Chufán, Eduardo E.; Karlin, Kenneth D., “An Iron-Peroxo Porphyrin Complex: New Synthesis and Reactivity Toward a Cu(II) Complex Giving a Heme-Peroxo-Copper Adduct”, J. Am. Chem. Soc.2003, 125, 16160-16161.
Shearer, Jason; Zhang, Christiana X.; Hatcher, Lanying Q; Karlin, Kenneth D. “Distinguishing Rate Limiting Electron- vs. H-Atom Transfers in Cu2(O2) Mediated Oxidative N-Dealkylations: Application of Inter- vs. Intramolecular KIEs” J. Am. Chem. Soc. 2003, 125, 12670-12671.
Shin, Hyosul; Lee, Dong-Heon, Kang, Chan; Karlin, Kenneth D. “Electrocatalytic four-electron reductions of O2 to H2O with cytochrome c oxidase model compounds” Electrochimica Acta2003, 48, 4077-4082.
Fry, H. Christopher; Scaltrito, Donald V.; Karlin, Kenneth D.; Meyer, Gerald, M. “The Rate of O2 and CO Binding to a Copper Complex, Determined by a “Flash-and-Trap” Technique, Exceeds that for Hemes”, J. Am. Chem. Soc. 2003, 125, 11866-11871.
Thompson, David, W.; Kretzer, Ryan M.; Lebeau, Estelle L.; Scaltrito, D. V.; Ghiladi, R. A.; Lam, Kin-Chung; Rheingold, Arnold L.; Karlin, Kenneth D.; Meyer, Gerald J. “Synthesis, Characterization and Laser Flash Photolysis Reactivity of a Carbonmonoxy Heme Complex”, Inorg. Chem. 2003, 42, 5211-5218.
Chen, Peng; Fujisawa, Kiyoshi; Helton, Matthew E.; Karlin, Kenneth D.; Solomon, Edward I. “Spectroscopy and Bonding in Side-On and End-On Cu2(S2) Cores: Comparison to Peroxide Analogues” J. Am. Chem. Soc. 2003, 125, 6394-6408.
Kamaraj, Kaliappan; Kim, Eunsuk; Galliker, Benedikt; Zakharov, Lev N.; Rheingold, Arnold L.; Zuberbühler, Andreas D.; Karlin, Kenneth D. “Copper(I) and Copper(II) Complexes Possessing Cross-Linked Imidazole-Phenol Ligands: Structures and Dioxygen Reactivity” J. Am. Chem. Soc. 2003, 125, 6028-6029.
Kretzer, Ryan M.; Ghiladi, Reza A.; Lebeau, Estelle, L.; Liang, Hong-Chang; Karlin, Kenneth D., “Synthesis and Characterization of Reduced Heme and Heme/Copper Carbonmonoxy Species”, Inorg. Chem. 2003, 42, 3016-3025.
Henson, Mark J.; Vance, Michael A.; Zhang, Christiana Xin; Liang, Hong-Chang; Karlin, Kenneth D.; Solomon, Edward I. “Resonance Raman Investigation of Equatorial Ligand Donor Effects on the Cu2O22+ Core in End-on and Side-on m-Peroxo-Dicopper(II) and Bis-m-oxo-Dicopper(III) Complexes”, J. Am. Chem. Soc. 2003, 125, 5186-5192.
Kim, Eunsuk; Helton, Matthew E.; Wasser, Ian M.; Karlin, Kenneth D.; Lu, Shen; Huang, Hong-wei; Moënne-Loccoz, P.; Incarvito, C. D.; Rheingold, A. L.; Honecker, Marcus; Kaderli, Susan; Zuberbühler, Andreas D., “Superoxo, m-peroxo and m-oxo complexes from heme/O2 and heme-copper/O2 reactivity studies: Copper-ligand influences in cytochrome c oxidase models”, Proc. Natl. Acad. Sci. U. S. A. 2003, 100, 3623-3628. PMC152972
Zhang, C. X.; Kaderli, S.; Costas, M.; Kim, E.-i.; Neuhold, Y.-M.; Karlin, K. D.; Zuberbühler, A. D., “Copper(I)-Dioxygen Reactivity of [(L)CuI]+ (L = tris(2-pyridymethyl)amine): Kinetic/Thermodynamic and Spectroscopic Studies Concerning the Formation of Cu-O2 and Cu2-O2 Adducts as a Function of Solvent Medium and 4-Pyridyl Ligand Substituent Variations”, Inorg. Chem., 2003, 42, 1807-1824.
Helton, M. E.; Chen, P.; Paul, P. P.; Tyeklar, Z.; Sommer, R. D.; Zakharov, L. N.; Rheingold, A. L.; Solomon, E. I.; Karlin, K. D., “Reaction of Elemental Sulfur with a Copper(I) Complex Forming a trans-m-1,2 End-On Disulfide Complex: New Directions in Copper-Sulfur Chemistry”, J. Am. Chem. Soc. 2003; 125, 1160-1161.
Zhang, C. X.; Liang, H.-C.; Kim, E.-i.; Shearer, J.; Helton, M. E.; Kim, E.; Kaderli, S.; Incarvito, C. D.; Zuberbuhler, A. D.; Rheingold, A. L.; Karlin, K. D., “Tuning Copper-Dioxygen Reactivity and Exogenous Substrate Oxidations via Alterations in Ligand Electronics” J. Am. Chem. Soc. 2003; 125, 634-635.
Zhang, Christiana Xin; Liang, Hong-Chang, Humphreys, Kristi J.; Karlin, Kenneth D. “Copper-dioxygen complexes and their roles in biomimetic oxidation reactions In “Advances in Catalytic Activation of Dioxygen by Metal Complexes” (László I. Simándi, Ed.), Catalysis by Metal Complexes, Vol. 26 (Brian R. James & Piet W.N.M. van Leeuwen, Eds), Kluwer Academic Publishers: Dordrecht, 2003. Chapter 2, pp. 79 – 121.
Fry, H. C.; Hoertz, P. G.; Wasser, I. M.; Karlin, K. D.; Meyer, G. J. “Efficient Photodissociation of O2 from Synthetic Heme/M (M = Fe, Cu) Complexes”, J. Am. Chem. Soc. 2004, 126, 16712-16713.
Wasser, Ian M.; Fry, H. Christopher; Hoertz, Paul G.; Meyer, Gerald J.; Karlin, Kenneth D. “Photochemical Organic Oxidations and Dechlorinations with a m-Oxo Bridged Heme/Non-Heme Diiron Complex”, Inorg. Chem.,2004, 43, 8272-8281.
Karlin, K. D.; Kim, E. “Ligand Influences in Heme–Copper O2–Chemistry as Synthetic Models for Cytochrome c Oxidase”, Chem. Lett. 2004, 33, 1226-1231.
Kim, E.; Shearer, J.; Lu, S.; Moënne-Loccoz, P.; Helton, M. E.; Kaderli, S.; Zuberbühler, A. D.; Karlin, K. D. “Heme/Cu/O2 Reactivity: Change in FeIII–(O22–)–CuII Unit Peroxo Binding Geometry Effected by Tridentate Copper Chelation”, J. Am. Chem. Soc. 2004, 126, 12716-12717.
Hatcher, L. Q.; Karlin, K. D. “Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cun-O2 structure and reactivity” J. Biol. Inorg. Chem.2004, 9, 669-683.
Lucchese, B.; Humphreys, K. J.; Lee, D.-H.; Incarvito, C. D.; Sommer, R. D.; Rheingold, A. L.; Karlin, K. D. “Mono-, Bi-, and Trinuclear CuII-Cl Containing Products Based on the Tris(2-Pyridylmethyl)amine Chelate Derived from Copper(I) Complex Dechlorination Reactions of Chloroform” Inorg. Chem. 2004, 43, 5987-5998.
Liang, H.-C.; Henson, M. J.; Hatcher, L. Q.; Vance, M. A.; Zhang, C. X.; Lahti, D.; Kaderli, S.; Sommer, R. D.; Rheingold, A. L.; Zuberbühler, A. D.; Solomon, E. I.; Karlin, K. D. “Solvent Effects on the Conversion of Dicopper(II) m-h2:h2-Peroxo to Bis-m-oxo Dicopper(III) Complexes: Direct Probing of the Solvent Interaction” Inorg. Chem. 2004, 43, 4115-4117.
Wick, P. K.; Karlin, K. D.; Suzuki, M.; Zuberbühler, A. D. “Dicopper peroxo complexes: low temperature stopped-flow reaction kinetics of [(BQPA)CuI]+ and [(Me2-TMPA)CuI]+”, Micron, 2004, 35, 137-139.
Kim, E.; Chufán, E. D.; Kamaraj, K.; Karlin, K. D. “Synthetic Models for Heme–Copper Oxidases”, Chem. Rev. 2004, 104, 1077-1133.
Lee, D.-H.; Lucchese, B.; Karlin, K. D. “Multimetal Oxidases”, Chapter 8.17, pp. 437-457, Volume 8, Bio-coordination Chemistry (Editors: Que, L.; Tolman, W. B.), in Comprehensive Coordination Chemistry II (McCleverty, J. A.; Meyer, T. J., Editors-in-Chief). Elsevier: Oxford, UK, 2004.
Ian M. Wasser, Constantinus F. Martens, Claudio N. Verani, Eva Rentschler, Hong-wei Huang, Pierre Möenne-Loccoz, Lev N. Zakharov, Arnold L. Rheingold and Kenneth D. Karlin, “Synthesis and spectroscopy of m-oxo bridged heme/non-heme diiron complexes: Models for the active site of nitric oxide reductase.” Inorg. Chem. 2004,43, 651-662.
