Kenneth D. Karlin Research Group > 2000-1996 Publications

2000-1996 Publications

  • Liang, H.-C.; Karlin, K. D.; Dyson, R.; Kaderli, S.; Jung, B.; Zuberbühler, A. D. “Dioxygen-Binding Kinetics and Thermodynamics of a Series of Dicopper(I) Complexes with Bis[2-(2-pyridyl)ethyl]amine Tridentate Chelators Forming Side-On Peroxo Bridged Dicopper(II) Adducts” Inorg. Chem. 2000, 39, 5884-5894.
  • Moënne-Loccoz, P.; Richter, O.-M. H.; Huang, H.-w.; Wasser, I. M. Ghiladi, R. A.; Karlin, K. D.; de Vries, S. “Nitric Oxide Reductase from Paracoccus denitrificans Contains an Oxo-Bridged Heme-Non-Heme Diiron Center”, J. Am. Chem. Soc., 2000, 122,9344-9345.
  • Ju, T. D.; Woods, A. S.; Cotter, R. J.; Moënne-Loccoz, P.; Karlin, K. D. “Dioxygen and Nitric Oxide Reactivity of a Reduced Heme/Non-Heme Diiron(II) Complex [(5L)FeII…FeII-Cl]+. Using a Tethered Tetraarylporphyrin for the Development of an Active Site Reactivity Model for Bacterial Nitric Oxide Reductase”, Inorg. Chim. Acta, 2000, 297, 362-372.
  • Kopf, M.-A.; Karlin, K. D. “Models of Copper Enzymes and Heme-Copper Oxidases”, In Biomimetic Oxidations; B. Meunier, Ed.; Imperial College Press: London, 2000; Ch. 7, pp 309-362.
  • Feiters, M. C.; Klein Gebbink, R. J. M.; Solé, V. A.; Nolting, H.-F.; Karlin, K. D.; Nolte, R. J. M. “X-ray Absorption Spectroscopic Studies of the Cu(I) Complexes of Crown Ether Appended Bis-{(2-pyridyl)ethyl}amines and Their Dioxygen Adducts”, Inorg. Chem., 1999, 38, 6171-6180.
  • Klein Gebbink, R. J. M.; Martens, C. F.; Kenis, P. J. A.; Jansen, R. J.; Nolting, H.-F.; Solé, V. A.; Feiters, M. C.; Karlin, K. D.; Nolte, R. J. M., “Synthesis, Structure and Reactivity of Copper Dioxygen Complexes Derived from Molecular Receptor Ligands”, Inorg. Chem., 1999, 38, 5755-5768.
  • Karlin, K. D.; Gan, Q.-f.; Tyeklár, Z. “Dioxygen-Copper Reactivity at Trinuclear Centers: Formation of Hexanuclear and Mixed-Valent Adducts” Chem. Commun., 1999, 2295-2296.
  • Ghiladi, R. A.; Ju, T. D.; Lee, D.-H.; Moënne-Loccoz, P.; Kaderli, S.; Neuhold, Y.-M.;  Zuberbühler, A. D.; Woods, A.S.; Cotter, R.J.; Karlin, K. D. “Formation and Characterization of a High-Spin Heme-Copper Dioxygen (Peroxo) Complex”, J. Am. Chem. Soc., 1999, 121, 9885-9886.
  • Kopf, M.-A.; Karlin, K. D., “Dioxygen Reactivity of Reduced Heme and Heme-Copper Complexes Utilizing Tetraarylporphryinates Tethered with both a Pyridyl Axial Ligand and N,N-bis[2-(2-pyridyl)ethyl]amine Chelate”, Inorg. Chem., 1999, 38, 4922-4923.
  • Kopf, M.-A.; Neuhold, Y.-M.; Zuberbühler, A. D.; Karlin, K. D. “Oxo and Hydroxo-Bridged Heme-Copper Assemblies from Acid-Base or Metal-Dioxygen Chemistry”, Inorg. Chem., 1999, 38, 3093-3102.
  • Ju, T. D.; Ghiladi, R. A.; Lee, D.-H.; van Strijdonck, G. P. F.; Woods, A. S.; Cotter, R. J.; Young, Jr., V. G.; Karlin, K. D. “Dioxygen Reactivity of Fully Reduced [(L)FeII…CuI]+ Complexes Utilizing Tethered Tetraarylporphyrinates: Active-Site Models for Heme-Copper Oxidases”, Inorg. Chem., 1999, 38, 2244-2245.
  • Becker, M.; Schindler, S.; Karlin, K. D.; Kaden, T. A.; Kaderli, S.; Palanché, T.; Zuberbühler, A. D. “Intramolecular Ligand Hydroxylation: Mechanistic High Pressure Studies on the Reaction of a Dinuclear Copper(I) Complex with Dioxygen”, Inorg. Chem., 1999, 38, 1989-1995.
  • Liang, H.-C., Dahan, M.; Karlin, K. D. “Dioxygen-activating bio-inorganic model complexes”, Current Opinion in Chemical Biology, 1999, 3, 168-175.
  • Corsi, D. M.; Murthy, N. N.; Young, Jr., V. G.; Karlin, K. D. “Synthesis, Structure and Solution NMR-Studies of Cyanide-Copper(II) and Cyanide-Bridged Fe(III)-Cu(II) Complexes”, Inorg. Chem., 1999, 38, 848-858.
  • Pidcock, E.; DeBeer, S.; Obias, H. V.; Hedman, B.; Hodgson, K. O.; Karlin, K. D.; Solomon, E. I. “A Study of Solid [{MePY2)}2(O2)]2+ using Resonance Raman and X-ray Absorption Spectroscopies; an Intermediate Cu2O2 Core Structure or a Solid Solution?”, J. Am. Chem. Soc., 1999, 121, 1870-1878.
  • Karlin, K. D.; Zuberbühler, A. D., “Formation, Structure, and Reactivity of Copper Dioxygen Complexes”, In Bioinorganic Catalysis:  Second Edition, Revised and Expanded. (Reedijk, J.; Bouwman, E.; Eds.), Marcel Dekker:  New York, 1999, Ch. 14, 469-534.
  • Pidcock, E.; Obias, H. V.; Abe, Masaaki; Liang, H.-C.; Karlin, K. D.; Solomon, E. I. “Spectroscopic and Theoretical Studies of Oxygenated Dicopper(I) Complexes Containing Hydrocarbon-linked Bis[2-(2-pyridyl)ethyl]amine units: Investigation of a Butterfly [Cu2-m-h2:h2)(O2)]2+ Core”, J. Am. Chem. Soc., 1999, 121, 1299-1308.
  • Obias, H. V.; Lin, Y.; Murthy, N. N.; Pidcock, E.; Solomon, E. I. Ralle, M.; Blackburn, N. J.; Neuhold, Y.-M.; Zuberbühler, A. D.; Karlin, K. D. “Peroxo-, Oxo-, and Hydroxo-Bridged Dicopper Complexes: Observation of Exogenous Hydrocarbon Substrate Oxidation”, J. Am. Chem. Soc., 1998, 120, 12960-12961.
  • Karlin, S.; Zhu, Z.-Y.; Karlin, K. D. “Extended Metal Environments of Cytochrome c Oxidase Structures”, Biochemistry, 1998, 37, 17726-17734.
  • Obias, H. V.; van Strijdonck, G. P. F.; Ralle, M.; Blackburn, N. J.; Karlin, K. D., “Heterobinucleating Ligand Induced Structural and Chemical Variations in [(L)FeIII-O-CuII]+ m-Oxo Complexes”, J. Am. Chem. Soc., 1998, 120, 9696-9697.
  • Root, D. E.; Mahroof-Tahir, M.; Karlin, K. D.; Solomon, E. I., “Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu2(UN-O-)(OOH)]2+ “, Inorg. Chem., 1998, 37, 4838-4848.
  • Pidcock, E.; Obias, H. V.; Zhang, C. X.; Karlin, K. D.; Solomon, E. I. “Investigation of the Reactive Oxygen Intermediate in an Arene Hydroxylation Reaction Performed by Xylyl-bridged Binuclear Complexes”, J. Am. Chem. Soc., 1998, 120, 7841-7847.
  • Karlin, K. D.; Zhu, Z-Y.; Karlin, S., “The Environment of Multinuclear Copper Metal Linkages in Protein Structures”, JBIC, J. Biol. Inorg. Chem., 1998, 3, 172-187.
  • Karlin, K. D.; Lee, D.-H.; Obias, H. V.; Humphreys, K. J., “Copper-Dioxygen Complexes: Functional Models for Proteins”, Pure Appl. Chem., 1998, 70, 855-862.
  • Karlin, S.; Zhu, Z.Y.; Karlin, K. D., “The Extended Environment of Mononuclear Metal Centers in Protein Structures”, Proc. Natl. Acad. Sci. USA, 1997, 94, 14225-14230. PMCID: PMC24917
  • Lee, D.-H.; Murthy, N. N.; Lin, Y.; Nasir, N. S.; Karlin, K. D., “Copper Ion Complexes with Derivatized Chelating Pterin Ligands”, Inorg. Chem., 1997, 119, 6328-6334.
  • Lee, D.-H.; Murthy, N. N.; Karlin, K. D., “Binuclear Copper Complexes Based on the 6,6′-Bis[[bis(2-pyridylmethyl)amino]methyl]-2,2′-bipyridine Ligand”, Inorg. Chem., 1997, 119, 5785-5792.
  • Comba, P.; Hilfenhaus, P.; Karlin, K. D. “Modeling of End-on m-Peroxo Dicopper(II) Complexes”, Inorg. Chem., 1997, 119, 2309-2313.
  • Nanthakumar, A.; Fox, S.; Murthy, N. M., Karlin, K. D., “Inferences from the 1H-NMR Spectroscopic Study of an Antiferromagnetically Coupled Heterobinuclear Fe(III)-(X)-Cu(II)  S = 2 System  (X = O2–, OH–),”  J. Am. Chem. Soc., 1997, 119, 3898-3906.
  • Karlin, K. D.; Kaderli, S.; Zuberbühler, A. D, “Kinetics and Thermodynamics of Copper(I)/Dioxygen Interaction”, Acc. Chem. Res., 1997, 30, 139-147.
  • Frey, S. T.; Murthy, N. N.; Weintraub, S. T.; Thompson, L. K.; Karlin, K. D., “Hydrolysis of Unactivated Esters and Acetonitrile Hydration by a Hydroxo-Dicopper(II) Complex, Inorg. Chem., 1997, 36, 956-957.
  • Karlin, K. D.; Lee, D.-H.; Kaderli, S.; Zuberbühler, A. D., “Copper Dioxygen Complexes Stable at Ambient Temperature: Optimization of Ligand Design and Solvent” Chem. Commun., 1997, 475-476.
  • K. Leidenberger, M. vom Orde, B. Fischer, M.-A. Kopf, D.-H. Lee and K. D. Karlin, “Chemical Models for the Active Centre of Copper Containing Amino Acid Hydroxylases”, Chem. Biol. Pteridines Folates, Proc. 11th Int. Symp. Pteridines and Folates‘ Eds.: W. Pfleiderer, H. Rokos, Blackwell Science: Berlin, Vienna, Fed. Rep. Ger., 1997, p. 61-64.
  • Klein Gebbink, R. J. M.; Martens, C. F.; Feiters, M. C.; Karlin, K. D.; Nolte, R. J. M. “Novel Molecular Receptors Capable of Forming Cu2-O2 Complexes.  Effect of Preorganization on O2-Binding.”,  Chem. Commun., 1997, 389-390.
  • Karlin, K. D.; Tolman, W. B.; Kaderli, S.; Zuberbühler, A. D., “Kinetic and Thermodynamic Parameters of Copper-Dioxygen Interaction with Different Oxygen Binding Modes”, J. Molec. Catal. A., 1997, 117(1-3), 215-222.
  • Murthy, N. N.; Karlin, K. D.; Bertini, I.; Luchinat, C., “NMR and Electronic Relaxation in Paramagnetic Dicopper(II) Compounds”, J. Am. Chem. Soc., 1997, 119, 2156-2162.
  • Jung, B.; Karlin, K. D.; Zuberbühler, A. D. “Formation and Interconversion of End-on and Side-on m-Peroxo Dicopper(II) Complexes,” J. Am. Chem. Soc., 1996, 118, 3763-3764.
  • Frey, S. T.; Sun, H. H. J.; Murthy, N. N.; Karlin, K. D. “A New Trinuclear Copper Complexes and Its Reactions with Plasmid DNA”, Inorg. Chim. Acta, 1996, 242, 329-338.
  • Fox, S.; Nanthakumar, A.; Wikström, M.; Karlin, K. D.; Blackburn, N. J. “XAS Structural Comparisons of Reversibly Interconvertible Oxo- and Hydroxo-Bridged Heme-Copper Oxidase Model Compounds”, J. Am. Chem. Soc., 1996, 118, 24-34.
  • Martens, C. F.; Murthy, N. N.; Obias, H. V.; Karlin, K. D. “Oxo-Bridged Heme/Non-heme Iron Complexes” J. Chem. Soc. Chem. Commun.  1996, 629-630.
  • Lee, D.-H.; Murthy, N. N.; Karlin, K. D. “Copper(I)/Dioxygen Reactivity with Dinuclear Compounds:  Catalytic Oxygenation and Oxo-Transfer to a Ketone”.  Inorg. Chem. 1996, 35, 804-805