Publications | JHU X-ray Crystallography Facility

“All we have discovered is that it starts with a single individual – always a child – and then spreads explosively, like the formation of crystals round the first nucleus in a saturated solution.” Arthur C. Clarke (Childhood’s End, 1953)

Maxime A. Siegler

(Google Scholar, accessed October 2025)
Citations: 12,782
h-index: 62
i10-index: 269
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378. Sarma, R., Wu, T., Ye, D., Qiu, Y. L., Park, S., Cohen, E., Xiong, J., Siegler, M. A., Guo, Y., & Garcia-Bosch, I. (2025). Stepwise 6H⁺/6e^– electron-coupled proton buffers based on Fe and redox-active ligands. Inorganic Chemistry, 64(39), 19632–19646. https://doi.org/10.1021/acs.inorgchem.5c02720
377. Hakkennes, M. L. A., Regeni, I., Husiev, Y., Andreeva, V. D., Siegler, M. A., Buda, F., & Bonnet, S. (2025). Structure over states: Planarity, not energy, dictates photoactivation in Ru(II) PACT agents. Journal of the American Chemical Society, 147(39), 35767–35787. https://doi.org/10.1021/jacs.5c12226
376. Luo, W., Garchitorena, K. M., Tweedie, D., Chau, C. H., Patel, C. N., Siegler, M. A., Vargesson, N., Hwang, I., Kim, S., Kim, D. S., Figg, W. D., & Greig, N. H. (2025). Monoterpenoid fluorophthalimide IMiDs that lack human cereblon binding: synthesis and anti-proliferative, anti-angiogenic and anti-inflammatory activities. Biochemical and Biophysical Research Communications, 779(152428), 152428. https://doi.org/10.1016/j.bbrc.2025.152428
375. Woge, F., Wang, M., White, B., Kiame, N., Siegler, M. A., Dudding, T., Pitts, C. R., & Lectka, T. (2025). The fluorinative skeletal rearrangement of lumisantonin: An unanticipated dual role of Selectfluor. The Journal of Organic Chemistry, 90(26), 9046–9052. https://doi.org/10.1021/acs.joc.5c00819
374. Wade, J. A., Dey, A., Confer, A., Yadav, S., Siegler, M. A., Albert, T., Moënne-Loccoz, P., Guo, Y., Thoi, V. S., & Goldberg, D. P. (2025). Electronic modification of a reduced mononuclear nonheme iron nitrosyl complex leads to HNO release. Journal of the American Chemical Society, 147(31), 27624–27639. https://doi.org/10.1021/jacs.5c05977
373. Fang, F., Molino, A., Wentz, K. E., Folster, C. P., Williams, J. L., Siegler, M. A., & Klausen, R. S. (2025). Homologous ladder cyclohexasilanes. Angewandte Chemie (International Ed. in English), 64(35), e202506054. https://doi.org/10.1002/anie.202506054
372. Bernier, S., Sinha, M., Pearson, T. J., Sushko, P. V., Oyala, P. H., Siegler, M. A., Adam Phelan, W., Neill, A. N., Freedman, D. E., & McQueen, T. M. (2025). Symmetry-mediated quantum coherence of W⁵⁺ spins in an oxygen-deficient double perovskite. Npj Quantum Materials, 10(1). https://doi.org/10.1038/s41535-025-00782-3
371. Hebert, D. D., Puri, A., Ye, D., McAninch, A., Chisholm, A., Siegler, M. A., Swart, M., & Garcia-Bosch, I. (2025). Synthesis and characterization of copper complexes featuring a redox-active ONO ligand in three molecular oxidation states. Inorganic Chemistry, 64(22), 11204–11218. https://doi.org/10.1021/acs.inorgchem.5c01578
370. Kingsbury, K., Feng, B., Thomas, J., Bassen, G., Ferrenti, A. M., Goldberg, D. P., McQueen, T. M., Siegler, M. A., & Kempa, T. J. (2025). Manipulation of valence trapping through local order of Fe₃O units in an intrinsically mixed-valence coordination polymer. Inorganic Chemistry, 64(20), 10208–10218. https://doi.org/10.1021/acs.inorgchem.5c01117
369. Bekaert, I. M., Siegler, M. A., & Wezenberg, S. J. (2025). Single-wavelength visible-light-induced reversible isomerization of stiff-stilbene under dynamic covalent control. Organic Letters, 27(14), 3612–3616. https://doi.org/10.1021/acs.orglett.5c00707
368. Wentz, K. E., Molino, A., Jiang, G. Q., Siegler, M. A., Wilson, D. J. D., Thoi, V. S., & Klausen, R. S. (2025). Synthesis and redox behavior of Si-Si dimeric 9-methylsilafluorene. Dalton Transactions (Cambridge, England: 2003), 54(15), 6167–6173. https://doi.org/10.1039/d5dt00097a
367. Wang, M., Prasad, A., Garrison, N. G., Rao, P., Kwon, H.-K., Siegler, M. A., & Lectka, T. (2025). Catalysis of free C-C bond rotation: C-F—H-X H-bonds find a catalytic role. Journal of the American Chemical Society, 147(7), 5577–5582. https://doi.org/10.1021/jacs.4c17384
366. Lygouras, C. J., Zhang, J., Gautreau, J., Pula, M., Sharma, S., Gao, S., Berry, T., Halloran, T., Orban, P., Grissonnanche, G., Chamorro, J. R., Mikuri, T., Bhoi, D. K., Siegler, M. A., Livi, K. J. T., Uwatoko, Y., Nakatsuji, S., Ramshaw, B. J., Li, Y., … McQueen, T. M. (2025). Type I and type II superconductivity in a quasi-2D Dirac metal. Materials Advances, 6(5), 1685–1694. https://doi.org/10.1039/d5ma00022j
365. de Jong, J., Siegler, M. A., & Wezenberg, S. J. (2025). A photoswitchable [2]catenane receptor. Chemical Communications (Cambridge, England), 61(12), 2548–2551. https://doi.org/10.1039/d4cc05934d
364. Bos, J. E., Duindam, N., Kock, T. J. F., Siegler, M. A., & Wezenberg, S. J. (2025). Control of bilayer transport through a photoswitchable membrane-stiffening agent. Angewandte Chemie (International Ed. in English), 64(6), e202420232. https://doi.org/10.1002/anie.202420232
363. Rajabalinia, S., Lotfian, H., Hoford, S., Wang, M., Siegler, M. A., Lectka, T., & Dudding, T. (2025). FON: An innovative fluorinated group via hydroetherification-type reactivity. Organic Letters, 27(1), 191–196. https://doi.org/10.1021/acs.orglett.4c04160
362. Yadav, V., Wen, L., Yadav, S., Siegler, M. A., & Goldberg, D. P. (2025). Nonheme mononuclear and dinuclear iron(II) and iron(III) fluoride complexes and their fluorine radical transfer reactivity. Inorganic Chemistry, 64(1), 682–691. https://doi.org/10.1021/acs.inorgchem.4c03335
361. Rajabalinia, S., Lotfian, H., Hoford, S., Wang, M., Siegler, M. A., Lectka, T., & Dudding, T. (2025). FON: An innovative fluorinated group via hydroetherification-type reactivity. Organic Letters, 27(1), 191–196. https://doi.org/10.1021/acs.orglett.4c04160
360. Yadav, S., Lyons, R. S., Readi-Brown, Z., Siegler, M. A., & Goldberg, D. P. (2025). Influence of the second coordination sphere on O2 activation by a nonheme iron(II) thiolate complex. Journal of Inorganic Biochemistry, 264(112776), 112776. https://doi.org/10.1016/j.jinorgbio.2024.112776
359. Iwanicki, A. G., Wilfong, B., Zoghlin, E., Bunstine, W., Siegler, M. A., & McQueen, T. M. (2024). Hydroflux-controlled growth of magnetic K-Cu-Te-O(H) phases. Physical Review Materials, 8(11). https://doi.org/10.1103/physrevmaterials.8.114423
358. Davis, J., Beccar-Varela, P., Banerjee, S., Siegler, M. A., Thoi, V. S., & Drichko, N. (2024). Tunable magnetism in boron imidazolate based metal-organic frameworks. Physical Review. B, 110(18). https://doi.org/10.1103/physrevb.110.184426
357. Ye, D., Wu, T., Puri, A., Hebert, D. D., Siegler, M. A., Hendrich, M. P., Swart, M., & Garcia-Bosch, I. (2024). Enhanced proton-coupled electron-transfer reactivity by a mononuclear nickel(II) hydroxide radical complex. Inorganic Chemistry, 63(52), 24453–24465. https://doi.org/10.1021/acs.inorgchem.4c03370
356. Bos, J. E., Siegler, M. A., & Wezenberg, S. J. (2024). Activity control of a synthetic transporter by photodynamic modulation of membrane mobility and incorporation. Journal of the American Chemical Society, 146(45), 31085–31093. https://doi.org/10.1021/jacs.4c10952
355. Orban, P. T., Bernier, S. M., Berry, T., Siegler, M. A., & McQueen, T. M. (2024). Random-exchange Heisenberg behavior in the electron-doped quasi-one-dimensional spin-1 chain compound AgVP2S6. Physical Review. B, 110(5). https://doi.org/10.1103/physrevb.110.054423
354. Bassen, G., Wilfong, B., Bunstine, W., Edmiston, N., Siegler, M. A., & McQueen, T. M. (2024). Tolerance factor approach for the design of Quaternary materials as applied to the A₂Ln₄Cu₂nQ_7+n homologous series. Journal of the American Chemical Society, 146(36), 25190–25199. https://doi.org/10.1021/jacs.4c08941
353. Hota, P. K., Panda, S., Phan, H., Kim, B., Siegler, M. A., & Karlin, K. D. (2024). Dioxygenase chemistry in nucleophilic aldehyde deformylations utilizing dicopper O2-derived peroxide complexes. Journal of the American Chemical Society, 146(34), 23854–23871. https://doi.org/10.1021/jacs.4c06243
352. Wagner, J. S., Siegler, M. A., Tomlinson, A. L., & Reynolds, J. R. (2024). Controlling charged state colors in triphenylamine-based anodically coloring electrochromes. Advanced Optical Materials, 12(28). https://doi.org/10.1002/adom.202400855
351. Abyar, S., Huang, L., Husiev, Y., Bretin, L., Chau, B., Ramu, V., Wildeman, J. H., Belfor, K., Wijaya, L. S., van der Noord, V. E., Harms, A. C., Siegler, M. A., Le Dévédec, S. E., & Bonnet, S. (2024). Oxygen-dependent interactions between the ruthenium cage and the photoreleased inhibitor in NAMPT-targeted photoactivated chemotherapy. Journal of Medicinal Chemistry, 67(13), 11086–11102. https://doi.org/10.1021/acs.jmedchem.4c00589
350. Wang, M., Garrison, N., Nguyen, P. M., Prasad, A., Wang, Y., Kwon, H.-K., Kim, G., Siegler, M. A., & Lectka, T. (2024). Can the -CF₃ group act as a tight, well-defined hydrogen bond acceptor? A clear crystallographic CF₂-F···H-N⁺ interaction says yes. The Journal of Organic Chemistry, 89(13), 9681–9685. https://doi.org/10.1021/acs.joc.4c00873
349. Stoltzfus, A. T., Ballot, J. G., Vignane, T., Li, H., Worth, M. M., Muller, L., Siegler, M. A., Kane, M. A., Filipovic, M. R., Goldberg, D. P., & Michel, S. L. J. (2024). Chemoselective proteomics, zinc fingers, and a zinc(II) model for H₂S mediated persulfidation. Angewandte Chemie (International Ed. in English), 63(27), e202401003. https://doi.org/10.1002/anie.202401003
348. Ng, N., Siegler, M. A., Bernier, S., Bunstine, W., & McQueen, T. M. (2024). Disordered layers and dimerization in the crystal structure of TaOCl₂. Journal of Solid State Chemistry, 337(124771), 124771. https://doi.org/10.1016/j.jssc.2024.124771
347. Panda, S., Phan, H., Dunietz, E. M., Brueggemeyer, M. T., Hota, P. K., Siegler, M. A., Jose, A., Bhadra, M., Solomon, E. I., & Karlin, K. D. (2024). Intramolecular phenolic H-atom abstraction by a N₃ArOH ligand-supported (μ-η²:Η²-peroxo)dicopper(II) species relevant to the active site function of oxy-tyrosinase. Journal of the American Chemical Society, 146(22), 14942–14947. https://doi.org/10.1021/jacs.4c04402
346. Wu, T., Puri, A., Qiu, Y. L., Ye, D., Sarma, R., Wang, Y., Kowalewski, T., Siegler, M. A., Swart, M., & Garcia-Bosch, I. (2024). Tuning the thermochemistry and reactivity of a series of Cu-based 4H⁺/4e^– electron-coupled-proton buffers. Inorganic Chemistry, 63(20), 9014–9025. https://doi.org/10.1021/acs.inorgchem.4c00835
345. Wakefield, H., 4th, Melvin, S. J., Jiang, J., Kevlishvili, I., Siegler, M. A., Craig, S. L., Kulik, H. J., & Klausen, R. S. (2024). Angle-strained sila-cycloalkynes. Chemical Communications (Cambridge, England), 60(36), 4842–4845. https://doi.org/10.1039/d4cc00439f
344. Yadav, S., Yadav, V., Siegler, M. A., Moënne-Loccoz, P., Jameson, G. N. L., & Goldberg, D. P. (2024). A nonheme iron(III) superoxide complex leads to sulfur oxygenation. Journal of the American Chemical Society, 146(12), 7915–7921. https://doi.org/10.1021/jacs.3c12337
343. Zhou, X.-Q., Abyar, S., Carbo-Bague, I., Wang, L., Türck, S., Siegler, M. A., Basu, U., Ott, I., Liu, R., IJzerman, A. P., & Bonnet, S. (2024). Multitarget thiol-activated tetrapyridyl gold(III) complexes for hypoxic cancer therapy. CCS Chemistry, 6(3), 783–797. https://doi.org/10.31635/ccschem.023.202303190
342. Sagar, K., Kim, M., Wu, T., Zhang, S., Bominaar, E. L., Siegler, M. A., Hendrich, M., & Garcia-Bosch, I. (2024). Mimicking the reactivity of LPMOs with a mononuclear Cu complex. European Journal of Inorganic Chemistry, 27(15). https://doi.org/10.1002/ejic.202300774
341. Epping, R. F. J., de Zwart, F. J., van Leest, N. P., van der Vlugt, J. I., Siegler, M. A., Mathew, S., Reek, J. N. H., & de Bruin, B. (2024). PhenTAA: A redox-active N4-macrocyclic ligand featuring donor and acceptor moieties. Inorganic Chemistry, 63(4), 1974–1987. https://doi.org/10.1021/acs.inorgchem.3c03708
340. de Jong, J., Siegler, M. A., & Wezenberg, S. J. (2024). A photoswitchable macrocycle controls anion-templated pseudorotaxane formation and axle relocalization. Angewandte Chemie (International Ed. in English), 63(4), e202316628. https://doi.org/10.1002/anie.202316628
339. Puri, A., McAninch, A., Shu, S., Rajabimoghadam, K., Siegler, M. A., Swart, M., & Garcia-Bosch, I. (2024). Geometric control of Cu, Ni and Pd complexes in the solid state via intramolecular H-bonding interactions. Inorganica Chimica Acta, 561(121844), 121844. https://doi.org/10.1016/j.ica.2023.121844
338. den Boer, D., Stegman, H., Peeters, C. J. C., Siegler, M. A., & Hetterscheid, D. G. H. (2023). Electronic structure variations of Cu‐based water oxidation catalysts bearing redox‐active ligands. European Journal of Inorganic Chemistry. https://doi.org/10.1002/ejic.202300475
337. Langerman, M., van Langevelde, P. H., van de Vijver, J. J., Siegler, M. A., & Hetterscheid, D. G. H. (2023). Scaling relation between the reduction potential of copper catalysts and the turnover frequency for the oxygen and hydrogen peroxide reduction reactions. Inorganic Chemistry, 62(48), 19593–19602. https://doi.org/10.1021/acs.inorgchem.3c02939
336. Yang, E., Shen, X. E., West-Foyle, H., Hahm, T.-H., Siegler, M. A., Brown, D. R., Johnson, C. C., Kim, J. H., Roker, L. A., Tressler, C. M., Barman, I., Kuo, S. C., & Glunde, K. (2023). FluoMALDI microscopy: Matrix co-crystallization simultaneously enhances fluorescence and MALDI imaging. Advanced Science (Weinheim, Baden-Wurttemberg, Germany), 10(35), e2304343. https://doi.org/10.1002/advs.202304343
335. Garrison, N. G., Harry, S. A., Siegler, M. A., Cariello, G., Cormanich, R. A., & Lectka, T. (2023). The C F⋅⋅⋅H CF2 interaction: A combination of hydrogen bonding and n → σ* stabilization. Journal of Fluorine Chemistry, 272(110191), 110191. https://doi.org/10.1016/j.jfluchem.2023.110191
334. Yadav, V., Wen, L., Yadav, S., Siegler, M. A., & Goldberg, D. P. (2023). Selective radical transfer in a series of nonheme iron(III) complexes. Inorganic Chemistry, 62(43), 17830–17842. https://doi.org/10.1021/acs.inorgchem.3c02617
333. Pressley, L. A., Sinha, M., Siegler, M. A., Edmiston, N., Bernier, S., Ferrenti, A. M., Das, S., Ramesh, R., Kushwaha, S., & McQueen, T. M. (2023). Tunable W⁵⁺ absorbance in laser floating zone grown bismuth tungstate. The Journal of Physical Chemistry. C, Nanomaterials and Interfaces, 127(39), 19386–19395. https://doi.org/10.1021/acs.jpcc.3c04645
332. Ferrenti, A. M., Siegler, M. A., Ghosh, S., Zhang, X., Kintop, N., Vivanco, H. K., Lygouras, C., Halloran, T., Klemenz, S., Broholm, C., Drichko, N., & McQueen, T. M. (2023). Chemical tuning of a honeycomb magnet through a critical point. Physical Review. B, 108(6). https://doi.org/10.1103/physrevb.108.064433
331. Singh, K. K., Gerke, C. S., Saund, S. S., Zito, A. M., Siegler, M. A., & Thoi, V. S. (2023). CO₂ activation with manganese tricarbonyl complexes through an H-atom responsive benzimidazole ligand. Chemistry (Weinheim an Der Bergstrasse, Germany), 29(58), e202300796. https://doi.org/10.1002/chem.202300796
330. Duindam, N., van Dongen, M., Siegler, M. A., & Wezenberg, S. J. (2023). Monodirectional photocycle drives proton translocation. Journal of the American Chemical Society, 145(38), 21020–21026. https://doi.org/10.1021/jacs.3c06587
329. Kazim, M., Feng, Z., Vemulapalli, S., Siegler, M. A., Chopra, A., Minh Nguyen, P., Gargiulo Holl, M., Guan, L., Dudding, T., Tantillo, D. J., & Lectka, T. (2023). Through-space, lone-pair promoted aromatic substitution: A relay mechanism can beat out direct activation. Chemistry (Weinheim an Der Bergstrasse, Germany), 29(52), e202301550. https://doi.org/10.1002/chem.202301550
328. Man, H., Ghasemi, A., Adnani, M., Siegler, M. A., Anber, E. A., Li, Y., Chien, C.-L., Taheri, M. L., Chu, C.-W., Broholm, C. L., & Koohpayeh, S. M. (2023). Quantum paramagnetism in a non-Kramers rare-earth oxide: Monoclinic Pr₂Ti₂O₇. Physical Review Materials, 7(6). https://doi.org/10.1103/physrevmaterials.7.063401
327. Villarón, D., Brugman, G. E. A., Siegler, M. A., & Wezenberg, S. J. (2023). Photoswitching of halide-binding affinity and selectivity in dithienylethene-strapped calix[4]pyrrole. Chemical Communications (Cambridge, England), 59(56), 8688–8691. https://doi.org/10.1039/d3cc02264a
326. Hakkennes, M. L. A., Meijer, M. S., Menzel, J. P., Goetz, A.-C., Van Duijn, R., Siegler, M. A., Buda, F., & Bonnet, S. (2023). Ligand rigidity steers the selectivity and efficiency of the photosubstitution reaction of strained ruthenium polypyridyl complexes. Journal of the American Chemical Society, 145(24), 13420–13434. https://doi.org/10.1021/jacs.3c03543
325. Kazim, M., Wang, M., Vemulapalli, S., Nguyen, P. M., Wang, Y., Siegler, M. A., Dudding, T., & Lectka, T. (2023). How do face-to-face stacked aromatic rings activate each other to electrophilic aromatic substitution? Organic Letters, 25(23), 4318–4322. https://doi.org/10.1021/acs.orglett.3c01401
324. Pressley, L. A., Vivanco, H. K., Berry, T., Siegler, M. A., & McQueen, T. M. (2023). Transition metal (dis)order in single crystal multicomponent rare earth perovskites. Journal of Crystal Growth, 617(127262), 127262. https://doi.org/10.1016/j.jcrysgro.2023.127262
323. Kim, B., Brueggemeyer, M. T., Transue, W. J., Park, Y., Cho, J., Siegler, M. A., Solomon, E. I., & Karlin, K. D. (2023). Fenton-like chemistry by a copper(I) complex and H₂O₂ relevant to enzyme peroxygenase C-H hydroxylation. Journal of the American Chemical Society, 145(21), 11735–11744. https://doi.org/10.1021/jacs.3c02273
322. Zhou, X.-Q., Wang, P., Ramu, V., Zhang, L., Jiang, S., Li, X., Abyar, S., Papadopoulou, P., Shao, Y., Bretin, L., Siegler, M. A., Buda, F., Kros, A., Fan, J., Peng, X., Sun, W., & Bonnet, S. (2023). In vivo metallophilic self-assembly of a light-activated anticancer drug. Nature Chemistry, 15(7), 980–987. https://doi.org/10.1038/s41557-023-01199-w
321. Wakefield, H., 4th, Kevlishvili, I., Wentz, K. E., Yao, Y., Kouznetsova, T. B., Melvin, S. J., Ambrosius, E. G., Herzog-Arbeitman, A., Siegler, M. A., Johnson, J. A., Craig, S. L., Kulik, H. J., & Klausen, R. S. (2023). Synthesis and ring-opening metathesis polymerization of a strained trans-silacycloheptene and single-molecule mechanics of its polymer. Journal of the American Chemical Society, 145(18), 10187–10196. https://doi.org/10.1021/jacs.3c01004
320. Singh, K. K., Bhattacharyya, A., Havenridge, S., Ghabin, M., Ausmann, H., Siegler, M. A., Aikens, C. M., & Das, A. (2023). A first glance into mixed phosphine-stibine moieties as protecting ligands for gold clusters. Nanoscale, 15(15), 6934–6940. https://doi.org/10.1039/d2nr05497c
319. den Boer, D., Konovalov, A. I., Siegler, M. A., & Hetterscheid, D. G. H. (2023). Unusual water oxidation mechanism via a redox-active copper polypyridyl complex. Inorganic Chemistry, 62(14), 5303–5314. https://doi.org/10.1021/acs.inorgchem.3c00477
318. Wang, M., Sachs, R. K., Harry, S. A., Holt, E., Siegler, M. A., & Lectka, T. (2023). Bifurcated hydrogen bonding to fluorine in an all cis-difluoro-hydroxy array. Journal of Fluorine Chemistry, 267(110104), 110104. https://doi.org/10.1016/j.jfluchem.2023.110104
317. Gao, R.-D., Taylor, M., McInnis, T., Chen, Z., Gori, S. S., LaPorte, H. M., Siegler, M. A., Neisewander, J. L., Mach, R. H., Singh, M., Slusher, B. S., Rais, R., Luedtke, R. R., & Tsukamoto, T. (2023). Synthesis and pharmacological characterization of a difluorinated analogue of reduced haloperidol as a sigma-1 receptor ligand. ACS Chemical Neuroscience, 14(5), 947–957. https://doi.org/10.1021/acschemneuro.2c00791
316. Gordon, J. B., Albert, T., Yadav, S., Thomas, J., Siegler, M. A., Moënne-Loccoz, P., & Goldberg, D. P. (2023). Oxygen versus sulfur coordination in cobalt superoxo complexes: Spectroscopic properties, O2 binding, and H-atom abstraction reactivity. Inorganic Chemistry, 62(1), 392–400. https://doi.org/10.1021/acs.inorgchem.2c03484
315. van Geest, E. P., Götzfried, S. K., Klein, D. M., Salitra, N., Popal, S., Husiev, Y., Van der Griend, C. J., Zhou, X., Siegler, M. A., Schneider, G. F., & Bonnet, S. (2023). A lock-and-kill anticancer photoactivated chemotherapy agent. Photochemistry and Photobiology, 99(2), 777–786. https://doi.org/10.1111/php.13738
314. Castillo, A. E., Pérez-Gutiérrez, E., Ceballos, P., Venkatesan, P., Thamotharan, S., Siegler, M. A., & Percino, M. J. (2023). Non-covalent interactions towards 2-(4-(2,2-dicyanovinyl) benzylidene)malononitrile packing polymorphism due to solvent effect. Experimental and theoretical spectroscopy approach. Journal of Molecular Structure, 1275(134674), 134674. https://doi.org/10.1016/j.molstruc.2022.134674
313. Gittens, A. F., Jiang, Q., Siegler, M. A., & Klausen, R. S. (2022). Conjugation in isomeric cyclosilane thioethers. Organometallics, 41(23), 3762–3769. https://doi.org/10.1021/acs.organomet.2c00501
312. Banerjee, S., Han, X., Siegler, M. A., Miller, E. M., Bedford, N. M., Bukowski, B. C., & Thoi, V. S. (2022). Flexible 2D boron imidazolate framework for polysulfide adsorption in lithium–sulfur batteries. Chemistry of Materials: A Publication of the American Chemical Society, 34(23), 10451–10458. https://doi.org/10.1021/acs.chemmater.2c02324
311. Yadav, V., Wen, L., Rodriguez, R. J., Siegler, M. A., & Goldberg, D. P. (2022). Nonheme iron(III) azide and iron(III) isothiocyanate complexes: Radical rebound reactivity, selectivity, and catalysis. Journal of the American Chemical Society, 144(45), 20641–20652. https://doi.org/10.1021/jacs.2c07224
310. Scerba, M. T., Tweedie, D., Lecca, D., Siegler, M. A., Rais, R., & Greig, N. H. (2022). Thionated aminofluorophthalimides reduce classical markers of cellular inflammation in LPS-challenged RAW 264.7 cells. Bioorganic & Medicinal Chemistry Letters, 76(128972), 128972. https://doi.org/10.1016/j.bmcl.2022.128972
309. van de Griend, C., van de Vijver, J. J., Siegler, M. A., Dame, R. T., & Bonnet, S. (2022). Ruthenium-locked helical chirality: A barrier of inversion and formation of an asymmetric macrocycle. Inorganic Chemistry, 61(40), 16045–16054. https://doi.org/10.1021/acs.inorgchem.2c02447
308. Harry, S. A., Garrison, N. G., Zhu, A., Xiang, M. R., Siegler, M. A., & Lectka, T. (2022). C-F bonds as “frozen” nucleophiles: Unconsummated S_N2 reactions. The Journal of Organic Chemistry, 87(19), 13406–13410. https://doi.org/10.1021/acs.joc.2c01788
307. Marvelous, C., de Azevedo Santos, L., Siegler, M. A., Fonseca Guerra, C., & Bouwman, E. (2022). Redox conversion of cobalt(II)‐diselenide to cobalt(III)‐selenolate compounds: Comparison with their sulfur analogs. European Journal of Inorganic Chemistry, 2022(33). https://doi.org/10.1002/ejic.202200445
306. Wu, T., Rajabimoghadam, K., Puri, A., Hebert, D. D., Qiu, Y. L., Eichelberger, S., Siegler, M. A., Swart, M., Hendrich, M. P., & Garcia-Bosch, I. (2022). A 4H⁺/4e^– electron-coupled-proton buffer based on a mononuclear Cu complex. Journal of the American Chemical Society, 144(37), 16905–16915. https://doi.org/10.1021/jacs.2c05454
305. Marvelous, C., Siegler, M. A., & Bouwman, E. (2022). Structural investigations and reactivity of cobalt(II)–disulfide compounds. Inorganica Chimica Acta, 543(121193), 121193. https://doi.org/10.1016/j.ica.2022.121193
304. Banerjee, S., Gorham, J. M., Beccar-Varela, P., Hackbarth, H. G., Siegler, M. A., Drichko, N., Wright, J. T., Bedford, N. M., & Thoi, V. S. (2022). Atomically dispersed CuN_x sites from thermal activation of boron imidazolate cages for electrocatalytic methane generation. ACS Applied Energy Materials. https://doi.org/10.1021/acsaem.2c01174
303. Harry, S. A., Kazim, M., Nguyen, P. M., Zhu, A., Xiang, M. R., Catazaro, J., Siegler, M., & Lectka, T. (2022). The close interaction of a C-F bond with an amide carbonyl: Crystallographic and spectroscopic characterization. Angewandte Chemie (International Ed. in English), 61(34), e202207966. https://doi.org/10.1002/anie.202207966
302. Marvelous, C., de Azevedo Santos, L., Siegler, M. A., Fonseca Guerra, C., & Bouwman, E. (2022). Cleaner and stronger: how 8-quinolinolate facilitates formation of Co(III)-thiolate from Co(II)-disulfide complexes. Dalton Transactions (Cambridge, England: 2003), 51(31), 11675–11684. https://doi.org/10.1039/d2dt02106d
301. Jiang, Q., Gittens, A. F., Wong, S., Siegler, M. A., & Klausen, R. S. (2022). Highly selective addition of cyclosilanes to alkynes enabling new conjugated materials. Chemical Science (Royal Society of Chemistry: 2010), 13(25), 7587–7593. https://doi.org/10.1039/d2sc01690g
300. Ferrenti, A. M., Siegler, M. A., Gao, S., Ng, N., & McQueen, T. M. (2022). ScSI: A new exfoliatable semiconductor. Chemistry of Materials: A Publication of the American Chemical Society, 34(12), 5443–5451. https://doi.org/10.1021/acs.chemmater.2c00318
299. Marvelous, C., de Azevedo Santos, L., Siegler, M. A., Fonseca Guerra, C., & Bouwman, E. (2022). Probing the redox-conversion of Co(II)-disulfide to Co(III)-thiolate complexes: the effect of ligand-field strength. Dalton Transactions (Cambridge, England: 2003), 51(20), 8046–8055. https://doi.org/10.1039/d2dt00356b
298. Boer, D. den, Siberie, Q., Siegler, M. A., Ferber, T. H., Moritz, D. C., Hofmann, J. P., & Hetterscheid, D. G. H. (2022). On the homogeneity of a cobalt-based water oxidation catalyst. ACS Catalysis, 12(8), 4597–4607. https://doi.org/10.1021/acscatal.2c01299
297. Jiang, F., Marvelous, C., Verschuur, A. C., Siegler, M. A., Teat, S. J., & Bouwman, E. (2022). Cobalt(II)-disulfide compounds with the unusual PF₂O₂^– anion. ligand-dependent redox conversion to a cobalt(III)-thiolate complex. Inorganica Chimica Acta, 535(120880), 120880. https://doi.org/10.1016/j.ica.2022.120880
296. Machushynets, N. V., Elsayed, S. S., Du, C., Siegler, M. A., de la Cruz, M., Genilloud, O., Hankemeier, T., & van Wezel, G. P. (2022). Discovery of actinomycin L, a new member of the actinomycin family of antibiotics. Scientific Reports, 12(1), 2813. https://doi.org/10.1038/s41598-022-06736-0
295. Capilato, J. N., Harry, S. A., Siegler, M. A., & Lectka, T. (2022). Spectroscopic and crystallographic characterization of the R₃N⁺-C-H⋅⋅⋅X interaction. Chemistry (Weinheim an Der Bergstrasse, Germany), 28(8), e202103922. https://doi.org/10.1002/chem.202103922
294. Sacramento, J. J. D., Albert, T., Siegler, M., Moënne-Loccoz, P., & Goldberg, D. P. (2022). An iron(III) superoxide corrole from iron(II) and dioxygen. Angewandte Chemie (International Ed. in English), 61(2), e202111492. https://doi.org/10.1002/anie.202111492
293. Smits, N. W. G., Rademaker, D., Konovalov, A. I., Siegler, M. A., & Hetterscheid, D. G. H. (2022). Influence of the spatial distribution of copper sites on the selectivity of the oxygen reduction reaction. Dalton Transactions (Cambridge, England: 2003), 51(3), 1206–1215. https://doi.org/10.1039/d1dt03296h
292. Patty, J. B., Havenridge, S., Tietje-Mckinney, D., Siegler, M. A., Singh, K. K., Hajy Hosseini, R., Ghabin, M., Aikens, C. M., & Das, A. (2022). Crystal structure and optical properties of a chiral mixed thiolate/stibine-protected Au18 cluster. Journal of the American Chemical Society, 144(1), 478–484. https://doi.org/10.1021/jacs.1c10778
291. Wezenberg, S. J., Chen, L.-J., Bos, J. E., Feringa, B. L., Howe, E. N. W., Wu, X., Siegler, M. A., & Gale, P. A. (2022). Photomodulation of transmembrane transport and potential by stiff-stilbene based bis(thio)ureas. Journal of the American Chemical Society, 144(1), 331–338. https://doi.org/10.1021/jacs.1c10034
290. Gordon, J. B., Albert, T., Dey, A., Sabuncu, S., Siegler, M. A., Bill, E., Moënne-Loccoz, P., & Goldberg, D. P. (2021). A reactive, photogenerated high-spin (S = 2) FeI^V(O) complex via O₂ activation. Journal of the American Chemical Society, 143(51), 21637–21647. https://doi.org/10.1021/jacs.1c10051
289. Klein, D. M., Rodríguez-Jiménez, S., Hoefnagel, M. E., Pannwitz, A., Prabhakaran, A., Siegler, M. A., Keyes, T. E., Reisner, E., Brouwer, A. M., & Bonnet, S. (2021). Shorter alkyl chains enhance molecular diffusion and electron transfer kinetics between photosensitisers and catalysts in CO2 -reducing photocatalytic liposomes. Chemistry (Weinheim an Der Bergstrasse, Germany), 27(68), 17203–17212. https://doi.org/10.1002/chem.202102989
288. Farley, G. W., Siegler, M. A., & Goldberg, D. P. (2021). Halogen transfer to carbon radicals by high-Valent iron chloride and iron fluoride corroles. Inorganic Chemistry, 60(22), 17288–17302. https://doi.org/10.1021/acs.inorgchem.1c02666
287. Alvarado, J. G., Cummins, D. C., Diaconescu, A., Siegler, M. A., & Goldberg, D. P. (2021). The selective monobromination of a highly sterically encumbered corrole: Structural and spectroscopic properties of Fe(cl)(2-bromo-5,10,15-tris(triphenyl)phenyl corrole). Journal of Porphyrins and Phthalocyanines, 25(10–12), 1176–1185. https://doi.org/10.1142/s1088424621501169
286. Ballestero-Martínez, E., Ferguson, J. T., Siegler, M. A., & Klausen, R. S. (2021). Isolation of a cyclopentasilane from magnesium reduction of a linear hexasilane. European Journal of Organic Chemistry, 2021(33), 4641–4646. https://doi.org/10.1002/ejoc.202100768
285. Trammell, R., Cordova, A., Zhang, S., Goswami, S., Murata, R., Siegler, M. A., & Garcia-Bosch, I. (2021). Practical one-pot multistep synthesis of 2H-1,3-benzoxazines using copper, hydrogen peroxide and triethylamine. European Journal of Organic Chemistry, 2021(32), 4536–4540. https://doi.org/10.1002/ejoc.202100783
284. Dey, A., Gordon, J. B., Albert, T., Sabuncu, S., Siegler, M. A., MacMillan, S. N., Lancaster, K. M., Moënne-Loccoz, P., & Goldberg, D. P. (2021). A nonheme mononuclear {FeNO}7 complex that produces N2 O in the absence of an exogenous reductant. Angewandte Chemie (International Ed. in English), 60(39), 21558–21564. https://doi.org/10.1002/anie.202109062
283. Castillo, A. E., Ceballos, P., Cerón, M., Pérez-Gutiérrez, E., Sosa-Rivadeneyra, M., Bernal, W., Thamotharan, S., Siegler, M. A., & Percino, M. J. (2021). Spectroscopic characterization of 4,5-diphenyl-2-(2,4,5-trimethoxyphenyl)-1H-imidazole obtained from the condensation of benzyl. Experimental and DFT approach. Journal of Molecular Structure, 1246(131269), 131269. https://doi.org/10.1016/j.molstruc.2021.131269
282. Zhou, X.-Q., Mytiliniou, M., Hilgendorf, J., Zeng, Y., Papadopoulou, P., Shao, Y., Dominguez, M. P., Zhang, L., Hesselberth, M. B. S., Bos, E., Siegler, M. A., Buda, F., Brouwer, A. M., Kros, A., Koning, R. I., Heinrich, D., & Bonnet, S. (2021). Intracellular dynamic assembly of deep-red emitting supramolecular nanostructures based on the Pt…Pt metallophilic interaction. Advanced Materials (Deerfield Beach, Fla.), 33(37), e2008613. https://doi.org/10.1002/adma.202008613
281. Saund, S. S., Siegler, M. A., & Thoi, V. S. (2021). Electrochemical degradation of a dicationic rhenium complex via Hoffman-type elimination. Inorganic Chemistry, 60(17), 13011–13020. https://doi.org/10.1021/acs.inorgchem.1c01427
280. Busemann, A., Flaspohler, I., Zhou, X.-Q., Schmidt, C., Goetzfried, S. K., van Rixel, V. H. S., Ott, I., Siegler, M. A., & Bonnet, S. (2021). Ruthenium-based PACT agents based on bisquinoline chelates: synthesis, photochemistry, and cytotoxicity. Journal of Biological Inorganic Chemistry: JBIC: A Publication of the Society of Biological Inorganic Chemistry, 26(6), 667–674. https://doi.org/10.1007/s00775-021-01882-8
279. Zhang, S., Trammell, R., Cordova, A., Siegler, M. A., & Garcia-Bosch, I. (2021). Cu-promoted intramolecular hydroxylation of CH bonds using directing groups with varying denticity. Journal of Inorganic Biochemistry, 223(111557), 111557. https://doi.org/10.1016/j.jinorgbio.2021.111557
278. Sinha, M., Vivanco, H. K., Wan, C., Siegler, M. A., Stewart, V. J., Pogue, E. A., Pressley, L. A., Berry, T., Wang, Z., Johnson, I., Chen, M., Tran, T. T., Phelan, W. A., & McQueen, T. M. (2021). Twisting of 2D kagomé sheets in layered intermetallics. ACS Central Science, 7(8), 1381–1390. https://doi.org/10.1021/acscentsci.1c00599
277. Shirvan, A., Golchoubian, H., Siegler, M. A., & Bouwman, E. (2021). Copper (II) halide complexes with NNO tridentate ligand as chromotropic probes; synthesis, structural characterization and spectroscopic properties. Journal of Molecular Structure, 1243(130930), 130930. https://doi.org/10.1016/j.molstruc.2021.130930
276. Wu, T., Musgrove, J., Siegler, M. A., & Garcia-Bosch, I. (2021). Mononuclear and dinuclear copper complexes of tridentate redox-active ligands with tunable H-bonding donors: Structure, spectroscopy and H+/e- reactivity. Chemistry, an Asian Journal, 16(12), 1608–1618. https://doi.org/10.1002/asia.202100286
275. Scerba, M. T., Siegler, M. A., & Greig, N. H. (2021). Thionation of aminophthalimide hindered carbonyl groups and application to the synthesis of 3,6′-dithionated pomalidomides. Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, 32(09), 917–922. https://doi.org/10.1055/s-0040-1720460
274. Gordon, J. B., McGale, J. P., Siegler, M. A., & Goldberg, D. P. (2021). Proton-coupled electron-transfer reactivity controls iron versus sulfur oxidation in nonheme iron-thiolate complexes. Inorganic Chemistry, 60(9), 6255–6265. https://doi.org/10.1021/acs.inorgchem.0c03779
273. Castillo, A., Ceballos, P., Santos, P., Cerón, M., Venkatesan, P., Pérez-Gutiérrez, E., Sosa-Rivadeneyra, M., Thamotharan, S., Siegler, M. A., & Percino, M. J. (2021). Solution and solid-state photophysical properties of positional isomeric acrylonitrile derivatives with core pyridine and phenyl moieties: Experimental and DFT studies. Molecules (Basel, Switzerland), 26(6), 1500. https://doi.org/10.3390/molecules26061500
272. Zhou, X.-Q., Carbo-Bague, I., Siegler, M. A., Hilgendorf, J., Basu, U., Ott, I., Liu, R., Zhang, L., Ramu, V., IJzerman, A. P., & Bonnet, S. (2021). Rollover cyclometalation vs nitrogen coordination in tetrapyridyl anticancer gold(III) complexes: Effect on protein interaction and toxicity. JACS Au, 1(4), 380–395. https://doi.org/10.1021/jacsau.0c00104
271. Bhadra, M., Transue, W. J., Lim, H., Cowley, R. E., Lee, J. Y. C., Siegler, M. A., Josephs, P., Henkel, G., Lerch, M., Schindler, S., Neuba, A., Hodgson, K. O., Hedman, B., Solomon, E. I., & Karlin, K. D. (2021). A thioether-ligated cupric superoxide model with hydrogen atom abstraction reactivity. Journal of the American Chemical Society, 143(10), 3707–3713. https://doi.org/10.1021/jacs.1c00260
270. Villarón, D., Siegler, M. A., & Wezenberg, S. J. (2021). A photoswitchable strapped calix[4]pyrrole receptor: highly effective chloride binding and release. Chemical Science (Royal Society of Chemistry: 2010), 12(9), 3188–3193. https://doi.org/10.1039/d0sc06686a
269. Pannwitz, A., Saaring, H., Beztsinna, N., Li, X., Siegler, M. A., & Bonnet, S. (2021). Mimicking photosystem I with a transmembrane light harvester and energy transfer-induced photoreduction in phospholipid bilayers. Chemistry (Weinheim an Der Bergstrasse, Germany), 27(9), 3013–3018. https://doi.org/10.1002/chem.202003391
268. Yadav, V., Siegler, M. A., & Goldberg, D. P. (2021). Temperature-dependent reactivity of a non-heme Fe^III(OH)(SR) complex: Relevance to isopenicillin N synthase. Journal of the American Chemical Society, 143(1), 46–52. https://doi.org/10.1021/jacs.0c09688
267. Capilato, J. N., Siegler, M. A., Rowshanpour, R., Dudding, T., & Lectka, T. (2021). Cooperative noncovalent interactions lead to a highly diastereoselective sulfonyl-directed fluorination of steroidal α,β-unsaturated hydrazones. The Journal of Organic Chemistry, 86(1), 1300–1307. https://doi.org/10.1021/acs.joc.0c02716
266. Pérez-Gutiérrez, E., Percino, M. J., Bernal, W., Cerón, M., Ceballos, P., Rivadeneyra, M. S., Siegler, M. A., & Thamotharan, S. (2021). Fluorescence tuning with a single dye embedded in a polymer matrix and its Application on multicolor OLEDs. Dyes and Pigments: An International Journal, 186(108979), 108979. https://doi.org/10.1016/j.dyepig.2020.108979
265. Claire, F. J., Solomos, M. A., Kim, J., Wang, G., Siegler, M. A., Crommie, M. F., & Kempa, T. J. (2020). Structural and electronic switching of a single crystal 2D metal-organic framework prepared by chemical vapor deposition. Nature Communications, 11(1), 5524. https://doi.org/10.1038/s41467-020-19220-y
264. Lim, H., Baker, M. L., Cowley, R. E., Kim, S., Bhadra, M., Siegler, M. A., Kroll, T., Sokaras, D., Weng, T.-C., Biswas, D. R., Dooley, D. M., Karlin, K. D., Hedman, B., Hodgson, K. O., & Solomon, E. I. (2020). Kβ X-ray emission spectroscopy as a probe of Cu(I) sites: Application to the Cu(I) site in preprocessed galactose oxidase. Inorganic Chemistry, 59(22), 16567–16581. https://doi.org/10.1021/acs.inorgchem.0c02495
263. Smits, N. W. G., van Dijk, B., de Bruin, I., Groeneveld, S. L. T., Siegler, M. A., & Hetterscheid, D. G. H. (2020). Influence of ligand denticity and flexibility on the molecular copper mediated oxygen reduction reaction. Inorganic Chemistry, 59(22), 16398–16409. https://doi.org/10.1021/acs.inorgchem.0c02204
262. Hu, Y., Florio, F., Chen, Z., Phelan, W. A., Siegler, M. A., Zhou, Z., Guo, Y., Hawks, R., Jiang, J., Feng, J., Zhang, L., Wang, B., Wang, Y., Gall, D., Palermo, E. F., Lu, Z., Sun, X., Lu, T.-M., Zhou, H., … Shi, J. (2020). A chiral switchable photovoltaic ferroelectric 1D perovskite. Science Advances, 6(9), eaay4213. https://doi.org/10.1126/sciadv.aay4213
261. Ferguson, J. T., Jiang, Q., Marro, E. A., Siegler, M. A., & Klausen, R. S. (2020). Long-range coupling in cyclic silanes. Dalton Transactions (Cambridge, England: 2003), 49(42), 14951–14961. https://doi.org/10.1039/d0dt03163a
260. van Leest, N. P., Stroek, W., Siegler, M. A., van der Vlugt, J. I., & Bruin, B. de. (2020). Ligand-mediated spin-state changes in a cobalt-dipyrrin-bisphenol complex. Inorganic Chemistry, 59(17), 12903–12912. https://doi.org/10.1021/acs.inorgchem.0c01979
259. Ghorbani, F., Harry, S. A., Capilato, J. N., Pitts, C. R., Joram, J., Peters, G. N., Tovar, J. D., Smajlagic, I., Siegler, M. A., Dudding, T., & Lectka, T. (2020). Carbonyl-directed aliphatic fluorination: A special type of hydrogen atom transfer beats out Norrish II. Journal of the American Chemical Society, 142(34), 14710–14724. https://doi.org/10.1021/jacs.0c07004
258. Elsayed, S. S., Genta-Jouve, G., Carrión, V. J., Nibbering, P. H., Siegler, M. A., de Boer, W., Hankemeier, T., & van Wezel, G. P. (2020). Atypical spirotetronate polyketides identified in the underexplored genus Streptacidiphilus. The Journal of Organic Chemistry, 85(16), 10648–10657. https://doi.org/10.1021/acs.joc.0c01210
257. Kazim, M., Guan, L., Chopra, A., Sun, R., Siegler, M. A., & Lectka, T. (2020). Switching a HO···π interaction to a nonconventional OH···π hydrogen bond: A completed crystallographic puzzle. The Journal of Organic Chemistry, 85(15), 9801–9807. https://doi.org/10.1021/acs.joc.0c01121
256. Evans, C. A., Zuluaga, A., Vasquez Matute, D., Baradaran-Noviri, S., Perez-Cervantes, N., & Siegler, M. A. (2020). Synthesis and biological evaluation of thioadatanserin and its dialkylated products as partial 5-HTR1A agonists and 5-HTR2A antagonists for potential use in depression and anxiety disorders. Bioorganic & Medicinal Chemistry Letters, 30(16), 127358. https://doi.org/10.1016/j.bmcl.2020.127358
255. Wu, T., MacMillan, S. N., Rajabimoghadam, K., Siegler, M. A., Lancaster, K. M., & Garcia-Bosch, I. (2020). Structure, spectroscopy, and reactivity of a mononuclear copper hydroxide complex in three molecular oxidation states. Journal of the American Chemical Society, 142(28), 12265–12276. https://doi.org/10.1021/jacs.0c03867
254. Busemann, A., Araman, C., Flaspohler, I., Pratesi, A., Zhou, X.-Q., van Rixel, V. H. S., Siegler, M. A., Messori, L., van Kasteren, S. I., & Bonnet, S. (2020). Alkyne functionalization of a photoactivated ruthenium polypyridyl complex for click-enabled serum albumin interaction studies. Inorganic Chemistry, 59(11), 7710–7720. https://doi.org/10.1021/acs.inorgchem.0c00742
253. Zhou, X.-Q., Xiao, M., Ramu, V., Hilgendorf, J., Li, X., Papadopoulou, P., Siegler, M. A., Kros, A., Sun, W., & Bonnet, S. (2020). The self-assembly of a cyclometalated palladium photosensitizer into protein-stabilized nanorods triggers drug uptake in vitro and in vivo. Journal of the American Chemical Society, 142(23), 10383–10399. https://doi.org/10.1021/jacs.0c01369
252. Yadav, V., Rodriguez, R. J., Siegler, M. A., & Goldberg, D. P. (2020). Determining the inherent selectivity for carbon radical hydroxylation versus halogenation with Fe^III(OH)(X) complexes: Relevance to the rebound step in non-heme iron halogenases. Journal of the American Chemical Society, 142(16), 7259–7264. https://doi.org/10.1021/jacs.0c00493
251. Kazim, M., Siegler, M. A., & Lectka, T. (2020). Close amide NH···F hydrogen bonding interactions in 1,8-disubstituted naphthalenes. The Journal of Organic Chemistry, 85(9), 6195–6200. https://doi.org/10.1021/acs.joc.0c00553
250. Kerber, W. D., Hartnett, D. S., Wang, A., Mafrice, C. H., & Siegler, M. A. (2020). Enhanced relative stability of heterobimetallic Fe(II), Zn(II), and Mg(II) clusters supported by a µ-phenoxo bridge. Inorganica Chimica Acta, 506(119547), 119547. https://doi.org/10.1016/j.ica.2020.119547
249. Singh, K. K., Siegler, M. A., & Thoi, V. S. (2020). Unusual reactivity of a thiazole-based Mn tricarbonyl complex for CO₂ activation. Organometallics, 39(7), 988–994. https://doi.org/10.1021/acs.organomet.9b00727
248. van Leest, N. P., Tepaske, M. A., Oudsen, J.-P. H., Venderbosch, B., Rietdijk, N. R., Siegler, M. A., Tromp, M., van der Vlugt, J. I., & de Bruin, B. (2020). Ligand redox noninnocence in [Co^III(TAML)]^0/- complexes affects nitrene formation. Journal of the American Chemical Society, 142(1), 552–563. https://doi.org/10.1021/jacs.9b11715
247. Burns, D. A., Press, E. M., Siegler, M. A., Klausen, R. S., & Thoi, V. S. (2020). 2D oligosilyl metal-organic frameworks as multi-state switchable materials. Angewandte Chemie (International Ed. in English), 59(2), 763–768. https://doi.org/10.1002/anie.201912911
246. Zaragoza, J. P. T., Cummins, D. C., Mubarak, M. Q. E., Siegler, M. A., de Visser, S. P., & Goldberg, D. P. (2019). Hydrogen atom abstraction by high-Valent Fe(OH) versus Mn(OH) porphyrinoid complexes: Mechanistic insights from experimental and computational studies. Inorganic Chemistry, 58(24), 16761–16770. https://doi.org/10.1021/acs.inorgchem.9b02923
245. York, G. D., Siegler, M. A., Patel, D. D., & Lectka, T. (2019). Synthesis and X-Ray crystallography of a substituted trityl fluoride: Ordering power of a C-F bond. Journal of Fluorine Chemistry, 228(109377), 109377. https://doi.org/10.1016/j.jfluchem.2019.109377
244. Wijeratne, G. B., Bhadra, M., Siegler, M. A., & Karlin, K. D. (2019). Copper(I) complex mediated nitric oxide reductive coupling: Ligand hydrogen bonding derived proton transfer promotes N₂O(g) release. Journal of the American Chemical Society, 141(45), 17962–17967. https://doi.org/10.1021/jacs.9b07286
243. Marro, E. A., Folster, C. P., Press, E. M., Im, H., Ferguson, J. T., Siegler, M. A., & Klausen, R. S. (2019). Stereocontrolled syntheses of functionalized cis- and trans-siladecalins. Journal of the American Chemical Society, 141(44), 17926–17936. https://doi.org/10.1021/jacs.9b09902
242. Kazim, M., Foy, H., Siegler, M. A., Dudding, T., & Lectka, T. (2019). Discovery and mechanistic study of a totally organic C(aryl)-C(alkyl)oxygen insertion reaction. The Journal of Organic Chemistry, 84(21), 14349–14353. https://doi.org/10.1021/acs.joc.9b02238
241. Plessius, R., Orth, N., Ivanović-Burmazović, I., Siegler, M. A., Reek, J. N. H., & van der Vlugt, J. I. (2019). Reversible multi-electron storage in dual-site redox-active supramolecular cages. Chemical Communications (Cambridge, England), 55(84), 12619–12622. https://doi.org/10.1039/c9cc07138e
240. van Vliet, K. M., Polak, L. H., Siegler, M. A., van der Vlugt, J. I., Guerra, C. F., & de Bruin, B. (2019). Efficient copper-catalyzed multicomponent synthesis of N-acyl amidines via acyl nitrenes. Journal of the American Chemical Society, 141(38), 15240–15249. https://doi.org/10.1021/jacs.9b07140
239. Rebreyend, C., Mouarrawis, V., Siegler, M. A., van der Vlugt, J. I., & de Bruin, B. (2019). Steric protection of rhodium‐nitridyl radical species: Steric protection of rhodium-nitridyl radical species. European Journal of Inorganic Chemistry, 2019(39–40), 4249–4255. https://doi.org/10.1002/ejic.201900591
238. Lankelma, M., Vreeken, V., Siegler, M. A., & van der Vlugt, J. I. (2019). Dinuclear gold complexes supported by wide bite angle diphosphines for preorganization-induced selective dual-gold catalysis. Inorganics, 7(3), 28. https://doi.org/10.3390/inorganics7030028
237. Folster, C. P., Nguyen, P. N., Siegler, M. A., & Klausen, R. S. (2019). Tunable SiN hybrid conjugated materials. Organometallics, 38(15), 2902–2909. https://doi.org/10.1021/acs.organomet.9b00254
236. Confer, A. M., Sabuncu, S., Siegler, M. A., Moënne-Loccoz, P., & Goldberg, D. P. (2019). Mononuclear, nonheme, high-spin {FeNO}^7/8 complexes supported by a sterically encumbered N4S-thioether ligand. Inorganic Chemistry, 58(15), 9576–9580. https://doi.org/10.1021/acs.inorgchem.9b01475
235. Liu, J. J., Siegler, M. A., Karlin, K. D., & Moënne-Loccoz, P. (2019). Direct resonance Raman characterization of a peroxynitrito copper complex generated from O₂ and NO and mechanistic insights into metal-mediated peroxynitrite decomposition. Angewandte Chemie (International Ed. in English), 58(32), 10936–10940. https://doi.org/10.1002/anie.201904672
234. Yadav, V., Gordon, J. B., Siegler, M. A., & Goldberg, D. P. (2019). Dioxygen-derived nonheme mononuclear FeIII(OH) complex and its reactivity with carbon radicals. Journal of the American Chemical Society, 141(26), 10148–10153. https://doi.org/10.1021/jacs.9b03329
233. Rajabimoghadam, K., Darwish, Y., Bashir, U., Pitman, D., Eichelberger, S., Siegler, M. A., & Garcia-Bosch, I. (2019). Tunable intramolecular multicenter H-bonding interactions in first-row metal complexes bearing bidentate redox-active ligands. Journal of Coordination Chemistry, 72(8), 1346–1357. https://doi.org/10.1080/00958972.2019.1624728
232. van Rixel, V. H. S., Busemann, A., Wissingh, M. F., Hopkins, S. L., Siewert, B., van de Griend, C., Siegler, M. A., Marzo, T., Papi, F., Ferraroni, M., Gratteri, P., Bazzicalupi, C., Messori, L., & Bonnet, S. (2019). Induction of a Four-Way junction structure in the DNA palindromic hexanucleotide 5’-d(CGTACG)-3’ by a mononuclear platinum complex. Angewandte Chemie (International Ed. in English), 58(28), 9378–9382. https://doi.org/10.1002/anie.201814532
231. Li, M. M., Claire, F. J., Solomos, M. A., Tenney, S. M., Ivanov, S. A., Siegler, M. A., & Kempa, T. J. (2019). Molecular chains of coordinated dimolybdenum isonicotinate paddlewheel clusters. RSC Advances, 9(29), 16492–16495. https://doi.org/10.1039/c9ra03572a
230. Kazim, M., Siegler, M. A., & Lectka, T. (2019b). A protonated quinone methide stabilized by a combination of partial aromatization and π-interaction: Spectroscopic and crystallographic analysis. The Journal of Organic Chemistry, 84(12), 8284–8288. https://doi.org/10.1021/acs.joc.9b00923
229. Trammell, R., D’Amore, L., Cordova, A., Polunin, P., Xie, N., Siegler, M. A., Belanzoni, P., Swart, M., & Garcia-Bosch, I. (2019). Directed hydroxylation of sp2 and sp3 C-H bonds using stoichiometric amounts of Cu and H2O2. Inorganic Chemistry, 58(11), 7584–7592. https://doi.org/10.1021/acs.inorgchem.9b00901
228. Percino, M. J., Cerón, M., Pérez-Gutiérrez, E., Perumal, V., Siegler, M. A., Subbiah, T., Ceballos, P., Gordillo-Guerra, P., Bonilla-Cruz, J., Longoria, F. E., & Lara, T. (2019). Preferential orientation of crystals and its influence on the emission wavelength of acrylonitrile derivatives treated with polar solvents. Crystal Research and Technology, 54(7), 1800156. https://doi.org/10.1002/crat.201800156
227. Venkatesan, P., Cerón, M., Pérez-Gutiérrez, E., Castillo, A. E., Thamotharan, S., Robles, F., Siegler, M. A., & Percino, M. J. (2019). Experimental and theoretical insights into the optical properties and intermolecular interactions in push-pull bromide salts. ChemistryOpen, 8(4), 483–496. https://doi.org/10.1002/open.201900061
226. Zhou, X.-Q., Busemann, A., Meijer, M. S., Siegler, M. A., & Bonnet, S. (2019). The two isomers of a cyclometallated palladium sensitizer show different photodynamic properties in cancer cells. Chemical Communications (Cambridge, England), 55(32), 4695–4698. https://doi.org/10.1039/c8cc10134e
225. Kazim, M., Siegler, M. A., & Lectka, T. (2019). A case of serendipity: Synthesis, characterization, and unique chemistry of a stable, ring-unsubstituted aliphatic p-quinone methide. Organic Letters, 21(7), 2326–2329. https://doi.org/10.1021/acs.orglett.9b00615
224. Gordon, J. B., Vilbert, A. C., Siegler, M. A., Lancaster, K. M., Moënne-Loccoz, P., & Goldberg, D. P. (2019). A nonheme thiolate-ligated cobalt superoxo complex: Synthesis and spectroscopic characterization, computational studies, and hydrogen atom abstraction reactivity. Journal of the American Chemical Society, 141(8), 3641–3653. https://doi.org/10.1021/jacs.8b13134
223. Devillard, M., Ehlers, A., Siegler, M. A., & van der Vlugt, J. I. (2019). Selective carbanion-pyridine coordination of a reactive P,N ligand to RhI. Chemistry (Weinheim an Der Bergstrasse, Germany), 25(15), 3875–3883. https://doi.org/10.1002/chem.201805504
222. Luo, S., Siegler, M. A., & Bouwman, E. (2019). Transition metal compounds of pyridine-amide-functionalized carbene ligands: Synthesis, structure, and electrocatalytic properties in proton reduction. European Journal of Inorganic Chemistry, 2019(5), 617–627. https://doi.org/10.1002/ejic.201801131
221. Saund, S. S., Goldschmid, S. L., Ng, K., Stewart, V., Siegler, M. A., & Thoi, V. S. (2019). Exploring ligand non-innocence of coordinatively-versatile diamidodipyrrinato cobalt complexes. Chemical Communications (Cambridge, England), 55(12), 1825–1828. https://doi.org/10.1039/c8cc08674e
220. Purkait, T. K., Eric M. Press, Marro, E. A., Siegler, M. A., & Klausen, R. S. (2019). Low-energy electronic transition in SiB rings. Organometallics, 38(8), 1688–1698. https://doi.org/10.1021/acs.organomet.8b00804
219. Cuello-Garibo, J.-A., James, C. C., Siegler, M. A., Hopkins, S. L., & Bonnet, S. (2019). Selective preparation of a heteroleptic cyclometallated ruthenium complex capable of undergoing photosubstitution of a bidentate ligand. Chemistry (Weinheim an Der Bergstrasse, Germany), 25(5), 1260–1268. https://doi.org/10.1002/chem.201803720
218. Lameijer, L. N., van de Griend, C., Hopkins, S. L., Volbeda, A.-G., Askes, S. H. C., Siegler, M. A., & Bonnet, S. (2019). Photochemical resolution of a thermally inert cyclometalated Ru(phbpy)(N-N)(sulfoxide)⁺ complex. Journal of the American Chemical Society, 141(1), 352–362. https://doi.org/10.1021/jacs.8b10264
217. Jiang, F., Siegler, M. A., & Bouwman, E. (2019). Synthesis and characterization of a series of transition metal compounds of thioether and disulfide ligands. Inorganica Chimica Acta, 486, 135–140. https://doi.org/10.1016/j.ica.2018.10.047
216. Jiang, F., Siegler, M. A., & Bouwman, E. (2018). The reactivity of Fe^II and Co^II disulfide compounds with dihydrogen peroxide: The reactivity of FeII and CoII disulfide compounds with dihydrogen peroxide. European Journal of Inorganic Chemistry, 2018(43), 4696–4701. https://doi.org/10.1002/ejic.201800962
215. Rajabimoghadam, K., Darwish, Y., Bashir, U., Pitman, D., Eichelberger, S., Siegler, M. A., Swart, M., & Garcia-Bosch, I. (2018). Catalytic aerobic oxidation of alcohols by copper complexes bearing redox-active ligands with tunable H-bonding groups. Journal of the American Chemical Society, 140(48), 16625–16634. https://doi.org/10.1021/jacs.8b08748
214. Gordon, J. B., McGale, J. P., Prendergast, J. R., Shirani-Sarmazeh, Z., Siegler, M. A., Jameson, G. N. L., & Goldberg, D. P. (2018). Structures, spectroscopic properties, and dioxygen reactivity of 5- and 6-coordinate nonheme iron(II) complexes: A combined enzyme/model study of thiol dioxygenases. Journal of the American Chemical Society, 140(44), 14807–14822. https://doi.org/10.1021/jacs.8b08349
213. Claire, F. J., Tenney, S. M., Li, M. M., Siegler, M. A., Wagner, J. S., Hall, A. S., & Kempa, T. J. (2018). Hierarchically ordered two-dimensional coordination polymers assembled from redox-active dimolybdenum clusters. Journal of the American Chemical Society, 140(34), 10673–10676. https://doi.org/10.1021/jacs.8b06331
212. Jiang, F., Siegler, M. A., Sun, X., Jiang, L., Fonseca Guerra, C., & Bouwman, E. (2018). Redox interconversion between cobalt(III) thiolate and cobalt(II) disulfide compounds. Inorganic Chemistry, 57(15), 8796–8805. https://doi.org/10.1021/acs.inorgchem.8b00549
211. Bhadra, M., Lee, J. Y. C., Cowley, R. E., Kim, S., Siegler, M. A., Solomon, E. I., & Karlin, K. D. (2018). Intramolecular hydrogen bonding enhances stability and reactivity of mononuclear cupric superoxide complexes. Journal of the American Chemical Society, 140(29), 9042–9045. https://doi.org/10.1021/jacs.8b04671
210. Jiang, F., Siegler, M. A., & Bouwman, E. (2018). A tetranuclear fluorido-bridged iron compound: Fluoride abstraction from the tetrafluoridoborate anion. Inorganic Chemistry Communications, 94, 53–56. https://doi.org/10.1016/j.inoche.2018.06.005
209. Messersmith, R. E., Siegler, M. A., & Tovar, J. D. (2018). A heptacyclic heptacycle: A doubly naphtho[b]thiophene fused borepin. Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, 29(19), 2499–2502. https://doi.org/10.1055/s-0037-1610163
208. Marro, E. A., Press, E. M., Siegler, M. A., & Klausen, R. S. (2018). Directional building blocks determine linear and cyclic silicon architectures. Journal of the American Chemical Society, 140(18), 5976–5986. https://doi.org/10.1021/jacs.8b02541
207. Hoffman, E. P., Riddle, V., Siegler, M. A., Dickerson, D., Backonja, M., Kramer, W. G., Nagaraju, K., Gordish-Dressman, H., Damsker, J. M., & McCall, J. M. (2018). Phase 1 trial of vamorolone, a first-in-class steroid, shows improvements in side effects via biomarkers bridged to clinical outcomes. Steroids, 134, 43–52. https://doi.org/10.1016/j.steroids.2018.02.010
206. Zaragoza, J. P. T., Siegler, M. A., & Goldberg, D. P. (2018). A reactive manganese(IV)-hydroxide complex: A missing intermediate in hydrogen atom transfer by high-Valent metal-oxo porphyrinoid compounds. Journal of the American Chemical Society, 140(12), 4380–4390. https://doi.org/10.1021/jacs.8b00350
205. Pangia, T. M., Davies, C. G., Prendergast, J. R., Gordon, J. B., Siegler, M. A., Jameson, G. N. L., & Goldberg, D. P. (2018). Observation of radical rebound in a mononuclear nonheme iron model complex. Journal of the American Chemical Society, 140(12), 4191–4194. https://doi.org/10.1021/jacs.7b12707
204. Luo, S., Bruggeman, D. F., Siegler, M. A., & Bouwman, E. (2018). Can pendant pyridyl arm assist the proton delivery in electrocatalysis? Inorganica Chimica Acta, 477, 24–30. https://doi.org/10.1016/j.ica.2018.02.030
203. Lameijer, L. N., Brevé, T. G., van Rixel, V. H. S., Askes, S. H. C., Siegler, M. A., & Bonnet, S. (2018). Effects of the bidentate ligand on the photophysical properties, cellular uptake, and (photo)cytotoxicity of glycoconjugates based on the [Ru(tpy)(NN)(L)]²⁺ scaffold. Chemistry (Weinheim an Der Bergstrasse, Germany), 24(11), 2709–2717. https://doi.org/10.1002/chem.201705388
202. Kottrup, K. G., D’Agostini, S., van Langevelde, P. H., Siegler, M. A., & Hetterscheid, D. G. H. (2018). Catalytic activity of an iron-based water oxidation catalyst: Substrate effects of graphitic electrodes. ACS Catalysis, 8(2), 1052–1061. https://doi.org/10.1021/acscatal.7b03284
201. van Rixel, V. H. S., Moolenaar, G. F., Siegler, M. A., Messori, L., & Bonnet, S. (2018). Controlling with light the interaction between trans-tetrapyridyl ruthenium complexes and an oligonucleotide. Dalton Transactions (Cambridge, England: 2003), 47(2), 507–516. https://doi.org/10.1039/c7dt03613b
200. Luo, S., Siegler, M. A., & Bouwman, E. (2018). Dinuclear nickel complexes of thiolate-functionalized carbene ligands and their electrochemical properties. Organometallics, 37(5), 740–747. https://doi.org/10.1021/acs.organomet.7b00576
199. Gezer, G., Durán Jiménez, D., Siegler, M. A., & Bouwman, E. (2017). Synthesis and characterization of trinuclear [Ni₂Ru] complexes with bridging thiolate or selenolate donors for electrocatalytic proton reduction: Synthesis and characterization of trinuclear [Ni2 Ru] complexes with bridging thiolate or selenolate donors for electrocatalytic proton reduction. European Journal of Inorganic Chemistry, 2017(43), 5027–5032. https://doi.org/10.1002/ejic.201700941
198. Messersmith, R. E., Yadav, S., Siegler, M. A., Ottosson, H., & Tovar, J. D. (2017). Benzo[b]thiophene fusion enhances local borepin aromaticity in polycyclic heteroaromatic compounds. The Journal of Organic Chemistry, 82(24), 13440–13448. https://doi.org/10.1021/acs.joc.7b02512
197. Marro, E. A., Press, E. M., Purkait, T. K., Jimenez, D., Siegler, M. A., & Klausen, R. S. (2017). Cooperative noncovalent interactions induce ion pair separation in diphenylsilanides. Chemistry (Weinheim an Der Bergstrasse, Germany), 23(62), 15633–15637. https://doi.org/10.1002/chem.201704217
196. Guan, L., Holl, M. G., Pitts, C. R., Struble, M. D., Siegler, M. A., & Lectka, T. (2017). Through-space activation can override substituent effects in electrophilic aromatic substitution. Journal of the American Chemical Society, 139(42), 14913–14916. https://doi.org/10.1021/jacs.7b09792
195. Gezer, G., Verbeek, S., Siegler, M. A., & Bouwman, E. (2017). Nickel-ruthenium-based complexes as biomimetic models of [NiFe] and [NiFeSe] hydrogenases for dihydrogen evolution. Dalton Transactions (Cambridge, England: 2003), 46(39), 13590–13596. https://doi.org/10.1039/c7dt02631e
194. Zaragoza, J. P. T., Yosca, T. H., Siegler, M. A., Moënne-Loccoz, P., Green, M. T., & Goldberg, D. P. (2017). Direct observation of oxygen rebound with an iron-hydroxide complex. Journal of the American Chemical Society, 139(39), 13640–13643. https://doi.org/10.1021/jacs.7b07979
193. Devillard, M., de Bruin, B., Siegler, M. A., & van der Vlugt, J. I. (2017). Transition-metal-free cleavage of CO. Chemistry (Weinheim an Der Bergstrasse, Germany), 23(55), 13628–13632. https://doi.org/10.1002/chem.201703798
192. Bume, D. D., Pitts, C. R., Ghorbani, F., Harry, S. A., Capilato, J. N., Siegler, M. A., & Lectka, T. (2017). Ketones as directing groups in photocatalytic sp³ C-H fluorination. Chemical Science (Royal Society of Chemistry: 2010), 8(10), 6918–6923. https://doi.org/10.1039/c7sc02703f
191. Wijeratne, G. B., Hematian, S., Siegler, M. A., & Karlin, K. D. (2017). Copper(I)/NO(g) reductive coupling producing a trans-hyponitrite bridged dicopper(II) complex: Redox reversal giving copper(I)/NO(g) disproportionation. Journal of the American Chemical Society, 139(38), 13276–13279. https://doi.org/10.1021/jacs.7b07808
190. Jang, H. J., Hopkins, S. L., Siegler, M. A., & Bonnet, S. (2017). Frontier orbitals of photosubstitutionally active ruthenium complexes: an experimental study of the spectator ligands’ electronic properties influence on photoreactivity. Dalton Transactions (Cambridge, England: 2003), 46(30), 9969–9980. https://doi.org/10.1039/c7dt01540b
189. Siewert, B., Langerman, M., Hontani, Y., Kennis, J. T. M., van Rixel, V. H. S., Limburg, B., Siegler, M. A., Talens Saez, V., Kieltyka, R. E., & Bonnet, S. (2017). Turning on the red phosphorescence of a [Ru(tpy)(bpy)(Cl)]Cl complex by amide substitution: self-aggregation, toxicity, and cellular localization of an emissive ruthenium-based amphiphile. Chemical Communications (Cambridge, England), 53(81), 11126–11129. https://doi.org/10.1039/c7cc02989f
188. Trammell, R., See, Y. Y., Herrmann, A. T., Xie, N., Díaz, D. E., Siegler, M. A., Baran, P. S., & Garcia-Bosch, I. (2017). Decoding the mechanism of intramolecular cu-directed hydroxylation of sp3 C-H bonds. The Journal of Organic Chemistry, 82(15), 7887–7904. https://doi.org/10.1021/acs.joc.7b01069
187. Gezer, G., Durán Jiménez, D., Siegler, M. A., & Bouwman, E. (2017). Electrocatalytic proton reduction by a model for [NiFeSe] hydrogenases. Dalton Transactions (Cambridge, England: 2003), 46(23), 7506–7514. https://doi.org/10.1039/c7dt00972k
186. Vreeken, V., Baij, L., de Bruin, B., Siegler, M. A., & van der Vlugt, J. I. (2017). N-Atom transfer via thermal or photolytic activation of a Co-azido complex with a PNP pincer ligand. Dalton Transactions (Cambridge, England: 2003), 46(22), 7145–7149. https://doi.org/10.1039/c7dt01712j
185. van Dijkman, T. F., de Bruijn, H. M., Brevé, T. G., van Meijeren, B., Siegler, M. A., & Bouwman, E. (2017). Extremely bulky copper(i) complexes of [HB(3,5-{1-naphthyl}₂pz)₃]- and [HB(3,5-{2-naphthyl}₂pz)₃]- and their self-assembly on graphene. Dalton Transactions (Cambridge, England: 2003), 46(19), 6433–6446. https://doi.org/10.1039/c6dt04851j
184. Cuello-Garibo, J.-A., Pérez-Gallent, E., van der Boon, L., Siegler, M. A., & Bonnet, S. (2017). Influence of the steric bulk and solvent on the photoreactivity of ruthenium polypyridyl complexes coordinated to l-proline. Inorganic Chemistry, 56(9), 4818–4828. https://doi.org/10.1021/acs.inorgchem.6b02794
183. Vreeken, V., Siegler, M. A., & van der Vlugt, J. I. (2017). Controlled interconversion of a dinuclear Au species supported by a redox-active bridging PNP ligand facilitates ligand-to-gold electron transfer. Chemistry (Weinheim an Der Bergstrasse, Germany), 23(23), 5585–5594. https://doi.org/10.1002/chem.201700360
182. Bagh, B., Broere, D. L. J., Sinha, V., Kuijpers, P. F., van Leest, N. P., de Bruin, B., Demeshko, S., Siegler, M. A., & van der Vlugt, J. I. (2017). Catalytic synthesis of N-heterocycles via direct C(sp³)-H amination using an air-stable iron(III) species with a redox-active ligand. Journal of the American Chemical Society, 139(14), 5117–5124. https://doi.org/10.1021/jacs.7b00270
181. Pitts, C. R., Siegler, M. A., & Lectka, T. (2017). Intermolecular aliphatic C-F···H-C interaction in the presence of “stronger” hydrogen bond acceptors: Crystallographic, computational, and IR studies. The Journal of Organic Chemistry, 82(7), 3996–4000. https://doi.org/10.1021/acs.joc.7b00268
180. Percino, J., Cerón, M., Venkatesan, P., Ceballos, P., Bañuelos, A., Rodríguez, O., Siegler, M. A., Robles, F., Chapela, V. M., Soriano-Moro, G., Pérez-Gutiérrez, E., Bonilla-Cruz, J., & Thamotharan, S. (2017). Two different emissions of (2Z)-2-(4-bromophenyl)-3-[4-(dimethylamino)phenyl]prop-2-enenitrile due to crystal habit and size: Synthesis, optical, and supramolecular characterization. Crystal Growth & Design, 17(4), 1679–1694. https://doi.org/10.1021/acs.cgd.6b01670
179. Levine, D. R., Messersmith, R. E., Siegler, M. A., & Tovar, J. D. (2017). Ring fusion isomers of dithienoborepins: perturbations of electronic structure, aromaticity, and reactivity in boron-containing polycyclic heteroaromatics. Canadian Journal of Chemistry, 95(4), 381–389. https://doi.org/10.1139/cjc-2016-0493
178. Pitts, C. R., Bume, D. D., Harry, S. A., Siegler, M. A., & Lectka, T. (2017). Multiple enone-directed reactivity modes lead to the selective photochemical fluorination of polycyclic terpenoid derivatives. Journal of the American Chemical Society, 139(6), 2208–2211. https://doi.org/10.1021/jacs.7b00335
177. Joslin, E. E., Zaragoza, J. P. T., Siegler, M. A., & Goldberg, D. P. (2017). meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine. Chemical Communications (Cambridge, England), 53(12), 1961–1964. https://doi.org/10.1039/c6cc09341h
176. Adam, S. M., Garcia-Bosch, I., Schaefer, A. W., Sharma, S. K., Siegler, M. A., Solomon, E. I., & Karlin, K. D. (2017). Critical aspects of heme-peroxo-Cu complex structure and nature of proton source dictate metal-O(peroxo) breakage versus reductive O-O cleavage chemistry. Journal of the American Chemical Society, 139(1), 472–481. https://doi.org/10.1021/jacs.6b11322
175. Press, E. M., Marro, E. A., Surampudi, S. K., Siegler, M. A., Tang, J. A., & Klausen, R. S. (2017). Synthesis of a fragment of crystalline silicon: Poly(cyclosilane). Angewandte Chemie (International Ed. in English), 56(2), 568–572. https://doi.org/10.1002/anie.201610208
174. Liu, X., Siegler, M. A., Hilbers, M., & Bouwman, E. (2017). Synthesis, structure and photoluminescence properties of lanthanoid coordination polymers based on tetra(3,5-dicarboxyphenoxymethyl)methane. Polyhedron, 123, 1–8. https://doi.org/10.1016/j.poly.2016.10.050
173. Sahu, S., Zhang, B., Pollock, C. J., Dürr, M., Davies, C. G., Confer, A. M., Ivanović-Burmazović, I., Siegler, M. A., Jameson, G. N. L., Krebs, C., & Goldberg, D. P. (2016). Aromatic C-F hydroxylation by nonheme iron(IV)-oxo complexes: Structural, spectroscopic, and mechanistic investigations. Journal of the American Chemical Society, 138(39), 12791–12802. https://doi.org/10.1021/jacs.6b03346
172. Percino, María Judith, Cerón, M., Rodríguez, O., Soriano-Moro, G., Castro, M. E., Chapela, V. M., Siegler, M. A., & Pérez-Gutiérrez, E. (2016). Conformational and molecular structures of α,β-unsaturated acrylonitrile derivatives: Photophysical properties and their frontier orbitals. Molecules (Basel, Switzerland), 21(4), 389. https://doi.org/10.3390/molecules21040389
171. Garcia-Bosch, I., & Siegler, M. A. (2016). Copper-catalyzed oxidation of alkanes with H₂O₂ under a Fenton-like regime. Angewandte Chemie (International Ed. in English), 55(41), 12873–12876. https://doi.org/10.1002/anie.201607216
170. Luo, S., Siegler, M. A., & Bouwman, E. (2016). Nickel complexes of pyridine‐functionalized N‐heterocyclic carbenes: Syntheses, structures, and activity in electrocatalytic hydrogen production: Nickel complexes of pyridine-functionalized N-heterocyclic carbenes: Syntheses, structures, and activity in electrocatalytic hydrogen production. European Journal of Inorganic Chemistry, 2016(28), 4693–4700. https://doi.org/10.1002/ejic.201600917
169. Percino, M. J., Cerón, M., Ceballos, P., Soriano-Moro, G., Rodríguez, O., Chapela, V. M., Castro, M. E., Bonilla-Cruz, J., & Siegler, M. A. (2016). Changes in the luminescence emission of α,β-unsaturated acrylonitrile derivatives: morphology, polymorphism and solvent effect. CrystEngComm, 18(39), 7554–7572. https://doi.org/10.1039/c6ce01391k
168. Broere, D. L. J., Plessius, R., Tory, J., Demeshko, S., de Bruin, B., Siegler, M. A., Hartl, F., & van der Vlugt, J. I. (2016). Localized mixed-valence and redox activity within a triazole-bridged dinucleating ligand upon coordination to palladium. Chemistry (Weinheim an Der Bergstrasse, Germany), 22(39), 13965–13975. https://doi.org/10.1002/chem.201601900
167. Broere, D. L. J., van Leest, N. P., de Bruin, B., Siegler, M. A., & van der Vlugt, J. I. (2016). Reversible redox chemistry and catalytic C(sp³)-H amination reactivity of a paramagnetic pd complex bearing a redox-active o-aminophenol-derived NNO pincer ligand. Inorganic Chemistry, 55(17), 8603–8611. https://doi.org/10.1021/acs.inorgchem.6b01192
166. Joslin, E. E., Zaragoza, J. P. T., Baglia, R. A., Siegler, M. A., & Goldberg, D. P. (2016). The influence of peripheral substituent modification on P(V), Mn(III), and Mn(V)(O) corrolazines: X-ray crystallography, electrochemical and spectroscopic properties, and HAT and OAT reactivities. Inorganic Chemistry, 55(17), 8646–8660. https://doi.org/10.1021/acs.inorgchem.6b01219
165. Struble, M. D., Guan, L., Siegler, M. A., & Lectka, T. (2016). A C-F bond directed Diels-Alder reaction. The Journal of Organic Chemistry, 81(17), 8087–8090. https://doi.org/10.1021/acs.joc.6b01489
164. Jongbloed, L. S., García-López, D., van Heck, R., Siegler, M. A., Carbó, J. J., & van der Vlugt, J. I. (2016). Arene C(sp(²))-H metalation at Ni(II) modeled with a reactive PONCPh ligand. Inorganic Chemistry, 55(16), 8041–8047. https://doi.org/10.1021/acs.inorgchem.6b01162
163. Vreeken, V., Broere, D. L. J., Jans, A. C. H., Lankelma, M., Reek, J. N. H., Siegler, M. A., & van der Vlugt, J. I. (2016). Well-defined dinuclear gold complexes for preorganization-induced selective dual gold catalysis. Angewandte Chemie (International Ed. in English), 55(34), 10042–10046. https://doi.org/10.1002/anie.201603938
162. Sharma, S. K., Kim, H., Rogler, P. J., Siegler, M. A., & Karlin, K. D. (2016). Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization. Journal of Biological Inorganic Chemistry: JBIC: A Publication of the Society of Biological Inorganic Chemistry, 21(5–6), 729–743. https://doi.org/10.1007/s00775-016-1369-4
161. Holl, M. G., Struble, M. D., Siegler, M. A., & Lectka, T. (2016). The close interaction of a C-F bond with a carbonyl π–system: Attractive, repulsive, or both? Journal of Fluorine Chemistry, 188, 126–130. https://doi.org/10.1016/j.jfluchem.2016.06.016
160. Siewert, B., van Rixel, V. H. S., van Rooden, E. J., Hopkins, S. L., Moester, M. J. B., Ariese, F., Siegler, M. A., & Bonnet, S. (2016). Chemical swarming: Depending on concentration, an amphiphilic ruthenium polypyridyl complex induces cell death via two different mechanisms. Chemistry (Weinheim an Der Bergstrasse, Germany), 22(31), 10960–10968. https://doi.org/10.1002/chem.201600927
159 . Conyers, R. C., Mazzone, J. R., Siegler, M. A., & Posner, G. H. (2016). Highly regiocontrolled and stereocontrolled syntheses of polysubstituted aminocyclohexanes: mild inverse-electron-demand Diels–Alder cycloadditions of electrophilic 2-pyridones. Tetrahedron Letters, 57(30), 3344–3348. https://doi.org/10.1016/j.tetlet.2016.06.068
158. Bagh, B., Broere, D. L. J., Siegler, M. A., & van der Vlugt, J. I. (2016). Redox-active-ligand-mediated formation of an acyclic trinuclear ruthenium complex with bridging nitrido ligands. Angewandte Chemie (International Ed. in English), 55(29), 8381–8385. https://doi.org/10.1002/anie.201603659
157. DiMarco, B. N., Motley, T. C., Balok, R. S., Li, G., Siegler, M. A., O’Donnell, R. M., Hu, K., & Meyer, G. J. (2016). A distance dependence to lateral self-exchange across nanocrystalline TiO₂. A comparative study of three homologous Ru^III/II polypyridyl compounds. The Journal of Physical Chemistry. C, Nanomaterials and Interfaces, 120(26), 14226–14235. https://doi.org/10.1021/acs.jpcc.6b04438
156. Messersmith, R. E., Siegler, M. A., & Tovar, J. D. (2016). Aromaticity competition in differentially fused borepin-containing polycyclic aromatics. The Journal of Organic Chemistry, 81(13), 5595–5605. https://doi.org/10.1021/acs.joc.6b00927
155. Cao, R., Saracini, C., Ginsbach, J. W., Kieber-Emmons, M. T., Siegler, M. A., Solomon, E. I., Fukuzumi, S., & Karlin, K. D. (2016). Peroxo and superoxo moieties bound to copper ion: Electron-transfer equilibrium with a small reorganization energy. Journal of the American Chemical Society, 138(22), 7055–7066. https://doi.org/10.1021/jacs.6b02404
154. Liu, X., Siegler, M. A., & Bouwman, E. (2016). Ratiometric thermometer based on a lanthanoid coordination polymer: Ratiometric thermometer based on a lanthanoid coordination polymer. European Journal of Inorganic Chemistry, 2016(18), 2984–2988. https://doi.org/10.1002/ejic.201600141
153. Holl, M. G., Struble, M. D., Singal, P., Siegler, M. A., & Lectka, T. (2016). Positioning a carbon-fluorine bond over the π cloud of an aromatic ring: A different type of Arene activation. Angewandte Chemie (International Ed. in English), 55(29), 8266–8269. https://doi.org/10.1002/anie.201601989
152. van Rixel, V. H. S., Siewert, B., Hopkins, S. L., Askes, S. H. C., Busemann, A., Siegler, M. A., & Bonnet, S. (2016). Green light-induced apoptosis in cancer cells by a tetrapyridyl ruthenium prodrug offering two trans coordination sites. Chemical Science (Royal Society of Chemistry: 2010), 7(8), 4922–4929. https://doi.org/10.1039/c6sc00167j
151. Jung, J., Neu, H. M., Leeladee, P., Siegler, M. A., Ohkubo, K., Goldberg, D. P., & Fukuzumi, S. (2016). Photocatalytic oxygenation of substrates by dioxygen with protonated manganese(III) corrolazine. Inorganic Chemistry, 55(7), 3218–3228. https://doi.org/10.1021/acs.inorgchem.5b02019
150. van Dijkman, T. F., Siegler, M. A., & Bouwman, E. (2016). Copper(I) complexes of naphthyl‐substituted fluorinated trispyrazolylborate ligands with ethene and carbon monoxide. European Journal of Inorganic Chemistry, 2016(15–16), 2586–2594. https://doi.org/10.1002/ejic.201600015
149. Garcia-Bosch, I., Cowley, R. E., Díaz, D. E., Siegler, M. A., Nam, W., Solomon, E. I., & Karlin, K. D. (2016). Dioxygen activation by a macrocyclic copper complex leads to a Cu₂O₂ core with unexpected structure and reactivity. Chemistry (Weinheim an Der Bergstrasse, Germany), 22(15), 5133–5137. https://doi.org/10.1002/chem.201600551
148. McQuilken, A. C., Matsumura, H., Dürr, M., Confer, A. M., Sheckelton, J. P., Siegler, M. A., McQueen, T. M., Ivanović-Burmazović, I., Moënne-Loccoz, P., & Goldberg, D. P. (2016). Photoinitiated reactivity of a thiolate-ligated, spin-crossover nonheme {FeNO}⁷ complex with dioxygen. Journal of the American Chemical Society, 138(9), 3107–3117. https://doi.org/10.1021/jacs.5b12741
147. van de Wouw, H. L., Lee, J. Y., Siegler, M. A., & Klausen, R. S. (2016). Innocent BN bond substitution in anthracene derivatives. Organic & Biomolecular Chemistry, 14(12), 3256–3263. https://doi.org/10.1039/c5ob02309b
146. Phelan, W. A., Koohpayeh, S. M., Cottingham, P., Tutmaher, J. A., Leiner, J. C., Lumsden, M. D., Lavelle, C. M., Wang, X. P., Hoffmann, C., Siegler, M. A., Haldolaarachchige, N., Young, D. P., & McQueen, T. M. (2016). On the chemistry and physical properties of flux and floating zone grown SmB₆ single crystals. Scientific Reports, 6(1), 20860. https://doi.org/10.1038/srep20860
145. Broere, D. L. J., Modder, D. K., Blokker, E., Siegler, M. A., & van der Vlugt, J. I. (2016). Metal-metal interactions in heterobimetallic complexes with dinucleating redox-active ligands. Angewandte Chemie (International Ed. in English), 55(7), 2406–2410. https://doi.org/10.1002/anie.201509412
144. Kerber, W. D., Goheen, J. T., Perez, K. A., & Siegler, M. A. (2016). Enhanced stability of the Fe(II)/Mn(II) state in a synthetic model of heterobimetallic cofactor assembly. Inorganic Chemistry, 55(2), 848–857. https://doi.org/10.1021/acs.inorgchem.5b02322
143. Zheng, S., Reintjens, N. R. M., Siegler, M. A., Roubeau, O., Bouwman, E., Rudavskyi, A., Havenith, R. W. A., & Bonnet, S. (2016). Stabilization of the low-spin state in a mononuclear iron(II) complex and high-temperature cooperative spin crossover mediated by hydrogen bonding. Chemistry (Weinheim an Der Bergstrasse, Germany), 22(1), 331–339. https://doi.org/10.1002/chem.201503119
142. Zaragoza, J. P. T., Siegler, M. A., & Goldberg, D. P. (2016). Rhenium(V)-oxo corrolazines: isolating redox-active ligand reactivity. Chemical Communications (Cambridge, England), 52(1), 167–170. https://doi.org/10.1039/c5cc07956j
141. van Dijkman, T. F., Siegler, M. A., & Bouwman, E. (2015). Highly tunable fluorinated trispyrazolylborates [HB(3-CF3-5-{4-RPh}pz)₃](-) (R = NO₂, CF₃, Cl, F, H, OMe and NMe₂) and their copper(I) complexes. Dalton Transactions (Cambridge, England: 2003), 44(48), 21109–21123. https://doi.org/10.1039/c5dt04006j
140. Pascui, A. E., van Rees, K., Zant, D. W., Broere, D. L. J., Siegler, M. A., & van der Vlugt, J. I. (2015). Macrocyclic platinum(II) complexes with a bifunctional diphosphine ligand: Pt metallamacrocycles with a ditopic diphosphine ligand. European Journal of Inorganic Chemistry, 2015(34), 5687–5693. https://doi.org/10.1002/ejic.201501055
139. van Dijkman, T. F., de Bruijn, H. M., Siegler, M. A., & Bouwman, E. (2015). Bright cyan phosphorescence of a (phosphane)copper(I) complex of the trihydridopyrazolylborate ligand H 3 B(3,5‐ph 2 pz) –: Phosphorescence of a (phosphane)copper(I) complex. European Journal of Inorganic Chemistry, 2015(32), 5387–5394. https://doi.org/10.1002/ejic.201500812
138. Baglia, R. A., Prokop-Prigge, K. A., Neu, H. M., Siegler, M. A., & Goldberg, D. P. (2015). Mn(V)(O) versus Cr(V)(O) porphyrinoid complexes: Structural characterization and implications for basicity controlling H-atom abstraction. Journal of the American Chemical Society, 137(34), 10874–10877. https://doi.org/10.1021/jacs.5b05142
137. Struble, M. D., Holl, M. G., Scerba, M. T., Siegler, M. A., & Lectka, T. (2015). Search for a symmetrical C-F-C fluoronium ion in solution: Kinetic isotope effects, synthetic labeling, and computational, solvent, and rate studies. Journal of the American Chemical Society, 137(35), 11476–11490. https://doi.org/10.1021/jacs.5b07066
136. Hematian, S., Kenkel, I., Shubina, T. E., Dürr, M., Liu, J. J., Siegler, M. A., Ivanovic-Burmazovic, I., & Karlin, K. D. (2015). Nitrogen oxide atom-transfer redox chemistry; Mechanism of NO(g) to nitrite conversion utilizing μ-oxo heme-Fe(III)-O-Cu(II)(L) constructs. Journal of the American Chemical Society, 137(20), 6602–6615. https://doi.org/10.1021/jacs.5b02174
135. Zaragoza, J. P. T., Baglia, R. A., Siegler, M. A., & Goldberg, D. P. (2015). Strong inhibition of O-atom transfer reactivity for Mn(IV)(O)(π-radical-cation)(Lewis acid) versus Mn(V)(O) porphyrinoid complexes. Journal of the American Chemical Society, 137(20), 6531–6540. https://doi.org/10.1021/jacs.5b00875
134. Vreeken, V., Siegler, M. A., de Bruin, B., Reek, J. N. H., Lutz, M., & van der Vlugt, J. I. (2015). C-H activation of benzene by a photoactivated Ni(II)(azide): Formation of a transient nickel nitrido complex. Angewandte Chemie (International Ed. in English), 54(24), 7055–7059. https://doi.org/10.1002/anie.201501437
133. Ording-Wenker, E. C. M., Siegler, M. A., Lutz, M., & Bouwman, E. (2015). Catalytic catechol oxidation by copper complexes: development of a structure-activity relationship. Dalton Transactions (Cambridge, England: 2003), 44(27), 12196–12209. https://doi.org/10.1039/c5dt01041a
132. Neu, H. M., Jung, J., Baglia, R. A., Siegler, M. A., Ohkubo, K., Fukuzumi, S., & Goldberg, D. P. (2015). Light-driven, proton-controlled, catalytic aerobic C-H oxidation mediated by a Mn(III) porphyrinoid complex. Journal of the American Chemical Society, 137(14), 4614–4617. https://doi.org/10.1021/jacs.5b00816
131. Struble, M. D., Holl, M. G., Coombs, G., Siegler, M. A., & Lectka, T. (2015). Synthesis of a tight intramolecular OH···olefin interaction, probed by IR, (1)H NMR, and quantum chemistry. The Journal of Organic Chemistry, 80(9), 4803–4807. https://doi.org/10.1021/acs.joc.5b00470
130. Kumar, P., Lee, Y.-M., Park, Y. J., Siegler, M. A., Karlin, K. D., & Nam, W. (2015). Reactions of Co(III)-nitrosyl complexes with superoxide and their mechanistic insights. Journal of the American Chemical Society, 137(13), 4284–4287. https://doi.org/10.1021/ja513234b
129. Broere, D. L. J., Demeshko, S., de Bruin, B., Pidko, E. A., Reek, J. N. H., Siegler, M. A., Lutz, M., & van der Vlugt, J. I. (2015). Dinuclear palladium complexes with two ligand-centered radicals and a single bridging ligand: subtle tuning of magnetic properties. Chemistry (Weinheim an Der Bergstrasse, Germany), 21(15), 5879–5886. https://doi.org/10.1002/chem.201500084
128. Guo, X., Zhou, J., Siegler, M. A., Bragg, A. E., & Katz, H. E. (2015). Visible-light-triggered molecular photoswitch based on reversible E/Z isomerization of a 1,2-dicyanoethene derivative. Angewandte Chemie (International Ed. in English), 54(16), 4782–4786. https://doi.org/10.1002/anie.201410945
127. Kim, S., Ginsbach, J. W., Lee, J. Y., Peterson, R. L., Liu, J. J., Siegler, M. A., Sarjeant, A. A., Solomon, E. I., & Karlin, K. D. (2015). Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry. Journal of the American Chemical Society, 137(8), 2867–2874. https://doi.org/10.1021/ja508371q
126. Kim, S., Lee, J. Y., Cowley, R. E., Ginsbach, J. W., Siegler, M. A., Solomon, E. I., & Karlin, K. D. (2015). A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity. Journal of the American Chemical Society, 137(8), 2796–2799. https://doi.org/10.1021/ja511504n
125. Ording-Wenker, E. C. M., Siegler, M. A., & Bouwman, E. (2015). Coordination of new disulfide ligands to CuI and CuII: Does a CuII μ-thiolate complex form? Inorganica Chimica Acta, 428, 193–202. https://doi.org/10.1016/j.ica.2014.12.033
124. Kakuda, S., Rolle, C. J., Ohkubo, K., Siegler, M. A., Karlin, K. D., & Fukuzumi, S. (2015). Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate. Journal of the American Chemical Society, 137(9), 3330–3337. https://doi.org/10.1021/ja512584r
123. Long, S., Zhou, P., Theiss, K. L., Siegler, M. A., & Li, T. (2015). Solid-state identity of 2-hydroxynicotinic acid and its polymorphism. CrystEngComm, 17(28), 5195–5205. https://doi.org/10.1039/c4ce02290d
122. Surampudi, S., Yeh, M.-L., Siegler, M. A., Hardigree, J. F. M., Kasl, T. A., Katz, H. E., & Klausen, R. S. (2015). Increased carrier mobility in end-functionalized oligosilanes. Chemical Science (Royal Society of Chemistry: 2010), 6(3), 1905–1909. https://doi.org/10.1039/c4sc03274h
121. Fry, A. M., Sweeney, O. T., Adam Phelan, W., Drichko, N., Siegler, M. A., & McQueen, T. M. (2015). Unique edge-sharing sulfate-transition metal coordination in Na₂M(SO₄)₂ (M=Ni and Co). Journal of Solid State Chemistry, 222, 129–135. https://doi.org/10.1016/j.jssc.2014.11.010
120. Broere, D. L. J., Metz, L. L., de Bruin, B., Reek, J. N. H., Siegler, M. A., & van der Vlugt, J. I. (2015). Redox-active ligand-induced homolytic bond activation. Angewandte Chemie (International Ed. in English), 54(5), 1516–1520. https://doi.org/10.1002/anie.201410048
119. Hong, S., Sutherlin, K. D., Park, J., Kwon, E., Siegler, M. A., Solomon, E. I., & Nam, W. (2014). Crystallographic and spectroscopic characterization and reactivities of a mononuclear non-haem iron(III)-superoxo complex. Nature Communications, 5(1), 5440. https://doi.org/10.1038/ncomms6440
118. Khrimian, A., Shirali, S., Vermillion, K. E., Siegler, M. A., Guzman, F., Chauhan, K., Aldrich, J. R., & Weber, D. C. (2014). Determination of the stereochemistry of the aggregation pheromone of harlequin bug, Murgantia histrionica. Journal of Chemical Ecology, 40(11–12), 1260–1268. https://doi.org/10.1007/s10886-014-0521-2
117. Zheng, S., Siegler, M. A., Roubeau, O., & Bonnet, S. (2014). Influence of selenocyanate ligands on the transition temperature and cooperativity of bapbpy-based Fe(II) spin-crossover compounds. Inorganic Chemistry, 53(24), 13162–13173. https://doi.org/10.1021/ic502381m
116. Ording-Wenker, E. C. M., van der Plas, M., Siegler, M. A., Fonseca Guerra, C., & Bouwman, E. (2014). Protonation of a biologically relevant Cu(II) μ-thiolate complex: ligand dissociation or formation of a protonated Cu(I) disulfide species? Chemistry (Weinheim an Der Bergstrasse, Germany), 20(51), 16913–16921. https://doi.org/10.1002/chem.201403918
115. Kerber, W. D., Perez, K. A., Ren, C., & Siegler, M. A. (2014). Speciation of ferric phenoxide intermediates during the reduction of iron(III)-μ-oxo dimers by hydroquinone. Inorganic Chemistry, 53(21), 11507–11516. https://doi.org/10.1021/ic5014347
114. Sahu, S., Quesne, M. G., Davies, C. G., Dürr, M., Ivanović-Burmazović, I., Siegler, M. A., Jameson, G. N. L., de Visser, S. P., & Goldberg, D. P. (2014). Direct observation of a nonheme iron(IV)-oxo complex that mediates aromatic C-F hydroxylation. Journal of the American Chemical Society, 136(39), 13542–13545. https://doi.org/10.1021/ja507346t
113. Ording-Wenker, E. C. M., van der Plas, M., Siegler, M. A., Bonnet, S., Bickelhaupt, F. M., Fonseca Guerra, C., & Bouwman, E. (2014). Thermodynamics of the Cu(II) μ-thiolate and Cu(I) disulfide equilibrium: a combined experimental and theoretical study. Inorganic Chemistry, 53(16), 8494–8504. https://doi.org/10.1021/ic501060w
112. Struble, M. D., Kelly, C., Siegler, M. A., & Lectka, T. (2014). Search for a strong, virtually “no-shift” hydrogen bond: a cage molecule with an exceptional OH⋅⋅⋅F interaction. Angewandte Chemie (International Ed. in English), 53(34), 8924–8928. https://doi.org/10.1002/anie.201403599
111. Khrimian, A., Zhang, A., Weber, D. C., Ho, H.-Y., Aldrich, J. R., Vermillion, K. E., Siegler, M. A., Shirali, S., Guzman, F., & Leskey, T. C. (2014). Discovery of the aggregation pheromone of the brown marmorated stink bug (Halyomorpha halys) through the creation of stereoisomeric libraries of 1-bisabolen-3-ols. Journal of Natural Products, 77(7), 1708–1717. https://doi.org/10.1021/np5003753
110. Pitts, C. R., Bloom, S., Woltornist, R., Auvenshine, D. J., Ryzhkov, L. R., Siegler, M. A., & Lectka, T. (2014). Direct, catalytic monofluorination of sp³ C-H bonds: a radical-based mechanism with ionic selectivity. Journal of the American Chemical Society, 136(27), 9780–9791. https://doi.org/10.1021/ja505136j
109. Percino, M. J., Cerón, M., Ceballos, P., Soriano-Moro, G., Castro, M. E., Chapela, V. M., Bonilla-Cruz, J., Reyes-Reyes, M., López-Sandoval, R., & Siegler, M. A. (2014). Important role of molecular packing and intermolecular interactions in two polymorphs of (Z)-2-phenyl-3-(4-(pyridin-2-yl)phenyl)acrylonitrile. Preparation, structures, and optical properties. Journal of Molecular Structure, 1078, 74–82. https://doi.org/10.1016/j.molstruc.2014.04.088
108. Kim, S., Ginsbach, J. W., Billah, A. I., Siegler, M. A., Moore, C. D., Solomon, E. I., & Karlin, K. D. (2014). Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium. Journal of the American Chemical Society, 136(22), 8063–8071. https://doi.org/10.1021/ja502974c
107. Widger, L. R., Jiang, Y., McQuilken, A. C., Yang, T., Siegler, M. A., Matsumura, H., Moënne-Loccoz, P., Kumar, D., de Visser, S. P., & Goldberg, D. P. (2014). Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere. Dalton Transactions (Cambridge, England: 2003), 43(20), 7522–7532. https://doi.org/10.1039/c4dt00281d
106. Levine, D. R., Siegler, M. A., & Tovar, J. D. (2014). Thiophene-fused borepins as directly functionalizable boron-containing π-electron systems. Journal of the American Chemical Society, 136(19), 7132–7139. https://doi.org/10.1021/ja502644e
105. Talanov, A., Phelan, W. A., Kelly, Z. A., Siegler, M. A., & McQueen, T. M. (2014). Control of the iridium oxidation state in the hollandite iridate solid solution K_(1-x)Ir₄O₈. Inorganic Chemistry, 53(9), 4500–4507. https://doi.org/10.1021/ic5001667
104. Kim, S., Siegler, M. A., & Karlin, K. D. (2014). Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction. Chemical Communications (Cambridge, England), 50(22), 2844–2846. https://doi.org/10.1039/c3cc47942k
103. Conyers, R. C., Mazzone, J. R., Siegler, M. A., Tripathi, A. K., Sullivan, D. J., Mott, B. T., & Posner, G. H. (2014). The survival times of malaria-infected mice are prolonged more by several new two-carbon-linked artemisinin-derived dimer carbamates than by the trioxane antimalarial drug artemether. Bioorganic & Medicinal Chemistry Letters, 24(5), 1285–1289. https://doi.org/10.1016/j.bmcl.2014.01.059
102. Widger, L. R., Davies, C. G., Yang, T., Siegler, M. A., Troeppner, O., Jameson, G. N. L., Ivanović-Burmazović, I., & Goldberg, D. P. (2014). Dramatically accelerated selective oxygen-atom transfer by a nonheme iron(IV)-oxo complex: tuning of the first and second coordination spheres. Journal of the American Chemical Society, 136(7), 2699–2702. https://doi.org/10.1021/ja410240c
101. Hematian, S., Siegler, M. A., & Karlin, K. D. (2014). Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity. Journal of Biological Inorganic Chemistry: JBIC: A Publication of the Society of Biological Inorganic Chemistry, 19(4–5), 515–528. https://doi.org/10.1007/s00775-013-1081-6
100. Garza-Ortiz, A., Maheswari, P. U., Lutz, M., Siegler, M. A., & Reedijk, J. (2014). Tuning the cytotoxic properties of new ruthenium(III) and ruthenium(II) complexes with a modified bis(arylimino)pyridine Schiff base ligand using bidentate pyridine-based ligands. Journal of Biological Inorganic Chemistry: JBIC: A Publication of the Society of Biological Inorganic Chemistry, 19(4–5), 675–689. https://doi.org/10.1007/s00775-013-1083-4
99. Akerboom, S., Meijer, M. S., Siegler, M. A., Fu, W. T., & Bouwman, E. (2014). Structure, photo- and triboluminescence of the lanthanoid dibenzoylmethanates: HNEt3[Ln(dbm)4]. Journal of Luminescence, 145, 278–282. https://doi.org/10.1016/j.jlumin.2013.07.065
98 Struble, M. D., Strull, J., Patel, K., Siegler, M. A., & Lectka, T. (2014). Modulating “jousting” C-F—H-C interactions with a bit of hydrogen bonding. The Journal of Organic Chemistry, 79(1), 1–6. https://doi.org/10.1021/jo4018205
97. Akerboom, S., van den Elshout, J. J. M. H., Mutikainen, I., Siegler, M. A., Fu, W. T., & Bouwman, E. (2013). Substituted phenanthrolines as antennae in luminescent Eu III complexes: Substituted phenanthrolines in luminescent EuIIIComplexes. European Journal of Inorganic Chemistry, 2013(36), 6137–6146. https://doi.org/10.1002/ejic.201301000
96. Ording-Wenker, E. C. M., Siegler, M. A., Lutz, M., & Bouwman, E. (2013). Cu(I) thiolate reactivity with dioxygen: the formation of Cu(II) sulfinate and Cu(II) sulfonate species via a Cu(II) thiolate intermediate. Inorganic Chemistry, 52(22), 13113–13122. https://doi.org/10.1021/ic402001t
95. Peterson, R. L., Ginsbach, J. W., Cowley, R. E., Qayyum, M. F., Himes, R. A., Siegler, M. A., Moore, C. D., Hedman, B., Hodgson, K. O., Fukuzumi, S., Solomon, E. I., & Karlin, K. D. (2013). Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct. Journal of the American Chemical Society, 135(44), 16454–16467. https://doi.org/10.1021/ja4065377
94. Garza-Ortiz, A., Maheswari, P. U., Siegler, M., Spek, A. L., & Reedijk, J. (2013). A new family of Ru(ii) complexes with a tridentate pyridine Schiff-base ligand and bidentate co-ligands: synthesis, characterization, structure and in vitro cytotoxicity studies. New Journal of Chemistry, 37(11), 3450-3460. https://doi.org/10.1039/c3nj00415e
93. Slack, R. D., Siegler, M. A., & Posner, G. H. (2013). Highly stereocontrolled and regiocontrolled syntheses of polyoxygenated [2.2.2]oxabicyclic synthons. Tetrahedron Letters, 54(46), 6267–6270. https://doi.org/10.1016/j.tetlet.2013.09.030
92. McQuilken, A. C., Ha, Y., Sutherlin, K. D., Siegler, M. A., Hodgson, K. O., Hedman, B., Solomon, E. I., Jameson, G. N. L., & Goldberg, D. P. (2013). Preparation of non-heme {FeNO}7 models of cysteine dioxygenase: sulfur versus nitrogen ligation and photorelease of nitric oxide. Journal of the American Chemical Society, 135(38), 14024–14027. https://doi.org/10.1021/ja4064487
91. Widger, L. R., Jiang, Y., Siegler, M. A., Kumar, D., Latifi, R., de Visser, S. P., Jameson, G. N. L., & Goldberg, D. P. (2013). Synthesis and ligand non-innocence of thiolate-ligated (N4S) Iron(II) and nickel(II) bis(imino)pyridine complexes. Inorganic Chemistry, 52(18), 10467–10480. https://doi.org/10.1021/ic4013558
90. Ward, W. M., Farnum, B. H., Siegler, M., & Meyer, G. J. (2013). Chloride ion-pairing with Ru(II) polypyridyl compounds in dichloromethane. The Journal of Physical Chemistry. A, 117(36), 8883–8894. https://doi.org/10.1021/jp404838z
89. Bahreman, A., Limburg, B., Siegler, M. A., Bouwman, E., & Bonnet, S. (2013). Spontaneous formation in the dark, and visible light-induced cleavage, of a Ru-S bond in water: a thermodynamic and kinetic study. Inorganic Chemistry, 52(16), 9456–9469. https://doi.org/10.1021/ic401105v
88. Oldenhof, S., de Bruin, B., Lutz, M., Siegler, M. A., Patureau, F. W., van der Vlugt, J. I., & Reek, J. N. H. (2013). Base-free production of H2 by dehydrogenation of formic acid using an iridium-bisMETAMORPhos complex. Chemistry (Weinheim an Der Bergstrasse, Germany), 19(35), 11507–11511. https://doi.org/10.1002/chem.201302230
87. Sahu, S., Widger, L. R., Quesne, M. G., de Visser, S. P., Matsumura, H., Moënne-Loccoz, P., Siegler, M. A., & Goldberg, D. P. (2013). Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach. Journal of the American Chemical Society, 135(29), 10590–10593. https://doi.org/10.1021/ja402688t
86. Struble, M. D., Scerba, M. T., Siegler, M., & Lectka, T. (2013). Evidence for a symmetrical fluoronium ion in solution. Science (New York, N.Y.), 340(6128), 57–60. https://doi.org/10.1126/science.1231247
85. Leeladee, P., Jameson, G. N. L., Siegler, M. A., Kumar, D., de Visser, S. P., & Goldberg, D. P. (2013). Generation of a high-valent iron imido corrolazine complex and NR group transfer reactivity. Inorganic Chemistry, 52(8), 4668–4682. https://doi.org/10.1021/ic400280x
84. Widger, L. R., Siegler, M. A., & Goldberg, D. P. (2013). Sulfide oxidation by O2: Synthesis, structure and reactivity of novel sulfide-incorporated Fe(II) bis(imino)pyridine complexes. Polyhedron, 58, 179–189. https://doi.org/10.1016/j.poly.2013.01.043
83. Mott, B. T., Tripathi, A., Siegler, M. A., Moore, C. D., Sullivan, D. J., & Posner, G. H. (2013). Synthesis and antimalarial efficacy of two-carbon-linked, artemisinin-derived trioxane dimers in combination with known antimalarial drugs. Journal of Medicinal Chemistry, 56(6), 2630–2641. https://doi.org/10.1021/jm400058j
82. Zheng, S., Siegler, M. A., Sánchez Costa, J., Fu, W.-T., & Bonnet, S. (2013). Effect of metal dilution on the thermal spin transition of [Fe_xZn_1–x(bapbpy)(NCS)₂]. European Journal of Inorganic Chemistry, 2013(5–6), 1033–1042. https://doi.org/10.1002/ejic.201201183
81. Kim, S., Saracini, C., Siegler, M. A., Drichko, N., & Karlin, K. D. (2012). Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent. Inorganic Chemistry, 51(23), 12603–12605. https://doi.org/10.1021/ic302071e
80. Hematian, S., Siegler, M. A., & Karlin, K. D. (2012). Heme/copper assembly mediated nitrite and nitric oxide interconversion. Journal of the American Chemical Society, 134(46), 18912–18915. https://doi.org/10.1021/ja3083818
79. Yokoyama, A., Han, J. E., Cho, J., Kubo, M., Ogura, T., Siegler, M. A., Karlin, K. D., & Nam, W. (2012). Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. Journal of the American Chemical Society, 134(37), 15269–15272. https://doi.org/10.1021/ja307384e
78. Siegler, M. A., Parkin, S., & Brock, C. P. (2012). [Ni(MeCN)(H₂O)₂(NO₃)₂]·(15-crown-5)·MeCN: detailed study of a four-phase sequence that includes an intermediate modulated phase. Acta Crystallographica. Section B, Structural Science, 68(Pt 4), 389–400. https://doi.org/10.1107/S0108768112018319
77. Bahreman, A., Limburg, B., Siegler, M. A., Koning, R., Koster, A. J., & Bonnet, S. (2012). Ruthenium polypyridyl complexes hopping at anionic lipid bilayers through a supramolecular bond sensitive to visible light. Chemistry (Weinheim an Der Bergstrasse, Germany), 18(33), 10271–10280. https://doi.org/10.1002/chem.201200624
76. Ghiladi, R. A., Rheingold, A. L., Siegler, M. A., & Karlin, K. D. (2012). Synthesis and characterization of new trinuclear copper complexes. Inorganica Chimica Acta, 389, 131–137. https://doi.org/10.1016/j.ica.2012.02.020
75. Levine, D. R., Caruso, A., Jr, Siegler, M. A., & Tovar, J. D. (2012). Meta-B-entacenes: new polycyclic aromatics incorporating two fused borepin rings. Chemical Communications (Cambridge, England), 48(50), 6256–6258. https://doi.org/10.1039/c2cc32500d
74. McQuilken, A. C., Jiang, Y., Siegler, M. A., & Goldberg, D. P. (2012). Addition of dioxygen to an N₄S(thiolate) iron(II) cysteine dioxygenase model gives a structurally characterized sulfinato-iron(II) complex. Journal of the American Chemical Society, 134(21), 8758–8761. https://doi.org/10.1021/ja302112y
73. Heuer, W. B., Xia, H.-L., Ward, W., Zhou, Z., Pearson, W. H., Siegler, M. A., Narducci Sarjeant, A. A., Abrahamsson, M., & Meyer, G. J. (2012). New dicarboxylic acid bipyridine ligand for ruthenium polypyridyl sensitization of TiO₂. Inorganic Chemistry, 51(7), 3981–3988. https://doi.org/10.1021/ic201395q
72. Badiei, Y. M., Jiang, Y., Widger, L. R., Siegler, M. A., & Goldberg, D. P. (2012). Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: unexpected transmetalation mediated by LiAlH₄. Inorganica Chimica Acta, 382, 19–26. https://doi.org/10.1016/j.ica.2011.09.056
71. Patureau, F. W., Worch, C., Siegler, M. A., Spek, A. L., Bolm, C., & Reek, J. N. H. (2012). SIAPhos: Phosphorylated sulfonimidamides and their use in iridium‐catalyzed asymmetric hydrogenations of sterically hindered cyclic enamides. Advanced Synthesis & Catalysis, 354(1), 59–64. https://doi.org/10.1002/adsc.201100692
70. Scerba, M. T., Bloom, S., Haselton, N., Siegler, M., Jaffe, J., & Lectka, T. (2012). Interaction of a C-F bond with the π-system of a C═C bond or “head on” with a proximate C-H bond. The Journal of Organic Chemistry, 77(3), 1605–1609. https://doi.org/10.1021/jo2024152
69. Guthrie, D. A., Kim, N. Y., Siegler, M. A., Moore, C. D., & Toscano, J. P. (2012). Development of N-substituted hydroxylamines as efficient nitroxyl (HNO) donors. Journal of the American Chemical Society, 134(4), 1962–1965. https://doi.org/10.1021/ja2103923
68. Patureau, F. W., Siegler, M. A., Spek, A. L., Sandee, A. J., Jugé, S., Aziz, S., Berkessel, A., & Reek, J. N. H. (2012). Supramolecular hydrogen‐bonding tautomeric sulfonamido–phosphinamides: A perfect P‐chirogenic memory. European Journal of Inorganic Chemistry, 2012(3), 496–503. https://doi.org/10.1002/ejic.201100811
67. Arcis-Castíllo, Z., Zheng, S., Siegler, M. A., Roubeau, O., Bedoui, S., & Bonnet, S. (2011). Tuning the transition temperature and cooperativity of bapbpy-based mononuclear spin-crossover compounds: interplay between molecular and crystal engineering. Chemistry (Weinheim an Der Bergstrasse, Germany), 17(52), 14826–14836. https://doi.org/10.1002/chem.201101301
66. Siegler, M. A., Hao, X., Parkin, S., & Brock, C. P. (2011). [Ni(H₂O)₆](NO₃)₂·(15-crown-5)·2H₂O: three phase transitions and an intermediate modulated phase stable over a range of ca 40 K. Acta Crystallographica. Section B, Structural Science, 67(Pt 6), 486–498. https://doi.org/10.1107/S0108768111045897
65. Pijnenburg, N. J. M., Lutz, M., Siegler, M. A., Spek, A., Van Koten, G., & Gebbink, R. J. M. K. (2011). The role of the dendritic support in the catalytic performance of peripheral pincer Pd-complexes. New Journal of Chemistry, 35(10), 2356-2365. https://doi.org/10.1039/c1nj20366e
64. Scerba, M. T., Leavitt, C. M., Diener, M. E., DeBlase, A. F., Guasco, T. L., Siegler, M. A., Bair, N., Johnson, M. A., & Lectka, T. (2011). NH+-F hydrogen bonding in a fluorinated “proton sponge” derivative: integration of solution, solid-state, gas-phase, and computational studies. The Journal of Organic Chemistry, 76(19), 7975–7984. https://doi.org/10.1021/jo2015328
63. Goldbach, R. E., Rodriguez-Garcia, I., van Lenthe, J. H., Siegler, M. A., & Bonnet, S. (2011). N-acetylmethionine and biotin as photocleavable protective groups for ruthenium polypyridyl complexes. Chemistry (Weinheim an Der Bergstrasse, Germany), 17(36), 9924–9929. https://doi.org/10.1002/chem.201101541
62. Hencken, C. P., Genna, D. T., Siegler, M. A., & Posner, G. H. (2011). Highly stereocontrolled and regiocontrolled syntheses of 2,3,4-trisubstituted alkanoates and lactones. The Journal of Organic Chemistry, 76(12), 5149–5155. https://doi.org/10.1021/jo200795f
61. Hojahmat, M., Zheng, G., Siegler, M., Parkin, S., Biermann, M., & Crooks, P. A. (2011). (S)-1-(2-Chloro-phen-yl)-2-oxocyclo-hexan-1-aminium d-tartrate. Acta Crystallographica. Section E, Structure Reports Online, 67(Pt 3), o736. https://doi.org/10.1107/S1600536811006131
60. van Rijn, J. A., Gouré, E., Siegler, M. A., Spek, A. L., Drent, E., & Bouwman, E. (2011). The intriguing substitution behavior of CO with bidentate phosphine ligands induced by a gem-dialkyl effect. Journal of Organometallic Chemistry, 696(9), 1899–1903. https://doi.org/10.1016/j.jorganchem.2010.12.024
59. Moon, D. K., Tripathi, A., Sullivan, D., Siegler, M. A., Parkin, S., & Posner, G. H. (2011). A single, low, oral dose of a 5-carbon-linked trioxane dimer orthoester plus mefloquine cures malaria-infected mice. Bioorganic & Medicinal Chemistry Letters, 21(9), 2773–2775. https://doi.org/10.1016/j.bmcl.2010.09.123
58. Siegler, M. A., Parkin, S., Angel, R. J., & Brock, C. P. (2011). Detailed study of the phase transition in [Ni(H₂O)₆](NO₃)₂·(15-crown-5)·H₂O and analysis in terms of mean-field theory. Acta Crystallographica. Section B, Structural Science, 67(2), 130–143. https://doi.org/10.1107/s010876811100526x
57. Dzik, W. I., Fuente Arruga, L., Siegler, M. A., Spek, A. L., Reek, J. N. H., & de Bruin, B. (2011). Open-shell organometallic [M^II(dbcot(bislutidylamine)]²⁺ complexes (M = Rh, Ir): Unexpected base-assisted reduction of the metal instead of Amine ligand deprotonation. Organometallics, 30(7), 1902–1913. https://doi.org/10.1021/om101157r
56. Snelders, D. J. M., Siegler, M. A., von Chrzanowski, L. S., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2011). Coulombic inter-ligand repulsion effects on the Pt(II) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines. Dalton Transactions (Cambridge, England: 2003), 40(11), 2588–2600. https://doi.org/10.1039/c0dt01105c
55. Achey, D., Ardo, S., Xia, H.-L., Siegler, M. A., & Meyer, G. J. (2011). Sensitization of TiO₂ by the MLCT excited state of Co(I) coordination compounds. The Journal of Physical Chemistry Letters, 2(4), 305–308. https://doi.org/10.1021/jz101622k
54. Peterson, R. L., Himes, R. A., Kotani, H., Suenobu, T., Tian, L., Siegler, M. A., Solomon, E. I., Fukuzumi, S., & Karlin, K. D. (2011). Cupric superoxo-mediated intermolecular C-H activation chemistry. Journal of the American Chemical Society, 133(6), 1702–1705. https://doi.org/10.1021/ja110466q
53. Long, S., Siegler, M. A., Mattei, A., & Li, T. (2011). Phase transition from two Z′ = 1 forms to a Z′ = 2 form of a concomitant conformational polymorphic system. Crystal Growth & Design, 11(2), 414–421. https://doi.org/10.1021/cg101009g
52. Badiei, Y. M., Siegler, M. A., & Goldberg, D. P. (2011). O₂ activation by bis(imino)pyridine iron(II)-thiolate complexes. Journal of the American Chemical Society, 133(5), 1274–1277. https://doi.org/10.1021/ja109923a
51. Li, J., Siegler, M., Lutz, M., Spek, A. L., Klein Gebbink, R. J. M., & van Koten, G. (2010). PCN- and PCS-pincer palladium complexes as tandem catalysts in homoallylation reactions. Advanced Synthesis & Catalysis, 352(14–15), 2474–2488. https://doi.org/10.1002/adsc.201000204
50. Bonnet, S., Siegler, M. A., van Lenthe, J. H., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2010). Ruthenium‐to‐platinum interactions in η⁶,η¹ NCN‐pincer Arene heterobimetallic complexes: An experimental and theoretical study. European Journal of Inorganic Chemistry, 2010(29), 4667–4677. https://doi.org/10.1002/ejic.201000448
49. Genna, D. T., Hencken, C. P., Siegler, M. A., & Posner, G. H. (2010). α-Chloro-β,γ-ethylenic esters: enantiocontrolled synthesis and substitutions. Organic Letters, 12(20), 4694–4697. https://doi.org/10.1021/ol102142a
48. Jiang, Y., Widger, L. R., Kasper, G. D., Siegler, M. A., & Goldberg, D. P. (2010). Iron(II)-thiolate S-oxygenation by O2: synthetic models of cysteine dioxygenase. Journal of the American Chemical Society, 132(35), 12214–12215. https://doi.org/10.1021/ja105591q
47. Siegler, M. A., Bonnet, S., Schreurs, A. M. M., Klein Gebbink, R. J. M., van Koten, G., & Spek, A. L. (2010). On the two closely related phases of [Ru(C₅Me₅)(η⁶-1,3-(Me₂NCH₂)2C₆H₄)](BF₄) and the reversible solid–solid order–disorder phase transition. Journal of Chemical Crystallography, 40(9), 753–760. https://doi.org/10.1007/s10870-010-9732-8
46. Siegler, M. A., & Stavitski, E. (2010). On the sequence of three related phases of [Ni(H2O)2(15-crown-5)](HSO4)2 in the temperature range 110-295 K. Acta Crystallographica. Section B, Structural Science, 66(Pt 4), 430–440. https://doi.org/10.1107/S0108768110020410
45. Meeuwissen, J., Detz, R., Sandee, A. J., de Bruin, B., Siegler, M. A., Spek, A. L., & Reek, J. N. H. (2010). Ureaphosphanes as hybrid, anionic or supramolecular bidentate ligands for asymmetric hydrogenation reactions. European Journal of Inorganic Chemistry, 2010(19), 2992–2997. https://doi.org/10.1002/ejic.201000213
44. Wassenaar, J., Siegler, M. A., Spek, A. L., de Bruin, B., Reek, J. N. H., & van der Vlugt, J. I. (2010). Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity. Inorganic Chemistry, 49(14), 6495–6508. https://doi.org/10.1021/ic100221w
43. Caruso, A., Jr, Siegler, M. A., & Tovar, J. D. (2010). Synthesis of functionalizable boron-containing pi-electron materials that incorporate formally aromatic fused borepin rings. Angewandte Chemie (International Ed. in English), 49(25), 4213–4217. https://doi.org/10.1002/anie.201000411
42. Rubio, M., Siegler, M. A., Spek, A. L., & Reek, J. N. H. (2010). Heterotopic silver-NHC complexes: from coordination polymers to supramolecular assemblies. Dalton Transactions (Cambridge, England: 2003), 39(23), 5432–5435. https://doi.org/10.1039/c003352a
41. Meeuwissen, J., Sandee, A. J., de Bruin, B., Siegler, M. A., Spek, A. L., & Reek, J. N. H. (2010). Phosphinoureas: Cooperative ligands in rhodium-catalyzed hydroformylation? On the possibility of a ligand-assisted reductive elimination of the aldehyde. Organometallics, 29(11), 2413–2421. https://doi.org/10.1021/om901028z
40. Wassenaar, J., Jansen, E., van Zeist, W.-J., Bickelhaupt, F. M., Siegler, M. A., Spek, A. L., & Reek, J. N. H. (2010). Catalyst selection based on intermediate stability measured by mass spectrometry. Nature Chemistry, 2(5), 417–421. https://doi.org/10.1038/nchem.614
39. Siegler, M. A., Prewitt, J. H., Kelley, S. P., Parkin, S., Selegue, J. P., & Brock, C. P. (2010). More examples of the 15-crown-5…H2O-M-OH2…15-crown-5 motif, M = Al3+, Cr3+ and Pd2+. Acta Crystallographica. Section B, Structural Science, 66(Pt 2), 213–221. https://doi.org/10.1107/S0108768110007202
38. Cabon, Y., Kleijn, H., Siegler, M. A., Spek, A. L., Klein Gebbink, R. J. M., & Deelman, B.-J. (2010). Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands. Dalton Transactions (Cambridge, England: 2003), 39(9), 2423–2427. https://doi.org/10.1039/b924783c
37. Wassenaar, J., de Bruin, B., Siegler, M. A., Spek, A. L., Reek, J. N. H., & van der Vlugt, J. I. (2010). Activation of H₂ by a highly distorted Rh(II) complex with a new C3-symmetric tripodal tetraphosphine ligand. Chemical Communications (Cambridge, England), 46(8), 1232–1234. https://doi.org/10.1039/b917632b
36. Berthon-Gelloz, G., Siegler, M. A., Spek, A. L., Tinant, B., Reek, J. N. H., & Markó, I. E. (2010). IPr* an easily accessible highly hindered N-heterocyclic carbene. Dalton Transactions (Cambridge, England: 2003), 39(6), 1444–1446. https://doi.org/10.1039/b921894g
35. van der Vlugt, J. I., Siegler, M. A., Janssen, M., Vogt, D., & Spek, A. L. (2009). A cationic Ag^I(PNP^tBu) species acting as PNP transfer agent: Facile synthesis of pd(PNP^tBu)(alkyl) complexes and their reactivity compared to PCP^tBu analogues. Organometallics, 28(24), 7025–7032. https://doi.org/10.1021/om900862w
34. van Rijn, J. A., Siegler, M. A., Spek, A. L., Bouwman, E., & Drent, E. (2009). Ruthenium-diphosphine-catalyzed allylation of phenols: A gem-dialkyl-type effect induces high selectivity toward O-allylation. Organometallics, 28(24), 7006–7014. https://doi.org/10.1021/om900832g
33. Lee, Y., Park, G. Y., Lucas, H. R., Vajda, P. L., Kamaraj, K., Vance, M. A., Milligan, A. E., Woertink, J. S., Siegler, M. A., Narducci Sarjeant, A. A., Zakharov, L. N., Rheingold, A. L., Solomon, E. I., & Karlin, K. D. (2009). Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species. Inorganic Chemistry, 48(23), 11297–11309. https://doi.org/10.1021/ic9017695
32. Rubio, M., Jellema, E., Siegler, M. A., Spek, A. L., Reek, J. N. H., & de Bruin, B. (2009). Supramolecular NHC ligands: on the influence of Zn(II)-templates on the activity of Rh(I)(cod) complexes in “carbene polymerization.” Dalton Transactions (Cambridge, England: 2003), 41, 8970–8976. https://doi.org/10.1039/b911339h
31. Virboul, M. A. N., Lutz, M., Siegler, M. A., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2009). One-pot synthesis and immobilisation of sulfonate-tethered N-heterocyclic carbene complexes on polycationic dendrimers. Chemistry (Weinheim an Der Bergstrasse, Germany), 15(39), 9981–9986. https://doi.org/10.1002/chem.200901719
30. Li, J., Siegler, M. A., Lutz, M., Spek, A. L., Klein Gebbink, R. J. M., & van Koten, G. (2009). Chiralortho-palladated and -platinated arylphosphite complexes. Organometallics, 28(18), 5323–5332. https://doi.org/10.1021/om9003237
29. Warsink, S., Hauwert, P., Siegler, M. A., Spek, A. L., & Elsevier, C. J. (2009). Palladium(0) pre-catalysts with heteroditopic NHC-amine ligands by transmetallation from their silver(I) complexes. Applied Organometallic Chemistry, 23(6), 225–228. https://doi.org/10.1002/aoc.1501
28. Angamuthu, R., Gelauff, L. L., Siegler, M. A., Spek, A. L., & Bouwman, E. (2009). A molecular cage of nickel(II) and copper(I): a [{Ni(L)2}2(CuI)6] cluster resembling the active site of nickel-containing enzymes. Chemical Communications (Cambridge, England), 19, 2700–2702. https://doi.org/10.1039/b900423h
27. Patureau, F. W., de Boer, S., Kuil, M., Meeuwissen, J., Breuil, P.-A. R., Siegler, M. A., Spek, A. L., Sandee, A. J., de Bruin, B., & Reek, J. N. H. (2009). Sulfonamido-phosphoramidite ligands in cooperative dinuclear hydrogenation catalysis. Journal of the American Chemical Society, 131(19), 6683–6685. https://doi.org/10.1021/ja9024879
26. Wassenaar, J., van Zutphen, S., Mora, G., Le Floch, P., Siegler, M. A., Spek, A. L., & Reek, J. N. H. (2009). INDOLPhosphole and INDOLPhos Palladium−Allyl complexes in asymmetric allylic alkylations. Organometallics, 28(9), 2724–2734. https://doi.org/10.1021/om801204a
25. Bonnet, S., Li, J., Siegler, M. A., von Chrzanowski, L. S., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2009). Synthesis and resolution of planar-chiral ruthenium-palladium complexes with ECE’ pincer ligands. Chemistry (Weinheim an Der Bergstrasse, Germany), 15(14), 3340–3343. https://doi.org/10.1002/chem.200900117
24. Bonnet, S., van Lenthe, J. H., Siegler, M. A., Spek, A. L., van Koten, G., & Gebbink, R. J. M. K. (2009). Bimetallic η⁶,η¹NCN-pincer ruthenium palladium complexes with η⁶-RuCp coordination: Synthesis, X-ray structures, and catalytic properties. Organometallics, 28(7), 2325–2333. https://doi.org/10.1021/om801200c
23. Bonnet, S., Molnár, G., Sanchez Costa, J., Siegler, M. A., Spek, A. L., Bousseksou, A., Fu, W.-T., Gamez, P., & Reedijk, J. (2009). Influence of sample preparation, temperature, light, and pressure on the two-step spin crossover mononuclear compound [Fe(bapbpy)(NCS)₂]. Chemistry of Materials: A Publication of the American Chemical Society, 21(6), 1123–1136. https://doi.org/10.1021/cm803414q
22. Siegler, M. A., & Lutz, M. (2009). Ni(salen): A system that forms many solvates with interacting Ni atoms. Crystal Growth & Design, 9(2), 1194–1200. https://doi.org/10.1021/cg801109n
21. Siegler, M. A., Hao, X., Parkin, S., & Brock, C. P. (2008). Five more phases of the structural family [M(H₂O)₂(15-crown-5)](NO₃)₂. Acta Crystallographica. Section B, Structural Science, 64(Pt 6), 738–749. https://doi.org/10.1107/S0108768108034046
20. Siegler, M. A., Parkin, S., Selegue, J. P., & Brock, C. P. (2008). The elusive [Ni(H₂O)₂(15-crown-5)]²⁺ cation and related co-crystals of nickel(II) hydrates and 15-crown-5. Acta Crystallographica. Section B, Structural Science, 64(Pt 6), 725–737. https://doi.org/10.1107/S0108768108034058
19. Bonnet, S., Siegler, M. A., Costa, J. S., Molnár, G., Bousseksou, A., Spek, A. L., Gamez, P., & Reedijk, J. (2008). A two-step spin crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase. Chemical Communications (Cambridge, England), 43, 5619–5621. https://doi.org/10.1039/b811746b
18. Long, S., Parkin, S., Siegler, M. A., Cammers, A., & Li, T. (2008). Polymorphism and phase behaviors of 2-(phenylamino)nicotinic acid. Crystal Growth & Design, 8(11), 4006–4013. https://doi.org/10.1021/cg800123z
17. Long, S., Parkin, S., Siegler, M., Brock, C. P., Cammers, A., & Li, T. (2008). Polymorphism of an organic system effected by the directionality of hydrogen-bonding chains. Crystal Growth & Design, 8(9), 3137–3140. https://doi.org/10.1021/cg800339h
16. Garza-Ortiz, A., Maheswari, P. U., Siegler, M., Spek, A. L., & Reedijk, J. (2008). Ruthenium(III) chloride complex with a tridentate bis(arylimino)pyridine ligand: synthesis, spectra, X-ray structure, 9-ethylguanine binding pattern, and in vitro cytotoxicity. Inorganic Chemistry, 47(15), 6964–6973. https://doi.org/10.1021/ic8005579
15. Chen, J., Subramanian, S., Parkin, S. R., Siegler, M., Gallup, K., Haughn, C., Martin, D. C., & Anthony, J. E. (2008). The influence of side chains on the structures and properties of functionalized pentacenes. Journal of Materials Chemistry, 18(17), 1961-1969. https://doi.org/10.1039/b717082c
14. Siegler, M. A., Kooijman, H., & Spek, A. L. (2008b). (S)-6-methyl-∊-caprolactone. Acta Crystallographica. Section E, Structure Reports Online, 64(Pt 3), o607. https://doi.org/10.1107/S1600536808004583
13. Siegler, M. A., Kooijman, H., & Spek, A. L. (2008). (4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methylethenyl)perhydronaphthalen-2-one. Acta Crystallographica. Section E, Structure Reports Online, 64, o337–o337. https://doi.org/10.1107/s1600536807067335
12. Siegler, M. A., Fu, Y., Simpson, G. H., King, D. P., Parkin, S., & Brock, C. P. (2007). An unexpected co-crystal with a variable degree of order: 1:1 rac-1,2-cyclohexanediol/triphenylphosphine oxide. Acta Crystallographica. Section B, Structural Science, 63(Pt 6), 912–925. https://doi.org/10.1107/S0108768107054699
11. Xu, Y.-H., Siegler, M., & Long, S. (2007). (3aR,7aR)-Bis(4-nitrophenyl) 2-oxoperhydrobenzo[d]imidazole-1,3-dicarboxylate. Acta Crystallographica. Section E, Structure Reports Online, 63, o3835–o3835. https://doi.org/10.1107/s1600536807039785
10. Zhong, M., Siegler, M., & Long, S. (2007). tert-ButylN-[(1R,2R)-2-(isothiocyanato)cyclohexyl]carbamate. Acta Crystallographica. Section E, Structure Reports Online, 63, o3589–o3589. https://doi.org/10.1107/s1600536807035015
9. Long, S., Siegler, M., & Li, T. (2007). 2,4,6-Trimethylanilinium chloride. Acta Crystallographica. Section E, Structure Reports Online, 63, o3080–o3080. https://doi.org/10.1107/s1600536807025718
8. Sonar, V. N., Ring, J. R., Siegler, M., & Crooks, P. A. (2007). (E)-1-[(2-Chlorophenyl)methyleneamino]guanidinium chloride. Acta Crystallographica. Section E, Structure Reports Online, 63, o974–o975. https://doi.org/10.1107/s1600536807002887
7. Sonar, V. N., Neelakantan, S. , Siegler M., & Crooks, P. A.. (2007). (E)-1-[(2-Methoxyphenyl)methyleneamino]guanidinium chloride. Acta Crystallographica. Section E, Structure Reports Online, 63, o535-o536. https://doi.org/10.1107/S1600536806055383
6. Long, S., Siegler, M., & Li, T. (2007). 6-Chloronicotinic acid. Acta Crystallographica. Section E, Structure Reports Online, 63, o279-o281. https://doi.org/10.1107/S1600536806053177
5. Long, S., Siegler, M., & Li, T. (2006). 2-Oxo-1,2-dihydropyridine-3-carboxylic acid. Acta Crystallographica. Section E, Structure Reports Online, 62, o5664-o5665. https://doi.org/10.1107/S1600536806048768
4. Siegler, M., & Long, S. (2006). (4R,5R)-4,5-Diphenylimidazolidin-2-one. Acta Crystallographica. Section E, Structure Reports Online, 62, o5310–o5311. https://doi.org/10.1107/s1600536806044382
3. Long, S., Siegler, M., & Li, T. (2006). N-(3-Chloro-2-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxamide. Acta Crystallographica. Section E, Structure Reports Online, 62, o4278–o4279. https://doi.org/10.1107/s160053680603488x
2. Long, S., Siegler, M., & Li, T. (2006). 2-(2-Isopropylanilino)pyridine-3-carboxylic acid. Acta Crystallographica. Section E, Structure Reports Online, 62, o4211-o4213. https://doi.org/10.1107/S1600536806034131
1. Hao, X., Siegler, M. A., Parkin, S., & Brock, C. P. (2005). [M(H₂O)₂(15-crown-5)](NO₃)₂: A system rich in polymorphic and modulated phases. Crystal Growth & Design, 5(6), 2225–2232. https://doi.org/10.1021/cg050312j