen Adducts and the Side-on Peroxo Dicopper(II) / Bis(m-oxo) Dicopper(III) Equilibrium: Significant Ligand Electronic Effects”, Inorg. Chem., 2006,  45, 3004-3013.
  • Hatcher, L. Q.; Karlin, K. D. “Ligand Influences in Copper-Dioxygen Complex Formation and Substrate Oxidations”, Adv. Inorg. Chem. 2006, 58, 131-184.
  • Helton, M. E.; Maiti, D.; Zakharov, L. N.; Rheingold, A. L.; Porco, Jr., J. A.; Karlin, K. D. “A m-h2:h2-Disulfide Dicopper(II) Complex from Reaction of S8 with a Copper(I) Precursor:  Reactivity of the Bound Disulfur Moiety”, Angew. Chem. Int. Ed., 2006, 1138-1141.
  • Lee, Yunho; Sarjeant, A. A. N.; Karlin, K. D. “A molecular pinwheel multicopper(I) cluster, [(LS–)6CuI13(S2–)2]3+ with m4-sulfido, m3-thiolato and nitrogen ligands”, Chem. Commun., 2006, 621-623.
  • Li, Lei; Narducci, Sarjeant, Amy A.; Vance, Michael A.; Zakharov, Lev N.; Rheingold, Arnold, L.; Solomon, Edward I.; Karlin, Kenneth D., ”Exogenous Nitrile Substrate Hydroxylation by a New Dicopper Hydroperoxide Complex” J. Am. Chem. Soc., 2005, 127, 15360-15361.

{Highlighted in the Science magazine section on “Highlights of Recent Literature, Editor’s Choice”, Science, 2005, 310, 591}.

  • Shearer, J.; Karlin, K. D. “Copper: Hemocyanin/Tyrosinase Models” In “Encyclopedia of Inorganic Chemistry, 2nd Ed., Vol. II, King, R. B., Editor, Wiley:Chichester, 2005; pp 1091-1100.
  • Sprakel, Vera S. I.; Feiters, Martin C.; Meyer-Klaucke, Wolfram, Klopstra, Marten, Brinksma, Jelle, Feringa, Ben L.; Karlin, Kenneth D.; Nolte, Roeland J. M. “Oxygen Binding and Activation by the Complexes of PY2- and TPA- appended Diphenylglycoluril Receptors with Copper and Other Metals”, Dalton Trans. 2005, 3522-3534.
  • Ito, Takeo; Thyagarajan, Sunita; Karlin, Kenneth D.; Rokita, Steve E. “Recognition of Guanines at a Double Helix-Coil Junction in DNA by a Trinuclear Copper Complex”, Chem. Comm., 2005, 4812-4814.
  • Kim, Eunsuk; Helton, Matthew E.; Lu, Shen; Moënne-Loccoz, Pierre; Incarvito, Christopher D.; Rheingold, Arnold L.; Kaderli, Susan; Zuberbühler, Andreas D.; Karlin, Kenneth D., “Tridentate Copper Ligand Influences on Heme-Peroxo-Copper Formation and Properties: Reduced, Superoxo, and m-Peroxo Fe/Cu Complexes, Inorg. Chem., 2005, 44, 7014-7029.
  • del Río, Diego; Sarangi, Ritimunkta, Chufán, Eduardo, Karlin, Kenneth D.; Hedman, Britt; Hodgson, Keith O.; Solomon, Edward I. “Geometric and Electronic Structure of the Heme-Peroxo-Copper Complex [(F8TPP)FeIII-(O22–)-CuII(TMPA)](ClO4)” J. Am. Chem. Soc., 2005, 127, 11969-11978.
  • H. Christopher, Fry, Andrew. D. Cohen, John P. Toscano, Gerald J. Meyer and Kenneth D. Karlin, “Photoinduced Carbon Monoxide Migration in a Synthetic Heme-Copper Complex J. Am. Chem. Soc., 2005, 127,  6225-6230.
  • Shearer, J; Zhang, C. X.; Zakharov, L. M.; Rheingold, A. L.; Karlin, K. D. “Substrate Oxidations by Copper-Dioxygen Adducts: Mechanistic Considerations”, J. Am. Chem. Soc., 2005, 127, 5469-5483.
  • Wasser, I. M.; Huang, H.-w.; Moënne-Loccoz, P.; Karlin, K. D. “Heme/Non-Heme Diiron(II) Complexes and O2, CO and NO Adducts as Reduced and Substrate Bound Models for the Active Site of Bacterial Nitric Oxide Reductase (NOR)”, J. Am. Chem. Soc. 2005, 127, 3310-3320.
  • Kim, E.; Kamaraj, K.; Galliker, B.; Rubie, N. D.; Moënne-Loccoz, P.; Kaderli, S.; Zuberbühler, A. D.; Karlin, K. D. “Dioxygen Reactivity of Copper and Heme-Copper Complexes Possessing an Imidazole-Phenol Cross-Link”, Inorg. Chem., 2005, 44, 1238-1247.
  • Osako, T.; Karlin, K. D.; Itoh, S. “Carbon-Halogen Bond Activation Mechanism by Copper Complexes of (2-Pyridyl)alkylamine Ligands”, Inorg. Chem., 2005, 44, 410-415.
  • Li, Lei; Karlin, Kenneth D.; Rokita, Steven E. “Changing Selectivity of DNA Oxidation from Deoxyribose to Guanine by Ligand Design and a New Binuclear Copper Complex” J. Am. Chem. Soc., 2005, 127, 520-521.
  • Reza A. Ghiladi, Hong-wei Huang, Pierre Moënne-Loccoz, Jay Stasser, Ninian J. Blackburn, Amina S. Woods, Robert J. Cotter, Christopher D. Incarvito, Arnold L. Rheingold,  and Kenneth D. Karlin, “A Heme-Cu/Dioxygen Adduct Formation Relevant to Cytochrome c Oxidase: Spectroscopic Characterization of [(6L)FeIII-(O22–)-CuII]+ ”, J. Biol. Inorg. Chem. (JBIC), 2005, 10, 63-77