1990-86

  • Nasir, M. S.; Cohen, B. I.; Karlin, K. D. “Oxidative Dehalogenation During a Copper Complex Mediated Hydroxylation Reaction”, Inorg. Chim. Acta, 1990, 176, 185-187.
  • Karlin, K. D.; Gan, Q.-F.; Farooq, A.; Liu, S.; Zubieta, J., “A Trinuclear Copper(I) Complex, Reaction with Dioxygen and the Formation of a Hexanuclear Copper(II) Cluster.” Inorg. Chem. 1990, 29, 2549-2551.
  • Karlin, K. D.; Sanyal, I.; Farooq, A.; Jacobson, R. R.; Shaikh, S. N.; Zubieta, J. “Model for the Possible ‘Endogenous’ Bridge in Oxy-Hemocyanin: A Di-m-(OR)2-Bridged Dicopper(II) Complex (R = H, alkyl) with Low-Energy Charge-Transfer Absorption”, Inorg. Chim. Acta, 1990, 174, 13-15.
  • Paul, P. P.; Tyeklár, Z.; Farooq, A.; Karlin, K. D.; Liu, S.; Zubieta, J., “Isolation and X-ray Structure of a Dinuclear Copper-Nitrosyl Complex” J. Am. Chem. Soc. 1990, 112, 2430-2432.
  • Karlin, K. D.; Gan, Q.-F.; Farooq, A.; Liu, S.; Zubieta, J., “Synthesis and X-Ray Crystal Structure of a Trinuclear Copper Cluster” Inorg. Chim. Acta 1989, 165, 37-39.
  • Tyeklár, Z.; Karlin, K.D. “Copper-Dioxygen Chemistry. A Bioinorganic Challenge”, Acc. Chem. Res. 1989, 22, 241-248.
  • Pate, J. E.; Ross, P. K.; Thamann, T. J.; Reed, C. A.; Karlin, K. D.; Sorrell, T. N.; Solomon, E. I. “Spectroscopic Studies of the Charge Transfer and Vibrational Features of Binuclear Copper(II) Azide Complexes: Comparison to the Coupled Binuclear Copper Active Site in Met Azide Hemocyanin and Tyrosinase” J. Am. Chem. Soc. 1989, 111, 5198-5209.
  • Blackburn, N. J.; Strange, R. W.; Reedijk, J. Volbeda, A.; Farooq, A.; Karlin, K. D.; Zubieta, J. “X-Ray Absorption Edge Spectroscopy of Cu(I) Complexes. The Coordination Geometry of Cu(I) in the Reduced Forms of Copper Proteins and Their Derivatives with Carbon Monoxide” Inorg. Chem. 198928, 1349-1357.
  • Tyeklár, Z.; Paul, P.P.; Jacobson, R.R.; Farooq, A.; Karlin, K.D.; Zubieta, J. “Dioxygen-Copper Reactivity. Comparisons of the Reactions of Electrophiles and Other Reagents with Three Classes of {Cu2-O2}n+ Species”, J. Am. Chem. Soc., 1989, 111, 388-389.
  • Cruse, R.W.; Kaderli, S.; Karlin, K. D.; Zuberbühler, A.D. “Kinetic and Thermodynamic Studies on the Reaction of O2 with Two Dinuclear Copper(I) Complexes”, J. Am. Chem. Soc., 1988, 110, 6882-6883.
  • Karlin, K. D.; Ghosh, P.; Cruse, R. W.; Farooq, A.; Gultneh, Y.; Jacobson, R. R.; Blackburn, N. J.; Strange, R. W.; Zubieta, J. “Dioxygen-Copper Reactivity: Generation, Characterization and Reactivity of a Hydroperoxo-Dicopper(II) Complex”, J. Am. Chem. Soc. 1988, 110, 6769-6780.
  • Zuberbühler, A.D.; Cruse, R.W.; Kaderli, S.; Meyer, C.J.; Karlin, K.D. “Copper Mediated Hydroxylation of an Arene: Kinetics and Mechanism of the Reaction of a Dicopper(II) m-Xylyl Containing Complex with H2O2 to Yield a Phenoxo-Dicopper(II) Complex”, J. Am. Chem. Soc. 1988, 110, 5020-5024.
  • Karlin, K. D.; Farooq, A.; Gultneh, Y.; Hayes, J. C.; Zubieta, J. “Synthesis and Stucture of a CO-Containing Phenoxo-Bridged Dicopper(I) Complex”, Inorg. Chim. Acta, 1988, 153, 73-74.
  • Karlin, K. D.; Cohen, B. I.; Farooq, A.; Liu, S.; Zubieta J. “Copper Mediated Hydroxylation of a Modified Monooxygenases Model System”, Inorg. Chim. Acta, 1988, 153, 9-11.
  • Tyeklar, Z.; Ghosh, P.; Karlin, K.D.; Farooq, A.; Cohen, B.I.; Cruse, R.W.; Gultneh, Y.; Haka, M.S.; Jacobson, R.R.; Zubieta, J. “Models for Copper Proteins: Reversible Binding and Activation of Dioxygen and the Reactivity of Peroxo and Hydroperoxo Dicopper(II) Complexes”, In Metal Clusters in Proteins, L.Que, Ed., ACS Symposium Series No. 372; American Chemical Society:  Washington, D.C. 1988, Chapter 5, pp 85-104.
  • Blackburn, N.J.; Strange, R.W.; Farooq, A.; Haka, M.S.; Karlin, K.D. “X-ray Absorption Studies of Three Coordinate Dicopper(I) Complexes and Their Dioxygen Adducts” J. Am. Chem. Soc. 1988, 110, 4263-4272.
  • Jacobson, R. R.; Tyeklar, Z.; Karlin, K. D.; Liu, S.; Zubieta, J. “A Cu2-O2 Complex. Crystal Structure and Characterization of a Reversible Dioxygen Binding System”, J. Am. Chem. Soc. 1988, 110, 3690-3692.
  • Karlin, K.D.; Haka, M.S.; Cruse, R.W.; Meyer, G.J.; Farooq, A.; Gultneh, Y.; Hayes, J.C.; Zubieta, J. “Dioxygen-Copper Reactivity. Reversible O2 and CO Binding to Structurally Characterized Dicopper(I) Complexes Containing Hydrocarbon-Linked Bis[2-(2-pyridyl)ethyl)]amine Units”, J. Am. Chem. Soc., 1988, 110, 1196-1207.
  • Ghosh, P.; Tyeklar, Z.; Karlin, K.D.; Jacobson, R.R.; Zubieta, J. “Dioxygen-Copper Reactivity: X-ray Structure of an Acyl-Peroxo Dicopper(II) Complex J. Am. Chem. Soc. 1987, 109, 6889-6891.
  • Karlin, K.D.; Cohen, B.I.; Jacobson, R.R.; Zubieta, J. “Dioxygen-Copper Reactivity: Hydroxylation-Induced Methyl Migration in a Copper Monooxygenase Model System”, J. Am. Chem. Soc., 1987, 109, 6194-6196.
  • Karlin, K. D.; Gultneh, Y. “Binding and Activation of Molecular Oxygen by Copper Complexes” Prog. Inorg. Chem. 1987, 35, 219-327.
  • Karlin, K. D.; Farooq, A.; Cruse, R. W.; Gultneh, P.; Ghosh, P.; Jacobson, R. R.; Zubieta, J. “Dioxygen-Copper Reactivity: Reversible Binding of Dioxygen and the Reactivity of Peroxo- and Hydroperoxo-Dicopper(II) Complexes” Rec. Trav. Chim. Pays-Bas 1987, 106(6-7), 368.
  • Garcia, M. C.; Karlin, K. D.; Holwerda, R. A. “Oxidation of (Hydroxyethyl)ferrocene by [2-pyridylmethylbis(2-ethylthioethyl)amine]copper(II)” J. Inorg. Biochem. 1987, 30, 167-175.
  • Karlin, K. D.; Cruse, R. W.; Gultneh, Y.; Farooq, A.; Hayes, J. C.; Zubieta, J. “Dioxygen-Copper Reactivity. Reversible Binding of O2 and CO to a Phenoxo-Bridged Dicopper(I) Complex” J. Am. Chem. Soc. 1987, 109, 2668-2679.
  • Pate, J. E.; Cruse, R. W.; Karlin, K. D.; Solomon, E. I. “Vibrational, Electronic and Resonance Raman Spectral Studies of [Cu2(XYL-O-)O2]+, a Copper(II) Peroxide Model Complex of Oxyhemocyanin” J. Am. Chem. Soc. 1987, 109, 2624-2630.
  • Karlin, K. D.; Cruse, R. W.; Gultneh, Y. “Dioxygen-Copper Reactivity: Preparation and Characterization of a Hydroperoxo-Dicopper(II) Complex” J. Chem. Soc. Chem.Commun. 1987, 596-600.
  • Karlin, K. D.; Farooq, A.; Hayes, J. C.; Cohen, B. I.; Rowe, T. M., Sinn, E., Zubieta, J. “Models for Met-Hemocyanin Derivatives: Structural and Spectroscopic Comparisons of Analogous Phenoxo- and X (OH, OMe, N3, Cl, Br, OAc, OBz) Doubly-Bridged Dinuclear Copper(II) Complexes” Inorg. Chem. 1987, 26, 1271-1280.
  • Karlin, K. D.; Cohen, B. I.; Hayes, J. C.; Farooq, A.; Zubieta, J. “Models for Met-Hemocyanin Derivatives: Structural and Spectroscopic Comparisons of Related Azido-Coordinated (N3) Mono- and Dinuclear Copper(II) Complexes” Inorg. Chem. 1987, 26, 147-153.
  • Blackburn, N. J.; Strange, R. W.; Cruse, R. W.; Karlin, K. D. “Dioxygen-Copper Reactivity – EXAFS Studies of a Peroxo-Dicopper(II) Complex” J. Am. Chem. Soc. 1987, 109, 1235-1237.
  • Karlin, K. D.; Cruse, R. W.; Haka, M. S.; Gultneh, Y.; Cohen, B. I. “Intermediacy of a Peroxo-dicopper(II) Species in a Model Copper Mono-oxygenase System” Inorg. Chim. Acta 1986, 125, L43-L44.
  • Baek, H. K.; Karlin, K. D.; Holweda, R. A. “Kinetic Stability of the Cysteine Adduct with [Tris(2-pyridylethyl)amine]copper(II)” Inorg. Chem. 1986, 25, 2347-2349.
  • Karlin, K. D.; Cruse, R. W.; Gultneh, Y.; Hayes, J. C.; McKown, J. W.; Zubieta, J. “The Reversible Binding and Activation of Dioxygen with Dinuclear Copper Complex Systems” In Biological & Inorganic Copper Chemistry; Karlin, K. D.; Zubieta, J., Eds.; Adenine: Guilderland, N. Y., 1986; Vol. 2, pp 101-114.
  • Karlin, K. D.; Gultneh, Y.; Cruse, R.W.; Hayes, J. C.; Haka, M. S.; Zubieta, J. “Dioxygen Binding and Activation in Dinuclear Copper Complex Systems” In Frontiers in Bioinorganic Chemistry; Xavier, A., Ed.; VCH Publishers: Weinheim, Germany, 1986; pp 204-212.