Kenneth D. Karlin Research Group > 1985-81

1985-81

  • Karlin, K. D.; Gultneh, Y. “Bioinorganic Chemical Modeling of Dioxygen-Activating Copper Proteins” J. Chem. Educ. 1985, 62 (11), 983-990.
  • Karlin, K. D.; Gultneh, Y.; Nicholson, T.; Zubieta, J. “Catecholate Coordination to Copper: Structural Characterization of a Tetrachloro-o-catecholate-Bridged Dicopper(II) Complex as a Model for Intermediates in Copper-Catalyzed Oxidation of Catechols” Inorg. Chem. 1985, 24, 3725-3727.
  • Karlin, K. D.; Haka, M. S.; Cruse, R.W.; Gultneh, Y. “Dioxygen-Copper Reactivity. Reversible O2 and CO Binding by a New Series of Binuclear Copper(I) Complexes” J. Am. Chem. Soc. 1985, 107, 5828-5829.
  • Karlin, K. D.; Cohen, B. I. “Synthesis and Characterization of Copper(II) Complexes of a Tetradentate N3O Ligand: Mononuclear Analogs for Phenolate-Bridged Dinuclear Complexes” Inorg. Chim. Acta 1985, 107, L17-L20.
  • Karlin, K. D.; Gultneh, Y.; Cruse, R. W.; Hayes, J. C.; Zubieta, J. “Dioxygen Binding and Activation in Dinuclear Copper Complex Systems” Rev. Port. Quim. 1985, 27, 20-21 (Abstracts of Lectures at 2nd Intl. Conf. Bioinorg. Chem., April 15-19, 1985, Algarve Portugal).
  • Pyrz, J. W.; Karlin, K. D.; Sorrell, T. N.; Vogel, G. C.; Que, L, Jr. “Resonance Raman Studies of Phenolate Bridged Binuclear Copper Complexes. Relevance to Hemocyanin and Tyrosinase” Inorg. Chem. 1984, 23, 4581-4584.
  • Karlin, K. D.; Cruse, R. W.; McKown, J. W.; Hayes, J. C.; Dahlstrom, P. L.; Zubieta, J. “Structure and Properties of a Monomeric Copper(II) Complex with a N3Tridentate Unit Containing 2-Thio-1-Methylimidazole” Trans. Met. Chem. 1984, 9, 404-405.
  • Karlin, K. D.; McKown, J. W.; Hayes, J. C.; Hutchinson, J. P.; Zubieta, J. “Synthesis and Structure of a Mono-Chloro Bridged Copper(II) Dimer Containing a Linear Cu(II)-Cl-Cu(II) Bridge” Trans. Met. Chem. 1984, 9, 405-406.
  • Kokoszka, G.; Karlin, K. D.; Padula, F.; Baranowski, J.; Goldstein, C. “EPR of Cu(II) Complexes with Tripodal Ligands: Dynamical Properties” Inorg. Chem. 1984, 23, 4378-4380.
  • Blackburn, N. J.; Karlin, K. D.; Concannon, M.; Hayes, J. C.; Gultneh, Y.; Zubieta, J. “Studies on a Model Copper Monooxygenase System: Peroxo-Cu(II) Binuclear Intermediates in the Hydroxylation of an Aromatic Ring” J. Chem. Soc. Chem. Commun. 1984, 939-94035.
  • Karlin, K. D.; Cruse, R. W.; Gultneh, Y.; Hayes, J. C.; Zubieta, J. “Peroxide Coordination to a Dicopper(II) Center. Dioxygen Binding to a Structurally Characterized Phenoxide Bridged Binuclear Copper(I) Complex” J. Am. Chem. Soc. 1984, 106, 3372-3374.
  • Karlin, K. D.; Yandell, J. K. “Redox Behavior of Blue Copper Model Complexes. Redox Potentials and Electron-Transfer Kinetics of Some Copper(II)-Copper(I) Complexes with Nitrogen and Thioether Donors” Inorg. Chem. 1984, 23, 1184-1188.
  • Karlin, K. D.; Gultneh, Y.; Hayes, J. C.; Zubieta, J. “Copper(I) Dioxygen Reactivity, 2. Reaction of a Three-coordinate Cu(I) Complex with O2with Evidence for a Binuclear Oxo-Cu(II) Species: Structural Characterization of a Parallel-Planar Di-Hydroxo Bridged Dimer” Inorg. Chem. 1984, 23, 519-521.
  • Karlin, K. D.; Hayes, J. C.; Gultneh, Y.; Cruse, R. W.; McKown, J. W.; Hutchinson, J. P.; Zubieta, J. “Copper Mediated Hydroxylation of an Arene: Model System for the Action of Copper Monooxygenases and the Structures of a Binuclear Cu(I) Complex and its Oxygenated Product” J. Am. Chem. Soc. 1984, 106, 2121-2128.
  • Karlin, K. D.; Shi, J.; Hayes, J. C.; McKown, J. W.; Hutchinson, J. P.; Zubieta, J. “Cu(I)-Dioxygen Reactivity: Structural Characterization of a Bridged-Binuclear Cu(II) Complex Formed by Oxidation of a New Binuclear Cu(I) Compound” Inorg. Chim. Acta 1984, 91, L3-L7.
  • Karlin, K. D.; Hayes, J. C.; Hutchinson, J. P.; Zubieta, J. “Model Complexes for Ligand Probes of Met-Hemocyanin and Met-tyrosinase Derivatives. Structure of a Novel 1,1-Azido Bridged Binuclear Copper(II) Complex” J. Chem. Soc. Chem. Commun. 1983, 376-8.
  • Karlin, K. D.; Hayes, J.C.; Cruse, R. W.; Gultneh, Y.; Hutchinson, J. P.; Zubieta, J. “Model Complexes for the Active Sites of Reduced and Oxidized Sites of Hemocyanin and Tyrosinase. Structures of Binuclear Cu(I) and Cu(II) Complexes and Characterization of a Model Copper Monooxygenase Reaction” Inorg. Chim. Acta 1983, 79(B7), 98-99  (Intl. Conf. Bioinorg. Chem., Florence, Italy, June 1983).
  • Padula, F.; Goldstein, C.; Orsini, J.; Kokoszka, G.; Karlin, K. D. “EPR of Trigonal Bipyramidal Copper(II) Complexes with Tripod Ligands” Inorg. Chim. Acta 1983, 79(B7), 198-199.
  • Karlin, K. D.; Hayes, J. C.; Zubieta, J. “Copper(I) and Copper(II) Complexes with Xylyl Binucleating Ligands: Structures and Reactions with Dioxygen” In Copper Coordination Chemistry: Biochemical and Inorganic Perspectives; Karlin, K. D.; Zubieta, J., Eds.; Adenine Press: Albany, N.Y., 1983; pp 457-472.
  • Zubieta, J.; Karlin, K. D.; Hayes, J. C. “Structural Systematics of Cu(I) and Cu(II) Derivatives of Tripodal Ligands’ In Copper Coordination Chemistry: Biochemical and Inorganic Perspectives; Karlin, K. D.; Zubieta, J., Eds.; Adenine Press: Albany, N.Y., 1983; pp 97-108.
  • Karlin, K. D.; Hayes, J. C.; Hutchinson, J. P.; Zubieta, J. “Synthesis and Characterization of a Novel Dicopper(I) Complex of a Thiaether Containing meta-Xylyl Binucleating Ligand” Inorg. Chim. Acta 1983, 78, L45-L46.
  • Karlin, K. D.; Gultneh, Y.; Hutchinson, J. P.; Zubieta, J. “Three-Coordinate Binuclear Copper(I) Complex: Model Compound for the Copper Sites in Deoxyhemocyanin and Deoxytyrosinase” J. Am. Chem. Soc. 1982, 104, 5240-5242.
  • Karlin, K. D.; Hayes, J. C.; Shi Juen; Hutchinson, J. P.; Zubieta, J. “Tetragonal vs. Trigonal Coordination in Copper(II) Complexes with Tripod Ligands: Structures and Properties of (Cu(C21H24N4)Cl)PF6 and (Cu(C18H18H4)Cl)PF6“ Inorg. Chem. 1982, 21, 4106-4108.
  • Karlin, K. D.; Sherman, S. E. “Redox Comparisons of Pseudotetrahedral Copper(I) Complexes Containing Tripod Ligands” Inorg. Chim. Acta 1982, 65, L39-L40.
  • Karlin, K. D.; Moisan, M. P.; Kustyn, M.; Dahlstrom, P. L.; Zubieta, J.; Raithby, P. R. “Crystal and Molecular Structure of (Dicarbonyl(Triphenylphosphine)(Cyclooctatetraene)) Iron ((CO)2P(C6H5)3(C8H8)Fe)” Cryst. Struct. Commun. 1982, 11, 1945-1949.
  • Karlin, K. D.; Dahlstrom, P. L.; Hayes, J. C.; Simon, R. A.; Zubieta, J. “Crystal and Molecular Structure of Nitrato (Tris(2(-Pyridyl)ethyl)amine) Copper(II) Nitrate, C21H24N4Cu(NO3)2, (Cu(tepa)NO3)NO3“ Cryst. Struct. Commun. 1982, 11, 907-912.
  • Karlin, K. D.; Hayes, J. C.; Hutchinson, J. P.; Hyde, J. R.; Zubieta, J. “Synthesis and X-ray Structural Characterization of Cu(I) and Cu(II) Derivatives of a New Symmetrical Tripodal Ligand N(CH2CH2-py)3, (py=2-pyridyl)” Inorg. Chim. Acta 1982, 64, L219-L220.
  • Rosenstein, R. D.; Oberding, M.; Hyde, J. R.; Zubieta, J.; Karlin, K. D.; Seeman, N. C. “The Crystal Structure of Hypoxanthinium Nitrate Monohydrate, C5H7N5O5“ Cryst. Struct. Commun. 1982, 11, 1507-1513.
  • Karlin, K. D.; Cruse, R. W.; Kokoszka, B. F.; Orsini, J. J. “ESR Spectra of a New Dicopper(II) Complexes of Novel Binucleating Ligands” Inorg. Chim. Acta 1982, 66, L57-L58.
  • Karlin, K. D.; Hyde, J. R.; Zubieta, J. “Synthesis and Structure of a Novel Dicopper(I) Complex of a New Binucleating Ligand” Inorg. Chim. Acta 1982, 66, L23.
  • Karlin, K. D.; Hyde, J. R.; Zubieta, J. “The Structure of the Copper(II) Analogue of a Pseudotetrahedral Copper(I) Thioether Complex” Trans. Metal. Chem. 1981, 6, 314.
  • Karlin, K. D.; Dahlstrom, P. L.; Cozzette, S. N.; Scensny, P. M.; Zubieta, J. “Activation of O2 by a Binuclear Copper(I) Compound. Hydroxylation of a New Xylyl-binucleating Ligand to Produce a Phenoxy-bridged Binuclear Copper(II) complex; X-ray Structure of (Cu2(OC6H3)(CH2-N(CH2CH2py)2))2-2,6)(OMe)) (py = 2-pyridyl)” J. Chem. Soc. Chem. Commun. 1981, 881.
  • Augustin, M. A.; Yandell, J. K.; Addison, A.W.; Karlin, K. D. “Rates of Electron Transfer and Redox Potentials of some Copper(II) Thioether Complexes” Inorg. Chim. Acta 1981, 55, L35.
  • Karlin, K.D.; Dahlstrom, P. L.; DiPierro, L. T.; Simon, R. A.; Zubieta, J. “X-ray Structure Analysis of a Dicopper Complex of a New Binucleating Ligand Containing a para-Xylyl connecting Group; Large Cu…Cu Separation in ((CuCl2C18H30N3) 2).2H2O” J. Coord. Chem. 1981, 11, 61.